Manufactured natural pozzolan, improved manufactured natural pozzolan-based cement and method of making and using same
US-10155695-B2 · Dec 18, 2018 · US
US10315953B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10315953-B2 |
| Application number | US-201615549344-A |
| Country | US |
| Kind code | B2 |
| Filing date | Feb 7, 2016 |
| Priority date | Feb 8, 2015 |
| Publication date | Jun 11, 2019 |
| Grant date | Jun 11, 2019 |
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Bismuth oxyhalide-added building materials are disclosed. The building material is a binder-containing building material, which sets and harden when mixed with water, such as gypsum and cement-based building material. Methods for applying bismuth oxyhalide—comprising coatings onto surfaces of building materials, to protect them against pollutants, are described.
Opening claim text (preview).
The invention claimed is: 1. Bismuth oxyhalide-added gypsum, wherein the bismuth oxyhalide is selected from the group consisting of BiOCl y Br 1-y [0.6≤y≤0.95]; Bi (0) doped-BiOCl; Bi (0) doped-BiOBr; and Bi (0) doped-BiOCl y Br 1-y [0.6≤y≤0.95]. 2. Bismuth oxyhalide-added gypsum according to claim 1 , which is bismuth oxyhalide-coated gypsum, wherein the bismuth oxyhalide-coated gypsum has bismuth oxyhalide particles that are located in a bismuth oxyhalide-containing surface layer deposited on a gypsum-made base, with said gypsum-made base being essentially free of bismuth oxyhalide particles. 3. Bismuth oxyhalide-added gypsum according to claim 2 , wherein the thickness of the bismuth oxyhalide-containing surface layer is from 4 to 100 μm. 4. Bismuth oxyhalide-added gypsum according to claim 1 , wherein the bismuth oxyhalide is selected from the group consisting of BiOCl y Br 1-y [0.6≤y≤0.95] and Bi (0) doped-BiOCl y Br 1-y [0.6≤y≤0.95]. 5. Bismuth oxyhalide-added gypsum according to claim 4 , wherein the bismuth oxyhalide is BiOCl y Br 1-y [0.6≤y≤0.95]. 6. Bismuth oxyhalide-added gypsum according to claim 5 , wherein the bismuth oxyhalide is BiOCl y Br 1-y [0.75≤y≤0.90]. 7. Bismuth oxyhalide-added gypsum according to claim 6 , wherein the BiOCl y Br 1-y is BiOCl 0.8±δ Br 0.2±δ (0.01≤δ≤0.05). 8. A method for preparing bismuth oxyhalide-coated gypsum, comprising mixing plaster of Paris powder (CaSO 4 .0.5H 2 O) and water, allowing a so-formed mass to set and harden partially, applying onto the surface of the mass an aqueous suspension of bismuth oxyhalide microspheres selected from the group consisting of BiOCl y Br 1-y [0.6≤y≤0.95]; Bi (0) doped-BiOCl; Bi (0) doped-BiOBr; and Bi (0) doped-BiOCl y Br 1-y [0.6≤y≤0.95], and allowing the mass to dry and solidify.
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as one or more layers of a layered structure · CPC title
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