Fiber comprising a mixture of poly(m-phenylene isophthalamide) and copolymer made from 5(6)-amino-2-(p-aminophenyl)benzimidazole

Patent metadata

Field	Value
Publication number	US-10301747-B2
Application number	US-201414526635-A
Country	US
Kind code	B2
Filing date	Oct 29, 2014
Priority date	Oct 30, 2013
Publication date	May 28, 2019
Grant date	May 28, 2019

Abstract

The invention concerns fiber, and a process for making same, the fiber comprising a mixture of at least a first polymer and a second polymer,
the first polymer having a structure derived from the reaction of one or more amine monomers and a plurality of acid monomers, wherein the one or more amine monomers includes at least 60 mole percent 5(6)-amino-2-(p-aminophenyl)benzimidazole, and the plurality of acid monomers include those having a structure of

Cl—CO—Ar 1 —CO—Cl and Cl—CO—Ar 2 —CO—Cl

wherein Ar 1 is an aromatic group having para-oriented linkages and Ar 2 is an aromatic group having meta-oriented linkages, and wherein the plurality of acid monomers has at least 50 mole percent of the monomer containing aromatic group Ar 2 ; and
the second polymer has a structure derived from the reaction of metaphenylene diamine and isophthaloyl chloride. This fiber has use in heat-resistant protective apparel fabrics and garments.

First claim

What is claimed:

1. A fiber comprising a mixture of at least a first polymer and a second polymer;
the first polymer having a structure derived from the reaction of one or more amine monomers and a plurality of acid monomers, wherein
i) the one or more amine monomers being 100 mole percent 5(6)-amino-2-(p-aminophenyl) benzimidazole, or the combination of metaphenylene diamine and at least 60 mole percent 5(6)-amino-2-(p-aminophenyl)benzimidazole, based on the total amount of amine monomers; and
ii) the plurality of acid monomers include those having a structure of
Cl—CO—Ar 1 —CO—Cl and Cl—CO—Ar 2 —CO—Cl

wherein Ar 1 is an aromatic group having para-oriented linkages and Ar 2 is an aromatic group having meta-oriented linkages, and wherein the plurality of acid monomers has at least 50 mole percent of the monomer containing aromatic group Ar 2 ; and

the second polymer has a structure derived from the reaction of metaphenylene diamine and isophthaloyl chloride,
wherein the fiber has a first-polymer-rich sheath, a second-polymer-rich core, and a transition zone having a combination of the first and second polymers,
the transition zone further having a higher weight percentage of the second polymer nearer the core and a higher weight percentage of the first polymer nearer the sheath, forming a gradient between the second-polymer-rich core and the first-polymer-rich sheath.

2. The fiber of claim 1 , wherein the mixture of first polymer and second polymer contains 25 to 80 weight percent of the first polymer, based on the total amount of first polymer and second polymer.

3. The fiber of claim 2 , wherein the mixture of first polymer and second polymer contains 25 to 50 weight percent of the first polymer, based on the total amount of first polymer and second polymer.

4. A multifilament yarn comprising the fiber of any one of claims 1 , 2 or 3 .

5. A yarn comprising a staple fiber of any one of claims 1 , 2 or 3 .

6. A fabric comprising the fiber of any one of claims 1 , 2 or 3 .

7. A protective garment comprising the fiber of any one of claims 1 , 2 or 3 .

8. A method of producing a fiber comprising:
a) mixing or blending at least a first polymer and a second polymer;
the first polymer having a structure derived from the reaction of one or more amine monomers and a plurality of acid monomers, wherein
i) the one or more amine monomers being 100 mole percent 5(6)-amino-2-(p-aminophenyl) benzimidazole, or the combination of metaphenylene diamine and at least 60 mole percent 5(6)-amino-2-(p-aminophenyl)benzimidazole, based on the total amount of amine monomers; and
ii) the plurality of acid monomers include those having a structure of
Cl—CO—Ar 1 —CO—Cl and Cl—CO—Ar 2 —CO—Cl

wherein Ar 1 is an aromatic group having para-oriented linkages and Ar 2 is an aromatic group having meta-oriented linkages, and
wherein the plurality of acid monomers has at least 50 mole percent of the monomer containing aromatic group Ar 2 ; and

the second polymer has a structure derived from the reaction of metaphenylene diamine and isophthaloyl chloride;
b) providing a homogeneous solution of the at least first polymer and a second polymer the suitable for spinning fibers; and
c) spinning fibers from the solution,
wherein the fiber has a first-polymer-rich sheath, a second-polymer-rich core, and a transition zone having a combination of the first and second polymers,
the transition zone further having a higher weight percentage of the second polymer nearer the core and a higher weight percentage of the first polymer nearer the sheath, forming a gradient between the second-polymer-rich core and the first-polymer-rich sheath.

9. The method of producing a fiber of claim 8 , wherein the mixture of first polymer and second polymer contains 25 to 80 weight percent of the first polymer, based on the total amount of first polymer and second polymer.

10. The method of producing a fiber of claim 9 , wherein the mixture of first polymer and second polymer contains 25 to 50 weight percent of the first polymer, based on the total amount of first polymer and second polymer.

Assignees

• Du Pont

Inventors

• Lee Kiu-Seung

Classifications

• D10B2331/02

  polyamides (D10B2331/08 takes precedence) · CPC title

• D01F6/805

  from aromatic copolyamides · CPC title

• D01F6/74

  from polycondensates of cyclic compounds, e.g. polyimides, polybenzimidazoles · CPC title

• D01D5/06

  Wet spinning methods {(D01D5/0046 takes precedence)} · CPC title

• D01F6/905

  of aromatic polyamides · CPC title