Method for purifying metallic sodium

Patent metadata

Field	Value
Publication number	US-10316390-B2
Application number	US-201615564332-A
Country	US
Kind code	B2
Filing date	Jan 29, 2016
Priority date	Jan 29, 2016
Publication date	Jun 11, 2019
Grant date	Jun 11, 2019

Abstract

It is preferable that metallic sodium to be loaded to an engine valve used for an internal combustion engine such as automobile engine have high purity. However, conventionally, an organic solvent remaining in micropores on a surface of the metallic sodium have been hardly attracted attention. Provided is a method for purifying metallic sodium including steps of placing metallic sodium containing organic solvent in the micropores thereof in a melting tank which is sealed, and heating the melting tank under reduced pressure to vaporize and remove the organic solvent coating the metallic sodium.

First claim

The invention claimed is:

1. A method for purifying metallic sodium coated by a first organic solvent, the method comprising steps of:
placing the metallic sodium in a melting tank which is sealed; and
heating the melting tank under reduced pressure to vaporize and remove the first organic solvent coating the metallic sodium,
wherein the first organic solvent which is vaporized is introduced to a solvent trap filled with a second organic solvent and is caught in the second organic solvent.

2. A method for purifying metallic sodium according to claim 1 ,
wherein a sodium oxide layer covering a surface of melted metallic sodium in the melting tank is physically removed, the sodium oxide layer being formed of a sodium oxide formed by oxidation on the metallic sodium.

3. A method for purifying metallic sodium according to claim 2 , wherein a cold trap for removing sodium oxide formed by oxidation of the metallic sodium is installed downward of the melting tank.

4. A method for purifying metallic sodium according to claim 1 , further comprising a step of breaking at least a part of a sodium oxide layer which is covering the surface of the melted metallic sodium in the melting tank, the sodium oxide layer being formed of a sodium oxide formed as a result of oxidation of the metallic sodium, and the sodium oxide layer being broken by applying force thereto.

5. A method for purifying metallic sodium according to claim 1 , wherein a cold trap for removing sodium oxide formed by oxidation of the metallic sodium is installed downward of the melting tank.

Assignees

• Nittan Valva
• Sukegawa Elec

Inventors

• Uchida Shigeru
• Onose Ryo
• Homma Koichi
• Miura Kuniaki
• HANAWA Masashige

Classifications

• C22B9/006

  with use of an inert protective material including the use of an inert gas · CPC title

• C22B5/16

  with volatilisation or condensation of the metal being produced · CPC title

• B01D8/00

  Cold traps; Cold baffles (pumps for evacuating by condensing or freezing F04B37/08) · CPC title

• B01D2257/70

  Organic compounds not provided for in groups B01D2257/00 - B01D2257/602 · CPC title

• C22B9/02

  Refining by liquating, filtering, centrifuging, distilling, or supersonic wave action {including acoustic waves; (C22B9/003, C22B9/006, C22B9/05, C22B9/22 take precedence)} · CPC title