Separation method and separation process system for recovering ethylene

Patent metadata

Field	Value
Publication number	US-10315972-B2
Application number	US-201615321224-A
Country	US
Kind code	B2
Filing date	Apr 28, 2016
Priority date	Jun 9, 2015
Publication date	Jun 11, 2019
Grant date	Jun 11, 2019

Abstract

The present invention relates to a separation method and a separation process system for easily recovering ethanol from an ethanol oligomerization reactant containing unreacted ethanol. A separation method according to the present invention may easily reflux ethylene while reducing or excluding the use of a reflux system which uses an expensive cooling medium, and the like, and thus may improve the economics while increasing separation efficiency.

First claim

The invention claimed is:

1. A separation method for recovering ethylene from an ethylene oligomerization reactant, the method comprising:
1) cooling the ethylene oligomerization reactant to produce a cooled reactant;
2) flashing the cooled reactant in a flashing column thereby separating the cooled reactant into a first top fraction comprising ethylene and a first bottom fraction;
3) introducing at least a portion of the first bottom fraction into a condenser, and a remaining portion of the first bottom fraction into a distillation column, and recovering a second top fraction comprising ethylene from the top of the distillation column and a second bottom fraction from the bottom of the distillation column; and
4) condensing the second top fraction in a condenser such that a temperature of the second top fraction is decreased,
wherein the condensing is performed through a heat exchange using a temperature difference between the at least a portion of the first bottom fraction introduced into the condenser and the second top fraction, wherein a temperature of the at least a portion of the first bottom fraction prior to being introduced into the heat exchange is −28° C. to 7° C., and wherein the temperature difference between the at least a portion of the first bottom fraction and the second top fraction prior to being introduced into the heat exchange is 5° C. to 50° C.

2. The method of claim 1 , wherein the ethylene oligomerization reactant of the step 1) has a temperature range of 50° C. to 100° C. and a pressure of at least 60 bar.

3. The method of claim 1 , wherein the cooling is performed using cooling water such that the ethylene oligomerization reactant has a temperature range of 30° C. to 50° C. and a pressure of 55 to 60 bar.

4. The method of claim 1 , wherein the flashing of the step 2) is performed such that a temperature of the first bottom fraction is 5° C. to 50° C. lower than a temperature of the second top fraction.

5. The method of claim 1 , wherein the flashing of the step 2) is performed as thermally insulated flashing such that the first top fraction and the first bottom fraction produced from the cooled reactant have a pressure range of 5 to 20 bar.

6. The method of claim 1 , wherein the first top fraction is circulated and reused in an ethylene oligomerization reaction.

7. The method of claim 1 , wherein the flashing of the step 2) includes a high pressure flashing in order to produce a third top fraction and a third bottom fraction from the cooled reactant, which is followed by a thermally insulated flashing of the third bottom fraction in order to produce the first top fraction and the first bottom fraction which have a pressure range of 5 to 20 bar, wherein the third top fraction and the third bottom fraction having a higher pressure than the first top fraction and the first bottom fraction respectively.

8. The method of claim 7 , wherein the third top fraction is circulated and reused in an ethylene oligomerization reaction.

9. The method of claim 1 , wherein after the heat exchange, the at least a portion of the first bottom fraction is circulated and then introduced into the distillation column with the first bottom fraction of the step 3).

10. The method of claim 1 , wherein after the heat exchange, obtaining a condensed second top fraction, and reintroducing at least a portion of the condensed second top fraction to the top of the distillation column.

11. The method of claim 1 , wherein the second top fraction is circulated and reused in an ethylene oligomerization reaction.

12. The method of claim 1 , wherein the ethylene oligomerization reactant is produced through an ethylene oligomerization reaction, the ethylene oligomerization reaction being an ethylene trimerization reaction or an ethylene tetramerization reaction.

13. The method of claim 1 , wherein the ethylene oligomerization reactant is a multiphase multicomponent hydrocarbon containing ethylene oligomerization products, polymer products, and unreacted ethylene.

14. The method of claim 1 , further comprising a step for filtering the first bottom fraction before the step 3).

Assignees

• Lg Chemical Ltd

Inventors

• Jeong Hoi In
• Lee Jong Ku
• Lee Jeong Seok
• Kim Mi Kyung

Classifications

• C07C7/04

  by distillation · CPC title

• C07C7/005 Primary

  Processes comprising at least two steps in series · CPC title

• C07C11/04 Primary

  Ethene · CPC title

• C07C2/06

  of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond · CPC title

• B01D3/002

  by continuous methods · CPC title