Sulfur-loaded conductive polymer for high energy density lithium sulfide battery
US-2024186516-A1 · Jun 6, 2024 · US
US10320001B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10320001-B2 |
| Application number | US-201615289502-A |
| Country | US |
| Kind code | B2 |
| Filing date | Oct 10, 2016 |
| Priority date | Oct 20, 2015 |
| Publication date | Jun 11, 2019 |
| Grant date | Jun 11, 2019 |
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To provide a secondary cell including an electrode active material that is a compound represented by General Formula (1) below: where n is a natural number of from 4 through 8, a is a natural number of from 1 through 4, R 1 and R 2 may be identical to or different from each other and are each a hydrogen atom, an alkyl group, or an aromatic hydrocarbon group that may have a substituent, Y is a substituent, and b is an integer of from 0 through 3 and a+b is 4 or less in General Formula (1).
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What is claimed is: 1. A secondary cell comprising: an electrode active material that is a compound represented by General Formula (1) below: where n is a natural number of from 4 through 8, a is a natural number of from 1 through 4, R 1 and R 2 may be identical to or different from each other and are each a hydrogen atom, an alkyl group, or an aromatic hydrocarbon group that may have a substituent, Y is a substituent, and b is an integer of from 0 through 3 and a+b is 4 or less in General Formula (1), wherein when n ranges from 4 to 6: b is at least 1 and at least one Y in General Formula (1) is a substituent selected from the group consisting of a halogen atom, an alkoxy group, an aryl group, —SO 3 X where X is a hydrogen atom or an alkali metal, a sulfonic acid ester group, a carbamoyl group, a formyl group, a carboxyl group, and a carboxylic acid ester group; or at least one of R 1 and R 2 within General Formula (1) is an alkyl group, or an aromatic hydrocarbon group that may have a substituent. 2. The secondary cell according to claim 1 , wherein at least one of R 1 and R 2 in General Formula (1) are hydrogen atoms. 3. The secondary cell according to claim 1 , wherein Y in General Formula (1) is a hydrogen atom, an alkyl group, an alkoxy group, —SO 3 X, a formyl group, a carboxyl group, or a carboxylic acid ester group, where X in —SO 3 X is a hydrogen atom or an alkali metal. 4. The secondary cell according to claim 1 , wherein Y in General Formula (1) is a hydrogen atom, —SO 3 X, a formyl group, a carboxyl group, or a carboxylic acid ester group, where X in —SO 3 X is a hydrogen atom or an alkali metal. 5. The secondary cell according to claim 1 , wherein b in General Formula (1) is 0. 6. The secondary cell according to claim 1 , wherein n in General Formula (1) is 6 or 8. 7. The secondary cell according to claim 1 , wherein the compound represented by General Formula (1) is at least one selected from the group consisting of compounds represented by structural formulae below: 8. The secondary cell according to claim 1 , wherein the compound represented by General Formula (1) is a cathode active material. 9. The secondary cell according to claim 1 , wherein the compound represented by General Formula (1) undergoes a redox reaction during at least one of a charging process and a discharging process. 10. The secondary cell according to claim 1 , further comprising: a cathode; an anode; and an electrolyte. 11. The secondary cell according to claim 1 , wherein the secondary cell is a lithium ion secondary cell.
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