All-solid-state lithium-sulfur polymer electrochemical cells and production methods thereof

Patent metadata

Field	Value
Publication number	US-10320029-B2
Application number	US-201414899788-A
Country	US
Kind code	B2
Filing date	Jun 20, 2014
Priority date	Jun 21, 2013
Publication date	Jun 11, 2019
Grant date	Jun 11, 2019

Abstract

All-solid-state lithium-sulfur electrochemical cells and production methods thereof are described. The Li—S electrochemical cells comprise at least one multilayer component which comprises an ion-conductive solid electrolyte film, a positive electrode film containing a sulfur composite, and a negative electrode film containing lithium. Positive electrodes films, prefabricated electrolyte-positive electrode elements, their uses as well as methods of their production are also described.

First claim

The invention claimed is:

1. An electrochemical cell comprising at least one multilayer component which comprises:
a positive electrode film comprising, on a current collector, elemental sulfur particles as an electrochemically active material, conductive carbon, and a polymer binder, the elemental sulfur particles being encapsulated in an inorganic coating material, said inorganic coating material comprising an inorganic material selected from:
Li a M 1 b (XO 4 ), wherein 0≤a≤2, 0<b≤1; M 1 is selected from Fe, Mn, Co, Ni, and Ti, or combinations thereof, and X is selected from P, Si and S;
Li c M 2 d Z e , wherein 0≤c≤4, 0<d≤5, 0<e≤12, M 2 is selected from Mo, V, Ti, Al, and Si, and Z is O; and
Li c M 2 d Z e , wherein 1≤c≤4, 0<d≤5, 0<e≤12, M 2 is selected from Mo, V, Ti, Al, and Si, and Z is selected from S and Se;

a negative electrode film comprising lithium as an electrochemically active material; and
a solid electrolyte film between the negative and positive electrode films, said solid electrolyte film comprising at least one lithium salt and at least one polymeric layer, wherein the solid electrolyte film is an ion-conductive film and further comprises at least one electrolyte inorganic compound in the polymeric layer or in a separate ion-conductive solid layer, the polymeric layer comprising a block copolymer composed of at least one lithium-ion solvating segment and at least one cross-linkable segment, the cross-linkable segment being a polymer segment comprising at least one functional group cross-linkable multi-dimensionally by irradiation or thermal treatment, and the lithium-ion solvating segment being selected from homo- and copolymers having repeating units of formula (I):

wherein,
R is selected from H, C 1 -C 10 alkyl, or —(CH 2 —O—R a R b );
R a is (CH 2 —CH 2 —O) y ;
R b is selected from H and a C 1 -C 10 alkyl group;
x is an integer selected from the range of 10 to 200,000; and
y is an integer selected from the range of 0 to 10.

2. The electrochemical cell according to claim 1 , wherein the electrolyte inorganic compound in the solid electrolyte film is selected from SiO 2 , Al 2 O 3 , TiO 2 , lithium ion-conductive glasses or ceramics, and other lithium ion-conductive solids, and combinations thereof.

3. The electrochemical cell according to claim 2 , wherein the lithium ion-conductive glasses or ceramics are selected from NASICON, LISICON, thio-LISICON, Garnet, either in crystalline or amorphous form, and combinations thereof.

4. The electrochemical cell according to claim 1 , wherein the solid electrolyte film has a thickness between 10 and 200 μm.

5. The electrochemical cell according to claim 1 , wherein the polymer binder is a block copolymer composed of at least one lithium ion-solvating segment and at least one cross-linkable segment.

6. The electrochemical cell according to claim 5 , wherein the lithium ion-solvating segment is selected from homo- or copolymers having repeating units of Formula (I):

wherein,
R is selected from H, C 1 -C 10 alkyl, or —(CH 2 —O—R a R b );
R a is (CH 2 —CH 2 —O) y ;
R b is selected from H and a C 1 -C 10 alkyl group;
x is an integer selected from the range of 10 to 200,000; and
y is an integer selected from the range of 0 to 10.

7. The electrochemical cell according to claim 1 ,
wherein the inorganic material is in the form of particles, optionally coated with carbon.

