Gas separation method

Patent metadata

Field	Value
Publication number	US-10315156-B2
Application number	US-201816130463-A
Country	US
Kind code	B2
Filing date	Sep 13, 2018
Priority date	Sep 15, 2017
Publication date	Jun 11, 2019
Grant date	Jun 11, 2019

Abstract

Provided is a method for separating a specific gas from a raw gas using a gas separation membrane module that includes a gas separation membrane element enclosed in a housing. The element includes a gas separation membrane including a hydrophilic resin composition layer. The method includes: preparing the module; increasing pressure in an interior of the module; increasing a temperature in the interior; and feeding a raw gas to the interior. The layer of the module prepared is adjusted to contain moisture, and a moisture content thereof is an amount that allows an equilibrium relative humidity at a temperature of 23° C. of a gas phase portion in the housing to be 10% RH or more. The raw gas feeding step is performed after the preparation step. The pressure increase step and the temperature increase step are performed after the preparation step and before the raw gas feeding step.

First claim

What is claimed is:

1. A method for separating, from a raw gas containing a specific gas, the specific gas using a gas separation membrane module,
the gas separation membrane module including a housing and a gas separation membrane element enclosed in the housing,
the gas separation membrane element including a gas separation membrane including a hydrophilic resin composition layer for selectively allowing for permeation of the specific gas,
the method comprising the steps of:
preparing the gas separation membrane module;
increasing a pressure in an interior of the gas separation membrane module;
increasing a temperature in the interior of the gas separation membrane module; and
feeding the raw gas to the interior of the gas separation membrane module,
wherein
the hydrophilic resin composition layer included in the gas separation membrane module prepared in the step of preparing the gas separation membrane module is adjusted to contain moisture,
a moisture content of the hydrophilic resin composition layer is an amount that allows an equilibrium relative humidity at a temperature of 23° C. of a gas phase portion in the housing to be greater than or equal to 10% RH,
the step of feeding the raw gas is performed after the step of preparing the gas separation membrane module, and
the step of increasing a pressure and the step of increasing a temperature are performed after the step of preparing the gas separation membrane module and before the step of feeding the raw gas.

2. The method according to claim 1 , wherein the step of preparing the gas separation membrane module includes at least one of the steps of:
enclosing the gas separation membrane element including the gas separation membrane including the hydrophilic resin composition layer containing moisture in the housing; and
adding moisture to the hydrophilic resin composition layer of the gas separation membrane element enclosed in the housing.

3. The method according to claim 2 , wherein the step of adding moisture to the hydrophilic resin composition layer of the gas separation membrane element enclosed in the housing includes a step of distributing a humidified gas in the interior of the gas separation membrane module including the gas separation membrane element enclosed in the housing.

4. The method according to claim 1 , wherein the step of increasing a temperature is performed after the step of increasing a pressure.

5. The method according to claim 1 , wherein in the step of increasing a pressure, an inert gas is fed to increase the pressure in the interior of the gas separation membrane module.

6. The method according to claim 5 , wherein the inert gas has a water partial pressure lower than a maximum saturation water vapor pressure in the step of increasing a pressure.

7. The method according to claim 1 , wherein in the step of increasing a pressure, the pressure on a feed side in the interior of the gas separation membrane module is increased.

8. The method according to claim 1 , wherein the raw gas contains water vapor.

9. The method according to claim 8 , wherein in the step of increasing a temperature, the temperature in the interior of the gas separation membrane module is increased to a temperature higher than a dew point of the raw gas in the step of feeding the raw gas.

10. The method according to claim 1 , wherein the hydrophilic resin composition layer contains a hydrophilic resin and an acidic gas carrier capable of reversibly reacting with an acidic gas.

11. The method according to claim 1 , further comprising the steps of:
discharging a retentate gas that has not permeated through the gas separation membrane from the gas separation membrane module; and
purifying the retentate gas.

12. The method according to claim 11 , wherein in the step of purifying the retentate gas, the purifying is conducted by at least one method selected from the group consisting of an adsorption method, a physical absorption method, a chemical absorption method, a distillation method, and a cryogenic separation method.

Assignees

• Sumitomo Chemical Co

Inventors

• Kitaura Takenori
• Miyamoto Hisaaki
• Ota Yudai
• Nakasuji Takehiro

Classifications

• B01D53/228 Primary

  characterised by specific membranes · CPC title

• B01D53/22

  by diffusion (manufacturing semi-permeable membranes B01D67/00; form, structure or properties of semi-permeable membranes B01D69/00; material for semi-permeable membranes B01D71/00) · CPC title

• B01D69/142

  with "carriers" · CPC title

• B01D69/04

  Tubular membranes · CPC title

• B01D2257/504

  Carbon dioxide · CPC title