Rubbery blend containing trans isoprene-butadiene copolymer

Patent metadata

Field	Value
Publication number	US-10308792-B2
Application number	US-201715687958-A
Country	US
Kind code	B2
Filing date	Aug 28, 2017
Priority date	Oct 8, 2013
Publication date	Jun 4, 2019
Grant date	Jun 4, 2019

Abstract

The subject invention is directed towards tire components comprising rubber compositions comprising (1) about 2 phr to about 45 phr of a trans-1,4-isoprene-butadiene copolymer which has about 4 weight percent to about 16 weight percent butadiene repeat units and from about 84 weight percent to about 96 weight percent isoprene repeat units, wherein the trans-1,4-isoprene-butadiene copolymer has a Mooney ML 1+4 viscosity which is within the range of about 35 to about 80; and (2) about 55 phr to about 98 phr of at least one other elastomer, preferably a diene based elastomer. The most preferred tire components are those which contain cord reinforcements and require adequate green strength to enhance the tire building and shaping process to maintain cord integrity in the final cured tire.

First claim

What is claimed is:

1. A rubber composition consisting of (1) 3 phr to about 30 phr of a trans-1,4-isoprene-butadiene copolymer containing 5 weight percent to 10 weight percent 1,3-butadiene repeat units and from 90 weight percent to about 95 weight percent isoprene repeat units, wherein the trans-1,4-isoprene-butadiene copolymer has a Mooney ML 1+4 viscosity at 100° C. which is within the range of 65 to 75, and wherein the trans-1,4-isoprene-butadiene copolymer has a melting point which is within the range of 30° C. to 65° C.; (2) 70 phr to 97 phr of at least one other elastomer selected from the group consisting of natural rubber, synthetic polyisoprene homopolymer rubber, polybutadiene rubber, styrene-butadiene rubber, styrene-isoprene rubber, and styrene-isoprene-butadiene rubber; (3) a reinforcing filler; (4) a processing oil; (5) a antioxidant; (6) optionally, an antiozonant, and (7) optionally, a tackifier resin; wherein the rubber composition is cured.

2. The rubber composition as specified in claim 1 wherein the other elastomer is comprised of repeat units which are derived from 1,3-butadene.

3. The rubber composition as specified in claim 1 wherein the other elastomer is natural rubber.

4. The rubber composition as specified in claim 1 wherein the rubber composition contains from 5 phr to 20 phr of the trans-1,4-isoprene-butadiene copolymer and from 80 phr to 95 phr of the other elastomer.

5. The rubber composition as specified in claim 1 wherein the reinforcing filler is carbon black.

6. The rubber composition as specified in claim 1 wherein the reinforcing filler is silica.

7. A tire which is comprised of a generally toroidal-shaped carcass with an outer circumferential tread, two spaced beads, at least one ply extending from bead to bead and sidewalls extending radially from and connecting said tread to said beads, wherein said circumferential tread is adapted to be ground-contacting, wherein the circumferential tread is comprised of the rubber composition specified in claim 1 .

8. A tire which is comprised of a generally toroidal-shaped carcass with an outer circumferential tread, two spaced beads, at least one ply extending from bead to bead and sidewalls extending radially from and connecting said tread to said beads, wherein said circumferential tread is adapted to be ground-contacting, wherein the sidewalls are comprised of the rubber composition specified in claim 1 .

9. The tire as specified in claim 8 wherein the tire is a non-pneumatic tire.

10. The tire as specified in claim 8 wherein the tire is a pneumatic tire.

Assignees

• Goodyear Tire & Rubber

Inventors

• Sandstrom Paul Harry
• Yang Xiaoping
• Hua Kuo-Chih
• Golden James Joseph
• Beha Daniel Ray

Classifications

• C08F236/06

  Butadiene · CPC title

• B60C1/0016

  Compositions of the tread · CPC title

• B60C1/0025

  Compositions of the sidewalls · CPC title

• C08L9/00 Primary

  Compositions of homopolymers or copolymers of conjugated diene hydrocarbons · CPC title

• C08F236/08

  Isoprene · CPC title