8. The electrochemical cell according to claim 1 , wherein the inorganic material is selected from LiFePO 4 , LiNiPO 4 , LiMnPO 4 , LiCoPO 4 , and LiFe 1-x Ti x PO 4 , where 0<x<1.

9. The electrochemical cell according to claim 1 , wherein the inorganic material is selected from TiO 2 , V 2 O 5 , LiV 3 O 8 , Li 4 Ti 5 O 12 , MoO 2 , SiO 2 , and Al 2 O 3 .

10. The electrochemical cell according to claim 1 , wherein the positive electrode film comprises a composite material including sulfur encapsulated in a coating material and the composite material is prepared by mechanofusion.

11. The electrochemical cell according to claim 1 , wherein the conductive carbon is a carbon powder or fiber selected from carbon black, activated carbon, graphite, graphene, and mixtures thereof.

12. The electrochemical cell according to claim 11 , wherein the conductive carbon has a specific surface area of at least 5 m 2 /g.

13. The electrochemical cell according to claim 1 , wherein the electrochemically active material of the negative electrode film comprises a lithium metal foil or a lithium metal alloy comprising at least 90% by weight of lithium.

14. The electrochemical cell according to claim 13 , wherein a surface of the electrochemically active material of the negative electrode film further includes a passivation layer formed in situ.

15. The electrochemical cell according to claim 13 , wherein the negative electrode film further comprises a protective layer.

16. A method for the manufacturing of an electrochemical cell as defined in claim 1 , comprising the following steps:
a) providing the positive electrode film, the electrolyte film, and the negative electrode film; and
b) stacking and laminating together the positive electrode, electrolyte, and negative electrode films between at least two rollers;
wherein the step of providing the positive electrode film comprises the steps of mixing the electrochemically active material of the positive electrode together with a conductive carbon, polymer precursors, and optionally lithium salt(s), inorganic compound(s) and/or solvent(s), coating the mixture obtained on a current collector, evaporating the solvent (if present) and polymerizing, by UV irradiation or thermal treatment, to form the positive electrode film.

17. The method according to claim 16 , wherein the step of providing the electrolyte film comprises the steps of mixing polymer precursors, lithium salt(s), optionally inorganic compound(s) and/or solvent(s) to adjust viscosity, casting the mixture obtained on a substrate, evaporating the solvent (if present) and polymerizing, by UV irradiation or thermal treatment, to form the solid electrolyte film.

18. The process according to claim 16 , wherein the step of providing the electrolyte film comprises the steps of (i) mixing polymer precursors, lithium salt(s), inorganic compound(s), and optionally solvent(s) to adjust the viscosity, casting the mixture obtained on a substrate, evaporating the solvent (if present) and polymerizing, by UV irradiation or thermal treatment, to form the solid electrolyte film, thus obtaining a polymer-inorganic compound film; and (ii) mixing polymer precursors, lithium salt(s), and optionally solvent(s) to adjust the viscosity, casting the mixture obtained on the polymer-inorganic compound film, evaporating the solvent (if necessary) and polymerizing, by UV irradiation or thermal treatment, to form the solid electrolyte film.

19. The method according to claim 16 , wherein step (b) comprises laminating the positive electrode film together with the solid electrolyte film and subsequently laminating the negative electrode film thereon.

20. A positive electrode film comprising, on a current collector, elemental sulfur particles as an electrochemically active material, a polymer binder and a conductive carbon, the elemental sulfur particles being encapsulated in an inorgani

Assignees

• Hydro Quebec

Inventors

• Zaghib Karim
• Kim Chisu
• Guerfi Abdelbast
• Barray Francis
• Gagnon Catherine
• Trottier Julie

Classifications

• H01M10/056

  characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes · CPC title

• H01M4/667

  in the form of layers, e.g. coatings · CPC title

• H01M10/0565 Primary

  Polymeric materials, e.g. gel-type or solid-type · CPC title

• H01M2220/20

  Batteries in motive systems, e.g. vehicle, ship, plane · CPC title

• H01M4/622

  being polymers · CPC title