X-ray detector

Patent metadata

Field	Value
Publication number	US-10312292-B2
Application number	US-201615757994-A
Country	US
Kind code	B2
Filing date	Sep 7, 2016
Priority date	Sep 7, 2015
Publication date	Jun 4, 2019
Grant date	Jun 4, 2019

Abstract

Disclosed is a direct-conversion-type X-ray detector, including a first electrode on a substrate, a semiconductor structure including a photoconductor using a perovskite material on the first electrode, and a second electrode on the semiconductor structure.

First claim

The invention claimed is:

1. An X-ray detector, comprising:
a first electrode on a substrate;
a semiconductor structure including a photoconductor using a perovskite material on the first electrode; and
a second electrode on the semiconductor structure,
wherein the substrate is a CMOS substrate or a plastic substrate, and an adhesive polymer formed between the first electrode and the photoconductor is further included.

2. The X-ray detector of claim 1 , wherein the perovskite material is represented by a chemical formula ABX3, A being Cs, methyl ammonium (CH 3 NH 3 ) or formamidinium (NH 2 CH═NH 2 ), B being Pb, Sn, Cu, Ni, Bi, Co, Fe, Mn, Cr, Cd, Ge, or Yb, and X being I x Br (1-x) , I x Cl (1-x) , or Br x Cl (1-x) (0.2≤x≤1, a real number).

3. The X-ray detector of claim 1 , wherein the semiconductor structure includes a hole transport layer and an electron transport layer, and the photoconductor is provided in a film form between the hole transport layer and the electron transport layer.

4. The X-ray detector of claim 3 , wherein the hole transport layer includes first and second hole transport layers.

5. The X-ray detector of claim 1 , wherein the semiconductor structure includes one of an electron transport layer and a hole transport layer and a photoconductor film having a type opposite thereto and configured such that the photoconductor is provided in a film form, or includes an electron transport layer and a hole transport layer, and when the semiconductor structure includes the electron transport layer and the hole transport layer, the photoconductor is provided in a form of particles inside one of the electron transport layer and the hole transport layer.

6. The X-ray detector of claim 1 , wherein the semiconductor structure includes a hole transport layer and an electron transport layer, with a photoconductor film having a P type disposed therebetween and configured such that the photoconductor is provided in a film form, or includes a hole transport layer and an electron transport layer, with an additional hole transport layer disposed therebetween and configured such that the photoconductor is provided in a form of particles therein.

7. The X-ray detector of claim 1 , wherein the adhesive polymer is PAP (polyacryloyl piperidine).

8. The X-ray detector of claim 1 , further comprising a sealing member configured to seal an entire stacking structure comprising the substrate, the first electrode, the semiconductor structure and the second electrode, or to seal an entire stacking structure comprising the substrate, the first electrode and the semiconductor structure.

9. The X-ray detector of claim 8 , wherein the sealing member is formed of any one or a mixture of at least two selected from among a polyethylene-based resin, a polypropylene-based resin, a cyclic polyolefin-based resin, a polystyrene-based resin, an acrylonitrile-styrene copolymer, an acrylonitrile-butadiene-styrene copolymer, a poly(vinyl chloride)-based resin, a fluorine-based resin, a poly(meth)acrylate-based resin, and a polycarbonate-based resin, or is formed of Parylene.

10. The X-ray detector of claim 1 , wherein a film of the photoconductor has a thickness of 200 μm˜800 μm when the X-ray detector is used for at least one of a dental CT sensor and a cephalo sensor, a thickness of 150 μm˜600 μm when the X-ray detector is used for a dental panorama sensor, a thickness of 100 μm˜450 μm when the X-ray detector is used for an intraoral (I/O) sensor, a thickness of 60 μm˜300 μm when the X-ray detector is used for a mammography sensor, and a thickness of 90 μm˜1000 μm when the X-ray detector is used for a medical fluoroscopy X-ray sensor.

11. The X-ray detector of claim 1 , wherein the semiconductor structure includes a photoconductor film using the perovskite material and a quantum dot material for converting incident X-rays into visible light.

12. The X-ray detector of claim 11 , wherein the quantum dot is a-Se, Cs, CdSe, CdS, PbO, or PbI 2 , and has a diameter of 1 nm˜100 nm.

13. The X-ray detector of claim 11 , wherein the quantum dot is provided in a form of being dispersed in the photoconductor film, or in a form of a film in contact with at least one of an upper surface and a lower surface of the photoconductor film.

14. The X-ray detector of claim 13 , wherein the semiconductor structure includes one of a hole transport layer and an electron transport layer, and one of the hole transport layer and the electron transport layer is disposed between one of the first and second electrodes and the photoconductor film configured such that the quantum dot is provided therein or thereon.

15. The X-ray detector of claim 13 , wherein the semiconductor structure includes a hole transport layer and an electron transport layer, the hole transport layer is disposed between one of the first and second electrodes and the photoconductor film configured such that the quantum dot is provided therein or thereon, and the electron transport layer is disposed between a remaining one of the first and second electrodes and the photoconductor film configured such that the quantum dot is provided therein or thereon.

16. The X-ray detector of claim 13 , wherein the film comprising the quantum dot has a thickness of 100 nm˜1000 μm.

Assignees

• Rayence Co Ltd
• Vatech Ewoo Holdings Co Ltd

Inventors

• Heo Sung Kyn
• Shin Dong Hui
• Kim Tae Woo
• Yun Min Seok

Classifications

• A61B6/502

  for diagnosis of breast, i.e. mammography · CPC title

• H01L51/426

  Electricity · mapped topic

• C09K11/661

  Chalcogenides · CPC title

• C09K11/664

  Halogenides (C09K11/661 takes precedence) · CPC title

• H01G9/2018

  characterised by the ionic charge transport species, e.g. redox shuttles · CPC title