Multi-layered layer arrangement for a solid electrolyte

Patent metadata

Field	Value
Publication number	US-10312540-B2
Application number	US-201414892891-A
Country	US
Kind code	B2
Filing date	May 20, 2014
Priority date	May 21, 2013
Publication date	Jun 4, 2019
Grant date	Jun 4, 2019

Abstract

A cathode-electrolyte-anode unit for an electrochemical functional device, in particular a high-temperature fuel cell. The unit has a multi-layer solid-state electrolyte arranged between a porous anode and a porous cathode. The solid-state electrolyte is produced by a vapor deposition process and has a sandwich-type structure consisting of at least one first layer with a lower oxygen content, and at least one second layer with a higher oxygen content. The individual layers have substantially the same composition, with the exception of oxygen.

First claim

The invention claimed is:

1. A cathode-electrolyte-anode unit for an electrochemical functional device, the unit comprising:
a porous anode and a porous cathode;
a multi-layered solid electrolyte arranged between said porous anode and said porous cathode;
said solid electrolyte having characteristics of being formed of a layered structure of at least one first layer and at least one second layer;
said at least one second layer having a higher oxygen content than said at least one first layer, and said at least one first layer and said at least one second layer having the same composition except for oxygen;
said at least one first layer being a metallic PVD layer formed of a deposited mixture of metals converted beforehand, by way of a sputtering process, into gas phase; and
said at least one second layer being an oxide-ceramic PVD layer formed of the mixture of metals converted beforehand into the gas phase, or a gaseous mixture, with supply of oxygen or of an oxygen-containing gas as reactive gas or by using a sputtering target consisting of the metal oxide.

2. The cathode-electrolyte-anode unit according to claim 1 , configured for a high-temperature fuel cell.

3. The cathode-electrolyte-anode unit according to claim 1 , wherein said solid electrolyte comprises an alternating layer sequence wherein said at least one first layer with lower oxygen content and said at least one second layer with higher oxygen content are arranged alternately one above another.

4. The cathode-electrolyte-anode unit according to claim 3 , wherein said solid electrolyte is composed of an alternating layer sequence of a total of at least two said first layers with lower oxygen content and at least two said second layers with higher oxygen content.

5. The cathode-electrolyte-anode unit according to claim 1 , wherein said one or more first layers with lower oxygen content and said one or more second layers with higher oxygen content form different crystal structures.

6. The cathode-electrolyte-anode unit according to claim 1 , wherein said one or more first layers with lower oxygen content has or have in each case a layer thickness of between 200 and 800 nm.

7. The cathode-electrolyte-anode unit according to claim 6 , wherein the layer thickness lies between 300 and 500 nm.

8. The cathode-electrolyte-anode unit according to claim 1 , wherein each of said one or more second layers with higher oxygen content has or have in each case a layer thickness of between 200 and 800 nm.

9. The cathode-electrolyte-anode unit according to claim 1 , wherein a layer thickness of said solid electrolyte is between 1 and 10 μm.

10. The cathode-electrolyte-anode unit according to claim 1 in combination with a metal-substrate-supported fuel cell, an anode-supported fuel cell, or a cathode-supported fuel cell.

Assignees

• Plansee Composite Mat Gmbh
• Forschungszentrum Juelich Gmbh
• Fraunhofer Ges Forschung

Inventors

• Haydn Markus
• Ruettinger Matthias
• Franco Thomas
• Uhlenbruck Sven
• Jung Thomas
• Ortner Kai

Classifications

• H01M8/1004 Primary

  characterised by membrane-electrode assemblies [MEA] (H01M8/12 takes precedence) · CPC title

• H01M8/1246

  the electrolyte consisting of oxides · CPC title

• H01M2300/0074

  Ion conductive at high temperature · CPC title

• H01M2008/1293

  Fuel cells with solid oxide electrolytes · CPC title

• H01M8/1253

  the electrolyte containing zirconium oxide · CPC title