Composition, and method for producing foam molded material and electric wire

Patent metadata

Field	Value
Publication number	US-10304585-B2
Application number	US-201414759089-A
Country	US
Kind code	B2
Filing date	Jan 15, 2014
Priority date	Jan 24, 2013
Publication date	May 28, 2019
Grant date	May 28, 2019

Abstract

The present invention aims to provide a composition which can provide molded foams and foamed electric wires having a small average cell size and a high expansion ratio. The composition of the present invention includes a fluororesin; and boron nitride having an average particle size of 10.5 μm or greater, or boron nitride having a particle size distribution represented by (D84−D16)/D50 of 1.2 or lower.

First claim

The invention claimed is:

1. A composition comprising:
a fluororesin; and
boron nitride having an average particle size of 13.0 μm or greater,
wherein the amount of the boron nitride based on the sum of the amounts of the fluororesin and the boron nitride is 2.0% by mass or less,
wherein the fluororesin is one that has been subjected to fluorination so as to reduce unstable end groups.

2. The composition according to claim 1 ,
wherein the boron nitride has a particle size distribution represented by (D84−D16)/D50 of 1.2 or lower.

3. The composition according to claim 1 ,
wherein the boron nitride is in a pulverized form.

4. The composition according to claim 1 ,
wherein the fluororesin is a tetrafluoroethylene/hexafluoropropylene copolymer, a tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer, or a tetrafluoroethylene/ethylene copolymer.

5. The composition according to claim 1 ,
wherein the amount of the boron nitride is 0.5% to 2.0% by mass based on the sum of the amounts of the fluororesin and the boron nitride.

6. A molded foam, which is formed from the composition according to claim 1 .

7. An electric wire comprising
a core, and
a covering material which covers the core and which is formed from the composition according to claim 1 .

8. A method for producing a molded foam, comprising
foam-molding the composition according to claim 1 .

9. A method for producing an electric wire, comprising
covering a core with the composition according to claim 1 , to provide an electric wire.

10. A composition comprising:
a fluororesin; and
boron nitride having a particle size distribution represented by (D84−D16)/D50 of 1.1 or lower.

11. The composition according to claim 10 ,
wherein the boron nitride has an average particle size of 5.0 μm or greater.

12. A composition comprising:
a fluororesin;
boron nitride having an average particle size of 13.0 μm or greater, and a sulfonic acid or a salt thereof,
wherein the amount of the boron nitride based on the sum of the amounts of the fluororesin and the boron nitride is 2.0% by mass or less.

13. The composition according to claim 12 ,
wherein the boron nitride is in a pulverized form.

14. The composition according to claim 12 ,
wherein the fluororesin is a tetrafluoroethylene/hexafluoropropylene copolymer, a tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer, or a tetrafluoroethylene/ethylene copolymer.

15. The composition according to claim 12 ,
wherein the amount of the boron nitride is 0.5% to 2.0% by mass based on the sum of the amounts of the fluororesin and the boron nitride.

16. The composition according to claim 12 ,
wherein the sulfonic acid or a salt thereof is a sulfonic acid represented by the following formula (1):
F(CF 2 ) n SO 3 H  (1)

wherein n is 4 or 5, or the following formula (2):
F(CF 2 ) n CH 2 CH 2 SO 3 H  (2)

wherein n is 4 or 5, or a salt thereof.

17. A molded foam, which is formed from the composition according to claim 12 .

18. An electric wire comprising
a core, and
a covering material which covers the core and which is formed from the composition according to claim 12 .

19. A method for producing a molded foam, comprising
foam-molding the composition according to claim 12 .

20. A method for producing an electric wire, comprising
covering a core with the composition according to claim 12 to provide an electric wire.

Assignees

• Daikin Ind Ltd

Inventors

• Isaka Tadaharu
• Ishii Kenji
• Shimono Takeshi

Classifications

• B29C2948/92876

  Feeding, melting, plasticising or pumping zones, e.g. the melt itself · CPC title

• C08K5/42

  Sulfonic acids; Derivatives thereof · CPC title

• C09D127/18

  Homopolymers or copolymers of tetrafluoroethene · CPC title

• C08J2327/12

  containing fluorine atoms · CPC title

• C08J2201/03

  Extrusion of the foamable blend · CPC title