Thermally releasable adhesive member and display apparatus including the same

Patent metadata

Field	Value
Publication number	US-10316219-B2
Application number	US-201715647259-A
Country	US
Kind code	B2
Filing date	Jul 12, 2017
Priority date	Dec 2, 2016
Publication date	Jun 11, 2019
Grant date	Jun 11, 2019

Abstract

A thermally releasable adhesive member including a base resin and microcapsules dispersed and disposed in the base resin. The microcapsule includes a core part, a shell part wrapping the core part, and an organic solvent disposed in the core part, and an average diameter of the microcapsules is in a range from about 50 nm to about 500 nm. The adhesive member may maintain high optical transmittance and may be easily detached at a high temperature.

First claim

What is claimed is:

1. A thermally releasable adhesive member, comprising:
a base resin; and
microcapsules dispersed and disposed in the base resin,
wherein:
each microcapsule comprises:
a core part;
a shell part wrapping the core part; and
an organic solvent disposed in the core part;

an average diameter of the microcapsules is in a range from 50 nm to 500 nm; and
a transmittance in a wavelength range of 400 nm to 800 nm is greater than or equal to 90%.

2. The thermally releasable adhesive member of claim 1 , wherein an absolute value of refractive index difference of the base resin and the microcapsule is less than or equal to 0.1.

3. The thermally releasable adhesive member of claim 1 , wherein a haze value is less than or equal to 0.1%.

4. The thermally releasable adhesive member of claim 1 , wherein a vaporization temperature of the organic solvent is in a range from about 90° C. to about 110° C.

5. The thermally releasable adhesive member of claim 4 , wherein the organic solvent is leaked out from the microcapsule at a temperature higher than the vaporization temperature thereof.

6. The thermally releasable adhesive member of claim 4 , wherein the thermally releasable adhesive member has a first adhesion strength at room temperature and a second adhesion strength at the vaporization temperature, and a relation of “second adhesion strength<0.9×(first adhesion strength)” is satisfied.

7. The thermally releasable adhesive member of claim 1 , wherein the organic solvent has a solubility with respect to water that is less than or equal to 1.0 at room temperature.

8. The thermally releasable adhesive member of claim 1 , wherein the organic solvent comprises at least one selected from methylcyclohexane, cyclohexane, cyclopentane, isooctane, tert-butyl acetate, heptene or heptane.

9. The thermally releasable adhesive member of claim 1 , wherein an amount ratio of the microcapsules is in a range from 0.01 wt % to 20 wt % on the basis of a total weight of the base resin and the microcapsules.

10. The thermally releasable adhesive member of claim 1 , wherein the thermally releasable adhesive member is a double-sided adhesive sheet comprising a first side and an opposite second side, and
a dispersion density of the microcapsules decreases from the first side to the second side.

11. The thermally releasable adhesive member of claim 1 , wherein the thermally releasable adhesive member comprises:
a first adhesive part in which the microcapsules are dispersed with a first density;
a second adhesive part in which the microcapsules are dispersed with a second density; and
a third adhesive part disposed between the first adhesive part and the second adhesive part,
wherein:
the microcapsules in the third adhesive part are disposed with a third density; and
the third density is less than the first density or the second density.

12. The thermally releasable adhesive member of claim 1 , wherein the base resin comprises at least one of an acryl-based resin, a silicone-based resin, an urethane-based resin, an epoxy-based resin, a rubber-based resin, or a polyester-based resin.

13. The thermally releasable adhesive member of claim 1 , wherein the core part comprises at least one selected from poly(2-ethylhexylacrylate), polybutyl acrylate, polyvinyl acetate, polymethyl methacrylate, polyethyl acrylate, polymethyl acrylate, polybenzyl acrylate, polyphenoxyethyl acrylate, polyacrylic acid, polyhydroxyethyl methacrylate, polyglycidyl methacrylate, or polyacetoacetoxyethyl methacrylate.

14. The thermally releasable adhesive member of claim 1 , wherein the shell part comprises at least one selected from polyethyleneamine, polyallylamine, polyvinylamine, polydimethylaminoethyl methacrylate, poly diallyldimethylammonium chloride, gelatin, bovine serum albumin, casein, or chitosan.

15. A thermally releasable adhesive member, comprising:
a base resin; and
microcapsules dispersed and disposed in the base resin,
wherein:
each microcapsule comprises:
a core part;
a shell part wrapping the core part; and
an organic solvent disposed in the core part;

an average diameter of the microcapsules is in a range from 50 nm to 500 nm; and
the microcapsule is an amphiphilic particle in which the core part is hydrophobic and the shell part is hydrophilic.

16. A display apparatus comprising:
a display panel;
a window member disposed on the display panel; and
a thermally releasable adhesive member disposed between the display panel and the window member,
wherein:
the thermally releasable adhesive member comprises a base resin and microcapsules dispersed and disposed in the base resin;
the microcapsule comprises:
a core part;
a shell part wrapping the core part; and
an organic solvent disposed in the core part;

an average diameter of the microcapsules is in a range from 50 nm to 500 nm; and
a transmittance in a wavelength range of 400 nm to 800 nm is greater than or equal to 90%.

17. The display apparatus of claim 16 , wherein a vaporization temperature of the organic solvent is in a range from 90° C. to 110° C.

18. The display apparatus of claim 17 ,
the thermally releasable adhesive member comprises a first side adjacent to the window member; and
a second side opposite to the first side and adjacent to the display panel,
wherein at least one of the first side or the second side has a first adhesion strength at room temperature and at least one of the first side or the second side has a second adhesion strength at the vaporization temperature in the thermally releasable adhesive member, and
wherein a relation of “second adhesion strength<0.9×(first adhesion strength)” is satisfied.

19. The display apparatus of claim 16 , further comprising an optically clear adhesive member which comprises the base resin but not comprises the microcapsule,
wherein the optically clear adhesive member is disposed between the display panel and the thermally releasable adhesive member, or between the window member and the thermally releasable adhesive member.

Assignees

• Samsung Display Co Ltd
• Myongji Univ Industry And Academia Cooperation Foundation

Inventors

• Ahn Byungwook
• Youk Kikyung
• Jung Sukwon
• Hwang Jeongho
• Park Jongdeok
• Lee Seungchan
• Son Intae
• Lee Junhyup

Classifications

• C09J2205/302

  Chemistry & Metallurgy · mapped topic

• C09J2433/00

  Presence of (meth)acrylic polymer · CPC title

• C09J2479/02

  polyamine · CPC title

• B32B7/12

  using interposed adhesives or interposed materials with bonding properties · CPC title

• B32B27/06

  as the main or only constituent of a layer, {which is} next to another layer of {the same or of} a {different material (next to a layer of a particular substance B32B9/045; next to a bituminous or tarry layer B32B11/046; next to a water setting substance layer B32B13/12; next to a metal layer B32B15/08; next to a glass layer B32B17/10; next to a layer formed of natural mineral fibres or particles B32B19/045; next to a wood layer B32B21/08; next to a cellulosic plastic layer B32B23/08; next to a natural or synthetic rubber layer B32B25/08)} · CPC title