Method for producing elemental rhodium

Patent metadata

Field	Value
Publication number	US-10308997-B2
Application number	US-201615555238-A
Country	US
Kind code	B2
Filing date	Feb 1, 2016
Priority date	Mar 5, 2015
Publication date	Jun 4, 2019
Grant date	Jun 4, 2019

Abstract

Method for producing elemental rhodium, comprising the steps of:
(1) providing an aqueous suspension of diethylene triammonium hexahalogenorhodate adjusted with hydrohalic acid to a pH value of −1 to +2; (2) adding a sufficient quantity of reducing agent for complete conversion of the diethylene triammonium hexahalogenorhodate to the suspension provided in step (1) and allowing the reaction to proceed until the formation of elemental rhodium is completed; and (3) separating the elemental rhodium formed in step (2) from the hydrohalic aqueous composition formed in step (2);

whereby halogen is bromine and/or chlorine.

First claim

The invention claimed is:

1. A method for producing elemental rhodium, comprising the steps of:
(1) providing an aqueous suspension of diethylene triammonium hexahalogenorhodate adjusted with a hydrohalic acid to a pH value of −1 to +2;
(2) adding a sufficient quantity of at least one reducing agent to the suspension provided in step (1) to form a hydrohalic aqueous composition and elemental rhodium; and
(3) separating the elemental rhodium formed in step (2) from the hydrohalic aqueous composition formed in step (2);
wherein the halogen of the diethylene triammonium hexahalogenorhodate is bromine and/or chlorine.

2. The method of claim 1 ,
wherein the pH value of the aqueous suspension provided in step (1) is in the range of −0.5 to +0.5.

3. The method of claim 1 ,
wherein the diethylene triammonium hexahalogenorhodate originates from a rhodium separation step of a precious metals refining process.

4. The method of claim 1 ,
wherein the diethylene triammonium hexahalogenorhodate is suspended in water and the hydrohalic acid is added until the pH value of the aqueous suspension is adjusted to within the range of −1 to +2.

5. The method of claim 1 ,
wherein the aqueous suspension has 5 to 40% by weight of diethylene triammonium hexahalogenorhodate.

6. The method of claim 1 ,
wherein the aqueous suspension is agitated during step (2).

7. The method of claim 1 ,
wherein the at least one reducing agent is a combination of reducing agents, and wherein the combination of reducing agents are used one after the other, at the same time or overlapping in time.

8. The method of claim 1 ,
wherein the at least one reducing agent is selected from the group consisting of hydrazine hydrazine hydrate, Sn(II) compounds, zinc, iron, aluminium, and tin.

9. The method of claim 1 ,
wherein iron powder is used as the reducing agent.

10. The method of claim 1 ,
wherein the pH value is maintained in the range of −1 to +2 during step (2).

11. The method of claim 1 ,
wherein the temperature of the reaction material is maintained in the range of 20 to 70° C. during step (2).

12. The method of claim 1 ,
wherein a hydrohalic filtrate is obtained during the separation of the elemental rhodium from the hydrohalic aqueous composition, and wherein the hydrohalic filtrate is used in a step (4) to precipitate Rh 3+ as diethylene triammonium hexahalogenorhodate.

13. The method of claim 12 ,
the at least one reducing agent or an oxidation product of the at least one reducing agent is removed from the hydrohalic filtrate before using it in step (4).

14. The method of claim 1 ,
wherein the diethylene triammonium hexahalogenorhodate is diethylene triammonium hexachlororhodate.

15. The method of claim 1 ,
wherein the diethylene triammonium hexahalogenorhodate is added to and suspended in the hydrohalic acid, the hydrohalic acid having a pH in the range of −1 to +2.

16. The method of claim 1 ,
wherein the hydrohalic acid is hydrobromic acid, hydrochloric acid, or a combination thereof.

17. The method of claim 1 ,
wherein the pH value is maintained in the range of −1 to +2 during step (2) by adding a hydrohalic acid.

18. The method of claim 17 ,
wherein the hydrohalic acid is hydrobromic acid, hydrochloric acid, or a combination thereof.

Assignees

• Heraeus Deutschland Gmbh & Co Kg

Inventors

• Stettner Martin
• Thiel Vasco
• Alameda Stefanie F
• Voβ Steffen

Classifications

• C22B11/00 Primary

  Obtaining noble metals · CPC title

• C22B3/44

  by chemical processes (treatment or purification of solutions by liquid-liquid extraction C22B3/26, by ion-exchange extraction C22B3/42) · CPC title

• C22B7/006

  Wet processes · CPC title

• C22B11/04 Primary

  by wet processes (extraction of metal compounds by leaching in organic solutions C22B3/16; treatment or purification of solutions by liquid-liquid extraction C22B3/26) · CPC title

• C22B11/06 Primary

  Chloridising · CPC title