Mono- and multi-layer films and articles made therefrom

Patent metadata

Field	Value
Publication number	US-10308741-B2
Application number	US-201414175264-A
Country	US
Kind code	B2
Filing date	Feb 7, 2014
Priority date	Jun 1, 2011
Publication date	Jun 4, 2019
Grant date	Jun 4, 2019

Abstract

Mono- and multi-layer films comprising a polyethylene composition which comprises the reaction product of ethylene and optionally one or more alpha olefin comonomers in the presence of a catalyst composition comprising a multi-metallic procatalyst via a solution polymerization process in at least one reactor; wherein said polyethylene composition is characterized by one or more of the following properties: a melt index, I2, measured according to ASTM D 1238 (2.16 kg@190° C.), from 0.1 to 5 g/10 min; density, measured according to ASTM D-792, from 0.910 to 0.935 g/cc; melt flow ratio, I10/I2, wherein I10 is measured according to ASTM D1238 (10 kg@190° C.), from 6 to 7.4; and molecular weight distribution, (Mw/Mn) from 2.5 to 3.5 are provided. Also provided are articles made from the mono- and/or multi-layer films.

First claim

We claim:

1. A film comprising a polyethylene composition which comprises the reaction product of ethylene and optionally one or more alpha olefin comonomers in the presence of a catalyst composition comprising a multi-metallic procatalyst via a solution polymerization process in at least one reactor, wherein said polyethylene composition is characterized by one or more of the following properties:
(a) a melt index, I 2 , measured according to ASTM D1238 (2.16 kg at 190° C.), from 0.1 to 5 g/10 min;
(b) density, measured according to ASTM D-792, from 0.910 to 0.925 g/cc;
(c) melt flow ratio, I 10 /I 2 , wherein I 10 is measured according to ASTM D1238 (10 kg at 190° C.), from 6 to 7.4; and
(d) molecular weight distribution, (M W /M n ) from 2.5 to 3.5;
wherein said multi-metallic procatalyst is obtained according to a process comprising (a) reacting a hydrocarbon-soluble organomagnesium compound or complex thereof and an active non-metallic or metallic halide to form a magnesium halide support; (b) contacting the magnesium halide support with a conditioning compound containing an element selected from the group consisting of boron, aluminum, gallium, indium and tellurium under conditions sufficient to form a conditioned magnesium halide support; (c) contacting the conditioned magnesium halide support and a compound containing, as a first metal, titanium, to form a supported titanium compound; and (d) contacting the supported titanium compound and a second metal and a third metal independently selected from the group consisting of zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, and tungsten, provided that the second metal and the third metal are not the same; and further provided that the molar ratio of the magnesium to a combination of the titanium and the second and third metals ranges from 30:1 to 5:1; under conditions sufficient to form a multi-metallic procatalyst, and
wherein the polyethylene composition comprises greater than or equal to 1 parts by combined weight of at least three metal residues remaining from a multi-metallic catalyst formed from the multi-metallic procatalyst per one million parts of polyethylene composition.

2. The film according to claim 1 , wherein the solution polymerization occurs in a single reactor.

3. The film according to claim 1 , wherein the solution polymerization occurs in a dual reactor system wherein the same polymer is made in each of the dual reactors.

4. The film according to claim 1 , wherein the film is a mono-layer film.

5. The mono-layer film according to claim 4 , wherein the film has a thickness from 0.8 to 10 mils.

6. A multi-layer film comprising at least one layer which comprises the film of claim 1 .

7. A multilayer film comprising at least one layer which comprises the film of claim 1 having a thickness from 0.3 to 8 mils.

8. The film according to claim 4 , wherein when the film has a 2 mil thickness made according to the method described herein, said film is characterized by one or more of the following properties:
(a) a dart drop impact of at least 450 g, measured according to ASTM D-1709;
(b) 45 degree gloss greater than 57%, measured according to ASTM D-2547; and
(c) total haze of no greater than 13%, measured according to ASTM D-1003.

9. An article made from the film according to claim 1 .

10. The article according to claim 9 , wherein the article is selected from the group consisting of pouches, bags, thermoformed webs and laminates.

Assignees

• Dow Global Technologies Llc

Inventors

• Demirors Mehmet
• Karjala Teresa P
• Savargaonkar Nilesh R
• Patel Rajen M
• Desjardins Sylvie

Classifications

• Y10T428/1334

  Nonself-supporting tubular film or bag [e.g., pouch, envelope, packet, etc.] · CPC title

• C08F2410/03

  Multinuclear procatalyst, i.e. containing two or more metals, being different or not · CPC title

• C08F4/685 Primary

  Vanadium or compounds thereof in combination with titanium or compounds thereof · CPC title

• D01F6/04

  from polyolefins · CPC title

• C08F10/02 Primary

  Ethene · CPC title