Erosion resistant hard composite materials
US-2015354283-A1 · Dec 10, 2015 · US
US10308559B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10308559-B2 |
| Application number | US-201615569109-A |
| Country | US |
| Kind code | B2 |
| Filing date | Apr 22, 2016 |
| Priority date | Apr 27, 2015 |
| Publication date | Jun 4, 2019 |
| Grant date | Jun 4, 2019 |
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A sintered polycrystalline body and a method of forming the sintered polycrystalline body are disclosed. The sintered polycrystalline body comprises a plurality of particles cubic boron nitride dispersed in a matrix. The matrix includes materials selected from compounds of any of titanium and aluminium. The polycrystalline body further comprises 0.1 to 5.0 volume % of lubricating chalcogenide particles dispersed in the matrix. The chalcogenide particles have a coefficient of friction of less than 0.1 with respect to a workpiece material. Preferably sulfide particles are used as lubricant. Preferably 30-70 vol.-% cBN is contained. Sintering takes place at 1100-1600° C. and 4-8 GPa.
Opening claim text (preview).
The invention claimed is: 1. A sintered polycrystalline body comprising: a plurality of particles of cubic boron nitride dispersed in a matrix, the matrix comprising materials selected from the group consisting of titanium carbonitride, titanium carbide, titanium nitride, titanium diboride, aluminum nitride and aluminum oxide; wherein the polycrystalline body comprises 0.1 to 5.0 volume % of lubricating chalcogenide particles dispersed in the matrix, the chalcogenide particles selected from the group consisting of tungsten disulphide, tantalum disulphide and molybdenum disulphide, wherein the sintered polycrystalline body further comprises titanium carbosulfide (TiCS 2 ), and wherein the chalcogenide particles have a coefficient of friction of less than 0.1 with respect to a ferrous material. 2. The sintered polycrystalline body according to claim 1 , wherein the polycrystalline body comprises from 30 to 70 volume % cubic boron nitride. 3. The sintered polycrystalline body according to claim 1 , further comprising a substrate, wherein the matrix material is bonded to the substrate at an interface. 4. The sintered polycrystalline body according to claim 3 , wherein the substrate comprises tungsten carbide. 5. A tool comprising a sintered polycrystalline body according to claim 1 , the tool being for any of cutting, milling, grinding, drilling, or other abrasive applications. 6. A method of making a sintered polycrystalline body comprising: mixing a plurality of particles of cubic boron nitride with a matrix precursor material, the matrix precursor material comprising compounds for forming a compound selected from the group consisting of titanium carbonitride, titanium carbide, titanium nitride, titanium diboride, aluminum nitride and aluminum oxide; the sintered polycrystalline body further comprising titanium carbosulfide (TiCS 2 ); the matrix precursor material further comprising chalcogenide particles, the chalcogenide particles selected from the group consisting of tungsten disulphide, tantalum disulphide and molybdenum disulphide, and having a coefficient of friction of less than 0.1 with respect to a ferrous material, wherein the chalcogenide particles from 0.1 to 5.0 volume % of the combined superhard material particles and the matrix precursor material particles; consolidating and sintering the plurality of particles of cubic boron nitride and the particles of matrix precursor material at a pressure of between 4 GPa and 8 GPa and a temperature of between 1100° and 1600° C. 7. The method according to claim 6 , further comprising consolidating and sintering the plurality of particles of superhard material and the particles of matrix precursor material at a pressure of between 4 GPa and 6 GPa and a temperature of between 1200° and 1450° C. 8. The method according to claim 6 , wherein the sintered polycrystalline body comprises from 30 to 70 volume % cubic boron nitride. 9. The method according to claim 6 , further comprising providing a substrate precursor material, and consolidating and sintering the plurality of particles of cubic boron nitride and the particles of matrix precursor material onto the substrate precursor material, thereby forming a sintered polycrystalline body bonded to a substrate along an interface. 10. The method of claim 9 , wherein the substrate comprises tungsten carbide.
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