Sacrificial fibers to create channels in a composite material

Patent metadata

Field	Value
Publication number	US-10315960-B2
Application number	US-201615285589-A
Country	US
Kind code	B2
Filing date	Oct 5, 2016
Priority date	Sep 2, 2014
Publication date	Jun 11, 2019
Grant date	Jun 11, 2019

Abstract

A carbon fiber preform that includes a plurality of fibrous layers stacked together and a plurality of sacrificial fibers that bind the plurality of fibrous layers together, where at least one fibrous layer of the plurality of fibrous layers includes a plurality of carbon fibers or carbon fiber precursor fibers.

First claim

The invention claimed is:

1. A carbon fiber preform comprising:
a plurality of fibrous layers stacked together, wherein at least one fibrous layer of the plurality of fibrous layers comprises a plurality of carbon fibers or carbon fiber precursor fibers and a first plurality of sacrificial fibers mixed with the plurality of carbon fibers or carbon fiber precursor fibers; and
a second plurality of sacrificial fibers that bind the plurality of fibrous layers together,
wherein the first plurality of sacrificial fibers is interwoven with the plurality of carbon fibers or carbon fiber precursor fibers, and
wherein the plurality of fibrous layers further comprises a non-woven fibrous layer comprising a mixture of:
a third plurality of sacrificial fibers, and
a second plurality of carbon fibers or carbon fiber precursor fibers.

2. The carbon fiber preform of claim 1 , wherein the first and second plurality of sacrificial fibers comprise at least one of a polymeric fiber, a thermoplastic material, or an organic material.

3. The carbon fiber preform of claim 2 , wherein the first and second plurality of sacrificial fibers are configured to be substantially removed from the carbon fiber preform upon heating the carbon fiber preform between about 170° C. and about 400° C.

4. The carbon fiber preform of claim 1 , wherein the plurality of carbon fibers or carbon fiber precursor fibers comprises at least one of polyacrylonitrile (PAN) fibers or pitch fibers.

5. A method of forming a carbon fiber preform, the method comprising:
stacking plurality of fibrous layers together, wherein at least one fibrous layer comprises a plurality of carbon fibers or carbon fiber precursor fibers and a first plurality of sacrificial fibers mixed with the plurality of carbon fibers or carbon fiber precursor fibers;
mechanically binding the fibrous layers by forming a second plurality of sacrificial fibers that bind the plurality of fibrous layers together
wherein the first plurality of sacrificial fibers is interwoven with the plurality of carbon fibers or carbon fiber precursor fibers, and
wherein the plurality of fibrous layers further comprises a non-woven fibrous layer comprising a mixture of:
a third plurality of sacrificial fibers, and

a second plurality of carbon fibers or carbon fiber precursor fibers.

6. The method of claim 5 , further comprising, after mechanically binding plurality of fibrous layers, heating the plurality of fibrous layers to a temperature between about 170° C. and about 400° C. to substantially remove the first and second plurality of sacrificial fibers from the plurality of fibrous layers and form a plurality of channels in the carbon fiber preform in place of the sacrificial fibers.

7. The method of claim 6 , further comprising infiltrating at least some of the plurality of channels in the carbon fiber preform with a densifying agent.

8. The method of claim 7 , wherein infiltrating the at least some of the plurality of channels in the carbon fiber preform with the densifying agent comprises using at least one of chemical vapor deposition (CVD), chemical vapor infiltration (CVI), vacuum pressure infiltration (VPI), high pressure impregnation/carbonization (PIC), or resin transfer molding (RTM) to infiltrate the densifying agent.

9. The method of claim 5 , wherein mechanically binding the plurality of fibrous layers comprises needling at least some of the first plurality of sacrificial fibers to form at least some of the second plurality of sacrificial fibers.

10. The method of claim 5 , further comprising forming a woven fibrous layer comprising weaving the first plurality of sacrificial fibers with the plurality of carbon fibers or carbon fiber precursor fibers, and wherein stacking plurality of fibrous layers together comprises stacking the woven fibrous layer as part of the plurality of fibrous layers.

11. The method of claim 5 , wherein the plurality of carbon fibers or carbon fiber precursor fibers of the at least one fibrous layer comprises at least one of polyacrylonitrile (PAN) fibers or pitch fibers, the method further comprising:
heating plurality of fibrous layers to substantially remove the first and second plurality of sacrificial fibers from the plurality of fibrous layers and form a plurality of channels in the carbon fiber preform in place of the sacrificial fibers and to carbonize the at least one of PAN fibers or pitch fibers.

12. A carbon fiber preform comprising:
a plurality of fibrous layers stacked and needled together, wherein the plurality of fibrous layers comprises at least one woven fibrous layer comprising a plurality of carbon fibers or carbon fiber precursor fibers interwoven with a plurality of sacrificial fibers, and
wherein the plurality of fibrous layers comprises at least one non-woven fibrous layer stacked and needled to the at least one woven fibrous layer.

13. The carbon fiber preform of claim 12 , further comprising:
a plurality of needled fibers that bind the plurality of fibrous layers together, wherein at least some of the plurality of needled fibers include sacrificial fibers.

14. The carbon fiber preform of claim 13 , wherein the sacrificial fibers of the plurality of needled fibers and the at least one woven fibrous layer are configured to be substantially removed from the carbon fiber preform upon heating the carbon fiber preform between about 170° C. and about 400° C.

15. The carbon fiber preform of claim 13 , wherein the sacrificial fibers of the plurality of needled fibers and the woven fibrous layer comprise at least one of a polymeric material, a thermoplastic material, hemp fibers, grass, wood, or cotton.

16. The carbon fiber preform of claim 12 , wherein the at least one non-woven fibrous layer comprises carbon fibers or carbon fiber precursor fibers mixed with sacrificial fibers.

17. A carbon fiber reform comprising:
a plurality of fibrous layers stacked together, wherein at least one fibrous layer of the plurality of fibrous layers comprises a plurality of carbon fibers or carbon fiber precursor fibers and a first plurality of sacrificial fibers mixed with the plurality of carbon fibers or carbon fiber precursor fibers; and
a second plurality of sacrificial fibers that bind the plurality of fibrous layers together,
wherein the at least one fibrous layer comprises at least one tow of fibers, wherein the tow comprises the first plurality of sacrificial fibers mixed with the plurality of carbon fibers or carbon fiber precursor fibers.

Assignees

• Honeywell Int Inc

Inventors

• La Forest Mark L
• Fryska Slawomir T
• Wright David M

Classifications

• C04B35/62886

  by wet chemical techniques · CPC title

• C04B2235/48

  Organic compounds becoming part of a ceramic after heat treatment, e.g. carbonising phenol resins · CPC title

• C04B35/195

  Alkaline earth aluminosilicates, e.g. cordierite {or anorthite} · CPC title

• C04B35/62873

  Carbon · CPC title

• D06M10/10

  Macromolecular compounds · CPC title