Adsorbent for capturing carbon dioxide comprising magnesium oxide/titanium dioxide composite and method for manufacturing same

Patent metadata

Field	Value
Publication number	US-10322400-B2
Application number	US-201715442186-A
Country	US
Kind code	B2
Filing date	Feb 24, 2017
Priority date	Jun 13, 2016
Publication date	Jun 18, 2019
Grant date	Jun 18, 2019

Abstract

Provided is an adsorbent for capturing carbon dioxide and a method for manufacturing same, and more particularly, to an adsorbent for capturing carbon dioxide, including a magnesium oxide/titanium dioxide composite having wide surface area, large pore volume and good CO 2 adsorption performance, and a method for manufacturing same. According to the present invention, a novel MgO based composite metal oxide which may stably adsorb CO 2 at a low temperature such as room temperature is provided. The adsorbent for capturing carbon dioxide, including a magnesium oxide/titanium dioxide composite has good thermal stability, and controls basic sites easily, and is used in various fields for capturing carbon dioxide. In addition, by controlling the molar ratio of the metal ions of the magnesium oxide/titanium dioxide composite and controlling morphology, an adsorbent for capturing carbon dioxide having large surface area and pore volume and strong basic sites may be provided.

First claim

What is claimed is:

1. An adsorbent for capturing carbon dioxide comprising a magnesium oxide/titanium dioxide composite,
wherein a molar ratio of magnesium/titanium is greater than 2.0 and less than 5.0, and
wherein the magnesium oxide/titanium dioxide composite has a crystalline phase of MgO—MgTi 2 O 4 .

2. The adsorbent for capturing carbon dioxide according to claim 1 , wherein the magnesium oxide/titanium dioxide composite has a mesoporous structure.

3. The adsorbent for capturing carbon dioxide according to claim 1 , wherein the magnesium oxide/titanium dioxide composite is formed by self-assembly of a metal precursor comprising a magnesium precursor and a titanium precursor with a soft template.

4. The adsorbent for capturing carbon dioxide according to claim 3 , wherein the magnesium precursor is magnesium nitrate hexahydrate or magnesium acetate tetrahydrate, and the titanium precursor is titanium isopropoxide or titanium tetrabutoxide.

5. The adsorbent for capturing carbon dioxide according to claim 3 , wherein the soft template is diblock copolymer or triblock copolymer.

6. The adsorbent for capturing carbon dioxide according to claim 5 , wherein the triblock copolymer is polyethylene glycol-polypropylene glycol-polyethylene glycol or cetrimonium bromide.

7. The adsorbent for capturing carbon dioxide according to claim 1 , wherein the molar ratio of magnesium/titanium is from 3.0 to 4.0.

Assignees

• Myongji Univ Industry And Academia Cooperation Foundation

Inventors

• Seo Jeong Gil
• Hiremath Vishwanath
• Hwang Soon Ha

Classifications

• B01D2253/1124

  Metal oxides · CPC title

• F17C2221/013

  Carbon dioxide · CPC title

• B01D2253/25

  Coated, impregnated or composite adsorbents · CPC title

• B01J20/28057

  Surface area, e.g. B.E.T specific surface area · CPC title

• B01D2253/304

  Linear dimensions, e.g. particle shape, diameter · CPC title