Heat-resistant silane crosslinked resin molded body and method of producing the same, heat-resistant silane crosslinkable resin composition and method of producing the same, silane master batch, and heat-resistant product using heat-resistant silane crosslinked resin molded body

Patent metadata

Field	Value
Publication number	US-10304584-B2
Application number	US-201816104665-A
Country	US
Kind code	B2
Filing date	Aug 17, 2018
Priority date	Sep 27, 2013
Publication date	May 28, 2019
Grant date	May 28, 2019

Abstract

A method comprising at least a step (1) of preparing a silane master batch by melt-kneading, all or part of a polyolefin resin, an organic peroxide, an inorganic filler containing a metal hydrate and a metal carbonate, and a silane coupling agent, at a temperature equal to or higher than the decomposition temperature of the organic peroxide, and a step (3) of mixing the silane master batch and a silanol condensation catalyst or a catalyst master batch; a heat-resistant silane crosslinked resin molded body and a heat-resistant silane crosslinkable resin composition prepared by the method, and a silane master batch and a heat-resistant product.

First claim

The invention claimed is:

1. A method of producing a heat-resistant silane crosslinked resin molded body, comprising:
(a) a step of obtaining a mixture by melt-mixing, to 100 parts by mass of a polyolefin resin, from 0.01 to 0.6 parts by mass of an organic peroxide, from 44 to 300 parts by mass of an inorganic filler, and from 1 to 15.0 parts by mass of a silane coupling agent, and a silanol condensation catalyst;
(b) a step of obtaining a molded body by molding the mixture; and
(c) a step of obtaining a heat-resistant silane crosslinked resin molded body by contacting the molded body with water;
wherein the polyolefin resin comprises (i) a linear low-density polyethylene or an ethylene rubber; and (ii) a polyethylene different from the linear low-density polyethylene (i);
wherein the inorganic filler contains a metal hydrate and calcium carbonate, and the inorganic filler contains the metal hydrate in a mass proportion of from 40 to 150 parts by mass with respect to 100 parts by mass of the polyolefin resin, and also contains calcium carbonate in a mass proportion of from 10 to 100 parts by mass with respect to 100 parts by mass of the metal hydrate, and
wherein the step (a) has a step (1) and a step (3) below, and when part of the polyolefin resin is melt-mixed in the step (1) below, the step (a) has the step (1), a step (2), and the step (3) below:
Step (1): a step of melt-mixing of all or part of the polyolefin resin, the organic peroxide, the inorganic filler, and the silane coupling agent, at a temperature equal to or higher than the decomposition temperature of the organic peroxide, to prepare a silane master batch;
Step (2): a step of melt-mixing a remainder of the polyolefin resin and the silanol condensation catalyst, to prepare a catalyst master batch; and
Step (3): a step of mixing the silane master batch and either the silanol condensation catalyst or the catalyst master batch.

2. The method of producing a heat-resistant silane crosslinked resin molded body according to claim 1 , wherein the metal hydrate is at least one kind of magnesium hydroxide and aluminum hydroxide.

3. The method of producing a heat-resistant silane crosslinked resin molded body according to claim 1 , wherein the mixing amount of the silane coupling agent is more than 4 parts by mass and 15.0 parts by mass or less, with respect to 100 parts by mass of the polyolefin resin.

4. The method of producing a heat-resistant silane crosslinked resin molded body according to claim 1 , wherein substantially no silanol condensation catalyst is mixed in the step (1).

5. A heat-resistant silane crosslinked resin molded body produced by the method according to claim 1 .

6. A heat-resistant product comprising the heat-resistant silane crosslinked resin molded body according to claim 5 .

7. The heat-resistant product according to claim 6 , wherein the heat-resistant silane crosslinked resin molded body is provided as a coating for an electric wire or an optical fiber cable.

8. A method of producing a heat-resistant silane crosslinkable resin composition, comprising:
(a) a step of obtaining a mixture by melt-mixing, to 100 parts by mass of a polyolefin resin, from 0.01 to 0.6 parts by mass of an organic peroxide, from 44 to 300 parts by mass of an inorganic filler, and from 1 to 15.0 parts by mass of a silane coupling agent, and a silanol condensation catalyst;

wherein the polyolefin resin comprises (i) a linear low-density polyethylene or an ethylene rubber; and (ii) a polyethylene different from the linear low-density polyethylene (i);
wherein the inorganic filler contains a metal hydrate and calcium carbonate, and the inorganic filler contains the metal hydrate in a mass proportion of from 40 to 150 parts by mass with respect to 100 parts by mass of the polyolefin resin, and also contains calcium carbonate in a mass proportion of from 10 to 100 parts by mass with respect to 100 parts by mass of the metal hydrate, and
wherein the step (a) has a step (1) and a step (3) below, and when part of the polyolefin resin is melt-mixed in the step (1), the step (a) has the step (1), a step (2), and the step (3) below:
Step (1): a step of melt-mixing of all or part of the polyolefin resin, the organic peroxide, the inorganic filler, and the silane coupling agent, at a temperature equal to or higher than the decomposition temperature of the organic peroxide, to prepare a silane master batch;
Step (2): a step of melt-mixing a remainder of the polyolefin resin and the silanol condensation catalyst, to prepare a catalyst master batch; and
Step (3): a step of mixing the silane master batch and either the silanol condensation catalyst or the catalyst master batch.

9. A heat-resistant silane crosslinkable resin composition produced by the method according to claim 8 .

10. A silane master batch, for use in a production of a heat-resistant silane crosslinkable resin composition formed by melt-mixing, to 100 parts by mass of a polyolefin resin, from 0.01 to 0.6 parts by mass of an organic peroxide, from 44 to 300 parts by mass of an inorganic filler, and from 1 to 15.0 parts by mass of a silane coupling agent, and a silanol condensation catalyst;
wherein the polyolefin resin comprises (i) a linear low-density polyethylene or an ethylene rubber; and (ii) a polyethylene different from the linear low-density polyethylene (i);
wherein the inorganic filler contains a metal hydrate and calcium carbonate, and the inorganic filler contains the metal hydrate in a mass proportion of from 40 to 150 parts by mass with respect to 100 parts by mass of the polyolefin resin, and also contains calcium carbonate in a mass proportion of from 10 to 100 parts by mass with respect to 100 parts by mass of the metal hydrate, and
wherein all or part of the polyolefin resin, the organic peroxide, the inorganic filler, and the silane coupling agent are melt-mixed, at a temperature equal to or higher than the decomposition temperature of the organic peroxide.

Assignees

• Furukawa Electric Co Ltd

Inventors

• Matsumura Arifumi
• Nishiguchi Masaki

Classifications

• C08K2003/2224

  Magnesium hydroxide · CPC title

• C08J2423/06

  Polyethene · CPC title

• C08J2325/06

  Polystyrene · CPC title

• C08K3/26

  Carbonates; Bicarbonates · CPC title

• C08J3/24

  Crosslinking, e.g. vulcanising, of macromolecules (mechanical aspects B29C35/00; crosslinking agents C08K) · CPC title