Method and apparatus for producing a hydrogen-containing product

Patent metadata

Field	Value
Publication number	US-10308508-B2
Application number	US-201615148207-A
Country	US
Kind code	B2
Filing date	May 6, 2016
Priority date	May 6, 2016
Publication date	Jun 4, 2019
Grant date	Jun 4, 2019

Abstract

Process and apparatus for producing a hydrogen-containing product by steam-hydrocarbon reforming of multiple hydrocarbon feedstocks in a production facility utilizing a prereformer in addition to the primary reformer. The temperature of the reactant mixture introduced into the prereformer is controlled depending on the composition of the reactant mixture fed to the prereformer.

First claim

I claim:

1. An apparatus for producing a hydrogen-containing product, the apparatus comprising:
a catalyst-containing reactor having an inlet and an outlet, the inlet for receiving a feed, the outlet for discharging an effluent formed from the feed;
a reformer furnace comprising a combustion section and a heat exchanger section, the combustion section containing a plurality of catalyst-containing reformer tubes, the plurality of catalyst-containing reformer tubes operatively disposed to receive at least a portion of the effluent discharged from the catalyst-containing reactor, the heat exchanger section containing a plurality of heat exchangers, the heat exchanger section operatively disposed to receive a combustion product gas from the combustion section;
a first heat exchanger of the plurality of heat exchangers operatively configured to heat a reactant gas mixture by indirect heat exchange with the combustion product gas; and
a heat exchanger unit having an inlet and an outlet, the heat exchanger unit operatively configured to receive at least a fraction of the reactant gas mixture directly from the first heat exchanger and provide on demand cooling of the at least a fraction of the reactant gas mixture from the first exchanger and discharge the at least a fraction of the reactant gas mixture as an effluent from the outlet of the heat exchanger unit, wherein the inlet of the catalyst-containing reactor is operatively disposed to receive a portion or all of the effluent from the outlet of the heat exchanger unit as at least a portion of the feed to the catalyst-containing reactor;
a bypass conduit; and
one or more valves, the one or more valves capable of directing separate fractions of the reactant gas mixture from the first heat exchanger to the heat exchanger unit and the bypass conduit;
wherein the bypass conduit is operatively disposed to direct any fraction of the reactant gas mixture passing through the bypass conduit to the inlet of the catalyst-containing reactor as at least a second portion of the feed to the catalyst-containing reactor without passing that fraction of the reactant gas mixture through the heat exchanger unit,
wherein the heat exchanger unit is operatively configured to cool any fraction of reactant gas mixture that passes through the heat exchanger unit by indirect heat exchange with boiler feed water.

2. The apparatus of claim 1 further comprising:
at least one of (i) a temperature sensor operatively disposed to measure temperatures relatable to a temperatures of the effluent from the catalyst-containing reactor and provide signals in response thereto, and (ii) a composition measurement unit operatively disposed to measure compositions relatable to the compositions of the reactant gas mixture and provide signals in response thereto; and
a controller operatively configured to receive the signals from the at least one of the temperature sensor and the composition measurement unit, the controller operatively configured to generate control signals in response to receiving the signals;
wherein the one or more valves are operatively configured to receive the control signals generated by the controller and respond to the control signals from the controller.

3. The apparatus of claim 1 further comprising:
a second heat exchanger of the plurality of heat exchangers operatively configured to receive that fraction of the reactant gas mixture passed through the bypass conduit and heat that fraction of the reactant gas mixture passed through the bypass conduit by indirect heat exchange with the combustion product gas in the second heat exchanger of the plurality of heat exchangers wherein the inlet of the catalyst-containing reactor is operatively disposed to receive at least a portion of that fraction of the reactant gas mixture passed through the bypass conduit after that at least a portion of that fraction of the reactant gas mixture is heated by indirect heat exchange with the combustion product gas in the second heat exchanger of the plurality of heat exchangers.

4. The apparatus of claim 3 further comprising:
a third heat exchanger of the plurality of heat exchangers operatively configured to heat the at least a portion of the effluent discharged from the catalyst-containing reactor by indirect heat exchange with the combustion product gas, wherein the plurality of catalyst-containing reformer tubes are operatively disposed to receive the at least a portion of the effluent discharged from the catalyst-containing reactor after the at least a portion of the effluent is heated by indirect heat exchange with the combustion product gas in the third heat exchanger of the plurality of heat exchangers.

5. The apparatus of claim 3 wherein the inlet of the catalyst-containing reactor is operatively disposed to receive the at least a portion of that fraction of the reactant gas mixture passed through the bypass conduit directly from the second heat exchanger of the plurality of heat exchangers.

6. The apparatus of claim 4 wherein:
the second heat exchanger of the plurality of heat exchangers operatively configured to heat the at least a portion of the effluent discharged from the outlet of the heat exchanger unit by indirect heat exchange with the combustion product gas wherein the inlet of the catalyst-containing reactor is operatively disposed to receive the at least a portion of the effluent from the outlet of the heat exchanger unit after the at least a portion of the effluent is heated by indirect heat exchange with the combustion product gas in the second heat exchanger of the plurality of heat exchangers.

7. The apparatus of claim 6 wherein the inlet of the catalyst-containing reactor is operatively disposed to receive the at least a portion of the effluent from the outlet of the heat exchanger unit directly from the second heat exchanger of the plurality of heat exchangers.

8. The apparatus of claim 1 further comprising:
a second heat exchanger of the plurality of heat exchangers operatively configured to heat the at least a portion of the effluent discharged from the outlet of the heat exchanger unit by indirect heat exchange with the combustion product gas wherein the inlet of the catalyst-containing reactor is operatively disposed to receive the at least a portion of the effluent from the outlet of the heat exchanger unit after the at least a portion of the effluent is heated by indirect heat exchange with the combustion product gas in the second heat exchanger of the plurality of heat exchangers.

9. The apparatus of claim 1 further comprising a steam drum wherein the steam drum is operatively disposed to receive the boiler feed water from the heat exchanger unit.

10. The apparatus of claim 1 further comprising:
a pressure swing adsorption unit operatively disposed to receive at least a portion of a reformate discharged from the plurality of catalyst-containing reformer tubes, the reformate formed from the at least a portion of the effluent discharged from the catalyst-containing reactor, the pressure swing adsorption unit operatively configured to separate the at least a portion of the reformate to form a hydrogen product gas and a pressure swing adsorption unit by-product gas.

11. The apparatus of claim 1 wherein the inlet of the catalyst-containing reactor is operatively disposed to receive a divided portion or all of the effluent from the outlet of the heat exchanger unit as at least a portion of the feed to the catalyst-containing reactor.

Assignees

• Air Prod & Chem

Inventors

• Saloway Simon Craig

Classifications

• B01J2219/0004

  Processes in series · CPC title

• B01J2208/00504

  by means of a burner · CPC title

• C01B2203/1235

  Hydrocarbons · CPC title

• B01J2208/00176

  outside the reactor · CPC title

• C01B2203/0811

  by combustion of fuel · CPC title