Self-healing coatings for oil and gas applications

Patent metadata

Field	Value
Publication number	US-10316413-B2
Application number	US-201514829529-A
Country	US
Kind code	B2
Filing date	Aug 18, 2015
Priority date	Aug 18, 2015
Publication date	Jun 11, 2019
Grant date	Jun 11, 2019

Abstract

A coated article comprises a substrate and a self-healing coating disposed on a surface of the substrate, the self-healing coating comprising a metallic matrix; and a plurality of micro- or nano-sized particles dispersed in the metallic matrix; the micro- or nano-sized particles comprising an active agent disposed in a carrier comprising a micro- or nano-sized metallic container, a layered structure, a porous structure, or a combination comprising at least one of the foregoing.

First claim

What is claimed is:

1. A coated article comprising:
a substrate; and
a self-healing coating disposed on a surface of the substrate;
the self-healing coating comprising
a continuous metallic matrix formed from Ni, Cu, Ag, Au, Sn, Fe, In, W, Ti, Co, Al, Mg, Cr, Mo, or an alloy thereof, or a combination thereof; and
a plurality of micro- or nano-sized particles dispersed in the continuous metallic matrix;

the micro- or nano-sized particles having a core-shell structure comprising an active agent encapsulated in a micro- and nano-sized metallic container shell,
wherein the micro- or nano-sized metallic container and the continuous metallic matrix have at least one common metal; and
the micro- or nano-sized particles have a number average particle size of about 100 nm to about 100 microns; and
the micro- or nano-sized metallic container shell has a thickness of about 10 nanometers to about 50 nanometers.

2. The coated article of claim 1 , wherein the micro- or nano-sized metallic container comprises Fe, Zn, Ni, Cu, Ag, Au, W, Ti, Co, Al, Mg, Cr, Mo, alloys thereof, or a combination comprising at least one of the foregoing.

3. The coated article of claim 1 , wherein the active agent comprises a corrosion inhibitor, a scale inhibitor, or a combination comprising at least one of the foregoing.

4. The coated article of claim 3 , wherein the active agent comprises an inorganic corrosion inhibitor, an organic corrosion inhibitor comprising at least one of S, N, O, P, or a combination comprising at least one of the foregoing corrosion inhibitors.

5. The coated article of claim 3 , wherein the corrosion inhibitor comprises an amine, an imidazoline, a quaternary compound, an amide, a phosphate, a sulfur-containing compound, a vanadate, a molybdate, a tungstate, a chromate, a lanthanide, a niobate, a cerate, a borate, a polymeric corrosion inhibitor, or a combination comprising at least one of the foregoing.

6. The coated article of claim 1 , wherein the active agent is released from the micro- or nano-sized particles in response to a mechanical damage to the coating, a change of pH, temperature, pressure, radiation, or a combination comprising at least one of the foregoing.

7. The coated article of claim 1 , wherein the continuous metallic matrix comprises a nickel-based alloy or Ti-based alloy.

8. The coated article of claim 1 , wherein the self-healing coating further comprises carbon, boron, a carbide, a nitride, an oxide, a boride or a solid lubricant, or a combination comprising at least one of the foregoing.

9. The coated article of claim 1 , wherein the micro- or nano-sized particles are present in an amount of about 0.5 volume percent to about 40 volume percent based on the total volume of the self-healing coating.

10. The coated article of claim 1 , wherein the substrate comprises iron, magnesium, aluminum, titanium, manganese, cobalt, nickel, copper, molybdenum, tungsten, palladium, chromium, ruthenium, gold, silver, zinc, zirconium, vanadium, silicon, an alloy thereof, or a combination comprising at least one of the foregoing.

11. The coated article of claim 1 , wherein the self-healing coating has a thickness of about 0.1 micron to 10 mm.

12. The coated article of claim 1 , wherein the coated article is a downhole element.

13. The coated article of claim 1 , wherein the continuous metallic matrix comprises a Ni—P alloy, a Ni—B alloy, or a Ni—W alloy.

