Method for making organic light emitting diode

Patent metadata

Field	Value
Publication number	US-10319932-B2
Application number	US-201715848403-A
Country	US
Kind code	B2
Filing date	Dec 20, 2017
Priority date	Aug 30, 2017
Publication date	Jun 11, 2019
Grant date	Jun 11, 2019

Abstract

A method for making an organic light emitting diode includes providing a preform structure including an anode electrode, a hole transport layer, and an organic light emitting layer stacked on each other in that order. A carbon nanotube composite structure including a polymer and a plurality of first carbon nanotubes dispersed in the polymer is also provided. The plurality of first carbon nanotubes is substantially parallel to each other, and a part of surface of the plurality of first carbon nanotubes is exposed from the polymer. The preform structure, the carbon nanotube composite structure and a cathode electrode are stacked on each other in that order.

First claim

What is claimed is:

1. A method for making an organic light emitting diode, the method comprising:
providing a preform structure comprising an anode electrode, a hole transport layer, and an organic light emitting layer stacked on each other in that order;
providing a carbon nanotube composite structure comprising a polymer and a plurality of first carbon nanotubes dispersed in the polymer, wherein the plurality of first carbon nanotubes is substantially parallel to each other, and a partial surface of the plurality of first carbon nanotubes is exposed from the polymer;
providing a cathode electrode; and
stacking the preform structure, the carbon nanotube composite structure, and the cathode electrode on each other in that order.

2. The method of claim 1 , wherein a method for making the carbon nanotube composite structure comprising:
providing a substrate having a substrate surface;
placing a carbon nanotube structure comprising the plurality of first carbon nanotubes on the substrate surface to form a composite structure, wherein the plurality of first carbon nanotubes is in direct contact with the substrate surface;
disposing a monomer solution on the carbon nanotube structure, wherein the monomer solution is formed by dispersing monomers into an organic solvent;
polymerizing the monomer, wherein the plurality of first carbon nanotubes is in direct contact with the substrate surface during disposing the monomer solution and polymerizing the monomer; and
removing the substrate.

3. The method of claim 1 , wherein the polymer has an ability to transmit electrons.

4. The method of claim 1 , wherein the stacking of the preform structure, the carbon nanotube composite structure, and the cathode electrode, further comprises placing the carbon nanotube composite structure on a surface of the organic light emitting layer away from the hole transport layer.

5. The method of claim 1 , wherein the stacking of the preform structure, the carbon nanotube composite structure, and the cathode electrode on each other in that order comprising:
placing the carbon nanotube composite structure on the preform structure, wherein the plurality of first carbon nanotubes is in direct contact with the organic light emitting layer;
hot pressing the carbon nanotube composite structure and the preform structure; and
placing the cathode electrode on a surface of the carbon nanotube composite structure away from the preform structure.

6. The method of claim 1 , wherein the stacking the preform structure, the carbon nanotube composite structure and the cathode electrode on each other in that order comprising:
placing the carbon nanotube composite structure on the preform structure;
placing the cathode electrode on a surface of the carbon nanotube composite structure away from the preform structure, wherein the plurality of first carbon nanotubes is in direct contact with the cathode electrode.

7. The method of claim 1 , wherein the carbon nanotube composite structure further comprises a plurality of second carbon nanotubes; after making the preform structure, stacking the carbon nanotube composite structure and the cathode electrode on each other in that order, the plurality of first carbon nanotubes is exposed from the polymer and in direct contact with the organic light emitting layer, and the plurality of second carbon nanotubes is exposed from the polymer and in direct contact with the cathode electrode.

8. The method of claim 1 , wherein the preform structure further comprises a support body, and the support body, the anode electrode, the hole transport layer, and the organic light emitting layer are stacked on each other in that order.

9. The method of claim 2 , wherein the plurality of first carbon nanotubes is joined end-to-end by van der Waals attractive force and substantially extends along the same direction.

10. The method of claim 2 , wherein the carbon nanotube structure comprises two carbon nanotube films, and an angle between the plurality of first carbon nanotubes in the two carbon nanotube films ranges from about 0 degree to about 90 degrees.

11. The method of claim 2 , wherein the plurality of first carbon nanotubes is substantially parallel to the substrate surface.

12. The method of claim 2 , wherein a plurality of gaps is defined by the plurality of first carbon nanotubes, and the monomer solution passes through the plurality of gaps and arrive at the substrate surface during disposing the monomer solution.

13. The method of claim 2 , wherein the substrate is a silicon wafer, the monomer is poly(amic acid), and the polymer is polyimide.

14. The method of claim 2 , wherein the disposing the monomer solution comprises placing the carbon nanotube structure and the substrate in a container having an opening and injecting the monomer solution into the container from the opening.

15. The method of claim 2 , wherein disposing the monomer solution to the carbon nanotube structure comprises:
locating two composite structures on a base and spacing the two composite structures apart from each other;
forming a mold having an opening, by using the substrates of the two composite structures and the base, wherein the carbon nanotube structures of the two composite structures are opposite to each other and inside of the mold.

16. The method of claim 7 , wherein the carbon nanotube composite structure further comprises a plurality of third carbon nanotubes entirely enclosed by the polymer.

17. The method of claim 15 , wherein the step of disposing the monomer solution to the carbon nanotube structure comprises injecting the monomer solution into the mold from the opening.

Assignees

• Univ Tsinghua
• Hon Hai Prec Ind Co Ltd

Inventors

• Ning Wen
• Liu Peng
• Jiang Kai-Li
• Fan Shou-Shan

Classifications

• H01L51/56

  Electricity · mapped topic

• H01L51/5072 Primary

  Electricity · mapped topic

• H01L51/0024

  Electricity · mapped topic

• H01L51/0048

  Electricity · mapped topic

• H01L51/0003

  Electricity · mapped topic