Integral U/TRU recovery cathode system for electrorefining used nuclear fuel, method for electrorefining and harvesting metal from used nuclear fuel

Patent metadata

Field	Value
Publication number	US-10301729-B2
Application number	US-201615143173-A
Country	US
Kind code	B2
Filing date	Apr 29, 2016
Priority date	Apr 29, 2016
Publication date	May 28, 2019
Grant date	May 28, 2019

Abstract

The invention provides a system for collecting metal in an electrorefining process, the system having a hollow cathode; and a container defining an upwardly extending surface adapted to be received by the hollow cathode. An embodiment of the invention provides for metal reduction to occur on laterally facing and medially facing surfaces of the cathode such that electrolyte resides between surfaces of the cathode. Also provided is a metal electrorefining process having the steps of subjecting molten salt containing metal moieties to electrolysis wherein reduced metal accumulates in a cathode-cup construct in a first position; raising the construct to a second position above the molten salt while subjecting the construct to heat from the molten salt; withdrawing the cathode from the construct into a vestibule to the electrorefiner to a third position; and removing the cathode and cup from the electrorefiner to a fourth position.

First claim

The embodiment of the invention in which an exclusive property or privilege is claimed is defined as follows:

1. A system for collecting metal in an electrorefining process, the system comprising:
a. a hollow cathode; and
b. a container defining an upwardly extending surface adapted to slidably communicate with interior aspects of the hollow cathode;
wherein the container encircles the bottom and laterally facing surfaces of the cathode.

2. The system as recited in claim 1 wherein the extending surface is coaxial with the longitudinal axis of the container and of the cathode.

3. The system as recited in claim 1 wherein the cathode does not contact the container.

4. The system as recited in claim 1 wherein the cathode is not in electrical communication with the container.

5. The system as recited in claim 1 adapted to contain metal in two annular spaces between the cathode and the container.

6. The system as recited in claim 1 wherein the cathode and the container are adapted to be imbedded in molten salt in a first position.

7. The system as recited in claim 6 wherein the container is adapted to be imbedded in molten salt in a second position.

8. The system as recited in claim 1 , wherein annular spaces defined between the cathode and the container are adapted to retain metal formed during the electrorefining process, while displacing an electrolyte out of the annular spaces.

9. A system for collecting metal in an electrorefining process, the system comprising:
a. a rotatable, hollow cathode;
b. a container defining an upwardly extending surface adapted to oppose interior surfaces of the hollow cathode;
c. a first plate adapted to support the container;
d. a second plate superior from the first plate and connected thereto via a plurality of vertically extending struts; and
e. a cathode-scraper third plate disposed between the first plate and the second plate and attached to the struts, each of the first, second, and third plates defining a central aperture to slidably receive the cathode, wherein the cathode is collinearly aligned with the apertures of the first, second and third plates.

10. The system as recited in claim 9 further comprising:
f) radially extending protuberances on the surface of the cathode; and
g) diametrically opposed notches formed in the central aperture of the third plate, said notches in slidable communication with the protuberances upon rotation of the cathode.

11. The system as recited in claim 9 wherein the container defines a first annular region and a central protuberance coaxial with the annular region.

12. The system as recited in claim 11 wherein the cathode defines a tube adapted to receive the central protuberance of the container to define a second, inner annular region between the central protuberance and in the interior surfaces of the hollow cathode.

13. The system as recited in claim 12 , wherein the first and second annular regions are adapted to retain metal formed during the electrorefining process, while displacing an electrolyte from the annular regions.

Assignees

• Willit James L
• Williamson Mark A
• Wiedmeyer Stanley G
• Tylka Magdalena M
• Uchicago Argonne Llc

Inventors

• Willit James L
• Williamson Mark A
• Wiedmeyer Stanley G
• Tylka Magdalena M

Classifications

• Y02W30/884

  Cross-Sectional Technologies · mapped topic

• C25C7/025 Primary

  used in cells for the electrolysis of melts · CPC title

• G21C19/48

  Non-aqueous processes · CPC title

• C25C3/34

  of metals not provided for in groups C25C3/02 - C25C3/32 · CPC title

• G21C19/42

  Reprocessing of irradiated fuel · CPC title