14. The coated article of claim 1 , wherein the active agent is an imidazoline corrosion inhibitor.

15. The coated article of claim 1 , wherein the self-healing coating is configured to provide temperature shielding or thermal conductance to carry heat away from the substrate so that the substrate does not experience a temperature near its thermal decomposition temperature.

16. The coated article of claim 1 , wherein the micro- or nano-sized particles are homogeneously dispersed in the continuous metallic matrix.

17. The coated article of claim 1 , wherein the micro- or nano-sized metallic container comprises Fe, Zn, Cu, Ag, Au, W, Ti, Co, Mg, Mo, alloys thereof, or a combination comprising at least one of the foregoing.

18. A coated article comprising:
a substrate comprising a metal or an alloy; and
a self-healing coating having a thickness of about 10 nm to about 5 mm disposed on a surface of the substrate;
the self-healing coating comprising
a continuous metallic matrix comprising a nickel-based alloy, a Ti-based alloy, or an Al-based alloy;
about 5% to about 30% by volume of the coating a plurality of micro- or nano-sized particles dispersed in the continuous metallic matrix;

the micro- or nano-sized particles having a core-shell structure comprising an active agent encapsulated in a micro- or nano-sized metallic container shell, the micro- or nano-sized particles having a number average particle size of about 100 nm to about 100 microns, the active agent comprising a corrosion inhibitor, a scale inhibitor, or a combination comprising at least one of the foregoing, and the metallic container shell having a thickness of about 10 nanometers to about 50 nanometers,
wherein the micro- or nano-sized metallic container and the continuous metallic matrix have at least one common metal.

19. The coated article of claim 18 , wherein the corrosion inhibitor comprises an amine, an imidazoline, a quaternary compound, an amide, a phosphate, a sulfur-containing compound, a vanadate, a molybdate, a tungstate, a chromate, a lanthanide, a niobate, a cerate, a borate, a polymeric corrosion inhibitor, or a combination comprising at least one of the foregoing.

20. The coated article of claim 18 , wherein the continuous metallic matrix comprises a Ni—P alloy, a Ni—B alloy, or a Ni—W alloy.

21. A method of manufacturing the coated article of claim 1 , the method comprising:
depositing on the surface of the substrate the self-healing coating comprising the continuous metallic matrix formed from Ni, Cu, Ag, Au, Sn, Fe, In, W, Ti, Co, Al, Mg, Cr, Mo, or an alloy thereof, or a combination thereof; and the plurality of micro- or nano-sized particles dispersed in the continuous metallic matrix; the micro- or nano-sized particles having the core-shell structure comprising the encapsulated in the micro- or nano-sized metallic container shell, the micro- or nano-sized metallic container and the continuous metallic matrix having at least one common metal; the micro- or nano-sized particles having a number average particle size of about 100 nm to about 100 microns; and the micro- or nano-sized metallic container shell having a thickness of about 10 nanometers to about 50 nanometers,
wherein the depositing comprises electroplating, electrolessly depositing, thermal spraying, or a combination comprising at least one of the foregoing.

22. The method of claim 21 , wherein the continuous metallic matrix comprises a nickel-based alloy, a Ti-based alloy, or an Al-based alloy; and the active agent comprises a corrosion inhibitor, a scale inhibitor, or a combination comprising at least one of the foregoing.

Assignees

• Chilukuri Anusha
• Murugesan Sankaran
• Monteiro Othon
• Baker Hughes A Ge Co Llc

Inventors

• Chilukuri Anusha
• Murugesan Sankaran
• Monteiro Othon

Classifications

• C09D5/082 Primary

  characterised by the anti-corrosive pigment · CPC title

• C25D15/00

  Electrolytic or electrophoretic production of coatings containing embedded materials, e.g. particles, whiskers, wires · CPC title

• C23C18/1662

  Use of incorporated material in the solution or dispersion, e.g. particles, whiskers, wires · CPC title

• C08K9/10

  Encapsulated ingredients · CPC title

• C09D7/69 Primary

  Particle size larger than 1000 nm · CPC title