Method of oxidative dehydrogenation of hydrocarbon compounds
US-10125061-B2 · Nov 13, 2018 · US
US10308570B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10308570-B2 |
| Application number | US-201816157913-A |
| Country | US |
| Kind code | B2 |
| Filing date | Oct 11, 2018 |
| Priority date | Apr 13, 2017 |
| Publication date | Jun 4, 2019 |
| Grant date | Jun 4, 2019 |
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A method of oxidative dehydrogenating a butane-containing hydrocarbon stream by contacting the same with a bimetallic catalyst in the presence of an oxidant, wherein the bimetallic catalyst comprises nickel and bismuth on a titanium carbide catalyst support. Various embodiments of the method of oxidative dehydrogenating the butane-containing hydrocarbon stream and the bimetallic catalyst are also provided.
Opening claim text (preview).
The invention claimed is: 1. A method of dehydrogenating a butane-containing hydrocarbon stream, comprising: pretreating a bimetallic catalyst in a fixed bed reactor by heating to a temperature above 500° C., then cooling to a temperature of 400-450° C., then contacting the butane-containing hydrocarbon stream with the bimetallic catalyst in the presence of oxygen to form a product stream comprising a butene compound, wherein the bimetallic catalyst comprises nickel and bismuth on a titanium carbide catalyst support, and wherein the butane-containing hydrocarbon stream is contacted with the bimetallic catalyst at a temperature of 400 to 450° C. 2. The method of claim 1 , wherein a molar ratio of oxygen to butane is in a range of 1:1 to 4:1. 3. The method of claim 1 , wherein the bimetallic catalyst consists of nickel oxide and bismuth oxide on a titanium carbide catalyst support.
Heat treatment {(B01J37/0009, B01J37/0018 take precedence)} · CPC title
Operations & Transport · mapped topic
Mixing {(B01J37/0009, B01J37/0018 take precedence)} · CPC title
Carbon · CPC title
Drying, e.g. preparing a suspension, adding a soluble salt and drying · CPC title
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