Curable compositions and membranes
US-9527973-B2 · Dec 27, 2016 · US
US10322953B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10322953-B2 |
| Application number | US-201715681542-A |
| Country | US |
| Kind code | B2 |
| Filing date | Aug 21, 2017 |
| Priority date | Jun 13, 2006 |
| Publication date | Jun 18, 2019 |
| Grant date | Jun 18, 2019 |
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Water treatment systems including electrically-driven and pressure-driven separation apparatus configured to produce a first treated water suitable for use as irrigation water and a second treated water suitable for use as potable water from brackish water and methods of operation of same.
Opening claim text (preview).
What is claimed is: 1. A water treatment system for producing water for irrigation, the system comprising: an electrodialysis apparatus including one or more monovalent ion selective membranes and having an inlet fluidly connectable to a source of brackish water to be treated, a diluate outlet, and a concentrate outlet; a nanofiltration apparatus positioned downstream of the electrodialysis apparatus and having an inlet in fluid communication with the diluate outlet of the electrodialysis apparatus, a filtrate outlet, and a retentate outlet; an irrigation distribution system in fluid communication with the retentate outlet of the nanofiltration apparatus and with the diluate outlet of the electrodialysis apparatus; a diverting valve configured to vary an amount of diluate from the electrodialysis apparatus directed to the irrigation distribution system and an amount of diluate from the electrodialysis apparatus directed to the nanofiltration apparatus; a controller configured to adjust the amount of diluate from the electrodialysis apparatus directed to the irrigation distribution system and the amount of diluate from the electrodialysis apparatus directed to the nanofiltration apparatus with the diverting valve; an electrically operated separation apparatus having an inlet in fluid communication with the filtrate outlet of the nanofiltration apparatus, a diluate outlet, and a concentrate outlet; and a second diverting valve configured to adjust an amount of concentrate from the electrically operated separation apparatus directed to the electrodialysis apparatus as diluate makeup or as concentrate makeup. 2. The water treatment system of claim 1 , further comprising a pre-filtration system in fluid communication between the source of brackish water to be treated and the inlet of the electrodialysis apparatus. 3. The water treatment system of claim 2 , wherein a pre-filtration system includes one of a microfilter, a settler, and a coarse particle filter. 4. The water treatment system of claim 1 , wherein one or more monovalent ion selective membranes include one or more monovalent cation selective membranes. 5. The water treatment system of claim 4 , wherein the one or more monovalent cation selective membranes have a selectivity of at least about 2. 6. The water treatment system of claim 5 , wherein the one or more monovalent cation selective membranes have a selectivity of about 5. 7. The water treatment system of claim 4 , wherein the one or more monovalent ion selective membranes further include one or more monovalent anion selective membranes. 8. The water treatment system of claim 7 , wherein the one or more monovalent anion selective membranes have a selectivity of about 5. 9. The water treatment system of claim 1 , wherein the electrodialysis apparatus is configured to produce diluate having a sodium adsorption ratio (SAR) value of less than about 20. 10. The water treatment system of claim 9 , wherein the electrodialysis apparatus is configured to produce diluate having a SAR value of less than about 9. 11. The water treatment system of claim 1 , further including a mixer configured to blend diluate produced in the electrodialysis apparatus with any retentate produced in the nanofiltration apparatus. 12. The water treatment system of claim 11 , wherein the mixer is configured to produce irrigation water having a SAR value intermediate of a SAR value of the diluate and a SAR value of the retentate. 13. The water treatment system of claim 1 , further comprising a sensor in communication with the controller, the sensor configured to provide the controller with an indication of one or more parameters of one of diluate from the electrodialysis apparatus and retentate from the nanofiltration apparatus, the controller configured to adjust the diverting valve responsive to the indication of the one or more parameters. 14. The water treatment system of claim 1 , further comprising a sensor in communication with a controller, the sensor configured to provide the controller with an indication of one or more parameters of one of diluate from the electrodialysis apparatus and retentate from the nanofiltration apparatus, the controller configured to adjust one or more operating parameters of the electrodialysis apparatus responsive to the indication of the one or more parameters. 15. A method of treating brackish water to produce irrigation water, the method comprising: directing brackish water to be treated to an inlet of an electrodialysis apparatus including one or more monovalent ion selective membranes, a diluate outlet, and a concentrate outlet; treating the brackish water to be treated in the electrodialysis apparatus to produce a diluate; determining an amount of the diluate to direct to an inlet of a nanofiltration apparatus positioned downstream of the electrodialysis apparatus and having an inlet in fluid communication with the diluate outlet of the electrodialysis apparatus, a filtrate outlet, and a retentate outlet, and an amount of the diluate to direct to an irrigation distribution system in fluid communication with the retentate outlet of the nanofiltration apparatus and with the diluate outlet of the electrodialysis apparatus; directing at least a portion of the diluate to the irrigation distribution system; varying an amount of diluate from the electrodialysis apparatus directed to the irrigation distribution system and an amount of diluate from the electrodialysis apparatus directed to the nanofiltration apparatus using a diverting valve and a controller configured to adjust the amount of diluate from the electrodialysis apparatus directed to the irrigation distribution system and the amount of diluate from the electrodialysis apparatus directed to the nanofiltration apparatus with the diverting valve; treating any diluate directed to the inlet of a nanofiltration apparatus in the nanofiltration apparatus to produce a filtrate and a retentate; directing the filtrate from the nanofiltration apparatus to an electrically operated separation apparatus having an inlet in fluid communication with the filtrate outlet of the nanofiltration apparatus, a diluate outlet, and a concentrate outlet; and adjusting an amount of concentrate from the electrically operated separation apparatus directed to the electrodialysis apparatus as diluate makeup or as concentrate makeup using a second diverting valve; and combining any retentate from the nanofiltration apparatus with the portion of the diluate from the electrodialysis apparatus directed to the irrigation distribution system at the irrigation distribution system. 16. The method of claim 15 , wherein producing the diluate in the electrodialysis apparatus comprises producing treated water having a SAR value of less than about 20. 17. The method of claim 16 , wherein producing the diluate in the electrodialysis apparatus comprises producing treated water having a SAR value of less than about 9. 18. The method of claim 16 , wherein producing the retentate in the nanofiltration apparatus comprises producing treated water having a SAR value of less than the SAR value of the diluate. 19. The method of claim 16 , wherein producing the retentate and the permeate in the nanofiltration apparatus comprises producing retentate having a SAR value less than a SAR value of the permeate. 20. The method of claim 16 wherein combining any retentate with the portion of the diluate directed to the irrigation distribution system comprises producing irrigation water with a SAR value
by ultrafiltration or microfiltration · CPC title
by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis · CPC title
Reverse-osmosis · CPC title
Ion-selective electrodialysis · CPC title
Seawater, e.g. for desalination · CPC title
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