Process and apparatus for hydrocracking a hydrocarbon stream in two stages with aromatic saturation

Patent metadata

Field	Value
Publication number	US-10301560-B2
Application number	US-201715599289-A
Country	US
Kind code	B2
Filing date	May 18, 2017
Priority date	Jun 15, 2016
Publication date	May 28, 2019
Grant date	May 28, 2019

Abstract

A process and apparatus for two stage hydrocracking saturates aromatics from the first stage hydrocracking unit to prevent production of HPNA's. The saturated HPNA's can be hydrocracked in the second stage to minimize or eliminate purged unconverted oil to approach or obtain maximum conversion. In an aspect, the second stage hydrocracking reactor and hydrotreating reactor may be located in the same vessel.

First claim

The invention claimed is:

1. A process for hydrocracking a hydrocarbon stream comprising:
hydrocracking a first hydrocracking feed stream over a first hydrocracking catalyst and hydrogen in a first hydrocracking reactor to provide a first hydrocracked stream;
fractionating said first hydrocracked stream in a fractionation section to provide a recycle oil stream;
hydrotreating said recycle oil stream over a hydrotreating catalyst and hydrogen in a second hydrocracking reactor to saturate at least 60 wt % of aromatics in said recycle oil stream and provide a second hydrocracking feed stream, wherein said first hydrocracking reactor and said second hydrocracking reactor are different; and
hydrocracking said second hydrocracking feed stream over a second hydrocracking catalyst and hydrogen.

2. The process of claim 1 wherein said hydrotreating said recycle oil stream comprises hydrotreating said recycle oil stream over a noble metal catalyst.

3. The process of claim 1 further comprising hydrotreating a first hydrocarbon feed stream to provide said first hydrocracking feed stream prior to hydrocracking said first hydrocracking feed stream.

4. The process of claim 3 wherein a hydrotreating catalyst in said first hydrotreating step is different than a hydrotreating catalyst in said second hydrotreating step.

5. The process of claim 1 wherein said fractionating step comprises separating said hydrocracked stream into a liquid stream and stripping gases from said liquid stream to provide a stripped stream.

6. The process of claim 5 further comprising fractionating said stripped stream to provide a naphtha stream, a distillate stream and an unconverted oil stream from which said recycle oil stream is taken.

7. The process of claim 3 wherein said recycle oil stream is taken from a bottom of a fractionation column.

8. A process for hydrocracking a hydrocarbon stream comprising:
hydrotreating a first hydrocarbon stream to provide a first hydrocracking feed stream;
hydrocracking a first hydrocracking feed stream over a first hydrocracking catalyst and hydrogen in a first hydrocracking reactor to provide a first hydrocracked stream;
separating said first hydrocracked stream into a liquid stream;
stripping gases from said liquid stream to provide a stripped stream;
fractionating said stripped stream in a fractionation section to provide a naphtha stream, a distillate stream and an unconverted oil stream from which a recycle oil stream is taken;
hydrotreating said recycle oil stream over a hydrotreating catalyst and hydrogen in a second hydrocracking reactor to provide a second hydrocracking feed stream, wherein said first hydrocracking reactor and said second hydrocracking reactor are different; and
hydrocracking said second hydrocracking feed stream over a second hydrocracking catalyst and hydrogen.

9. The process of claim 8 wherein said hydrotreating said recycle oil stream comprises hydrotreating said recycle oil stream over a noble metal catalyst to saturate at least 60 wt % of all aromatics.

10. The process of claim 8 wherein a hydrotreating catalyst in said first hydrotreating step is different than a hydrotreating catalyst in said second hydrotreating step.

11. The process of claim 8 wherein said recycle oil stream is taken from a bottom of a fractionation column.

Assignees

• Uop Llc

Inventors

• Wang Haiyan
• Hoehn Richard K
• Zhu Xin X

Classifications

• C10G2300/1092

  C2-C4 olefins · CPC title

• C10G65/12 Primary

  including cracking steps and other hydrotreatment steps · CPC title

• C10G45/44

  Hydrogenation of the aromatic hydrocarbons · CPC title