Anti-static agent, anti-static agent composition, anti-static resin composition, and molding

Patent metadata

Field	Value
Publication number	US-10301519-B2
Application number	US-201515505429-A
Country	US
Kind code	B2
Filing date	Aug 5, 2015
Priority date	Aug 22, 2014
Publication date	May 28, 2019
Grant date	May 28, 2019

Abstract

Provided are: an antistatic agent and an antistatic agent composition which are capable of providing excellent antistatic effect in a small amount and have sufficient persistence and wiping resistance; and an antistatic resin composition and a molded article using the same.
The antistatic agent includes a polymer compound (E) having a structure in which a diol, a dicarboxylic acid, a compound (B) which comprises at least one group represented by the following Formula (1) and has hydroxyl groups at both ends, and a polycarboxylic acid compound (D) are bound via ester bonds:

—CH 2 —CH 2 —O—  (1).

First claim

The invention claimed is:

1. An antistatic agent comprising a polymer compound (E) having a structure in which a diol, a dicarboxylic acid, a compound (B) which comprises at least one group represented by the following Formula (1) and has hydroxyl groups at both ends, and a polycarboxylic acid compound (D) are bound via ester bonds:
—CH 2 —CH 2 —O—  (1)

wherein said polymer compound (E) has a structure in which a polyester (A), which is constituted by a diol and a dicarboxylic acid, said compound (B) and said polycarboxylic acid compound (D) are bound via ester bonds, and
wherein said polymer compound (E) has a structure in which a block polymer (C) having hydroxyl groups at both ends and said polycarboxylic acid compound (D) are bound via an ester bond, said block polymer (C) comprising a block constituted by said polyester (A) and a block constituted by said compound (B) that are repeatedly and alternately bound via ester bonds.

2. The antistatic agent according to claim 1 , wherein said polyester (A) has a structure comprising carboxyl group at one or both ends.

3. The antistatic agent according to claim 1 , wherein said block constituted by said polyester (A) has a number-average molecular weight of 800 to 8,000 in terms of polystyrene, said block constituted by said compound (B) has a number-average molecular weight of 400 to 6,000 in terms of polystyrene, and said block polymer (C) has a number-average molecular weight of 5,000 to 25,000 in terms of polystyrene.

4. The antistatic agent according to claim 1 , wherein said compound (B) is a polyethylene glycol.

5. The antistatic agent according to claim 1 , wherein said polycarboxylic acid compound (D) is a carboxylic acid having three or more carboxyl groups.

6. An antistatic agent composition comprising at least one selected from the group consisting of alkali metal salts and Group II element salts in the antistatic agent according to claim 1 .

7. An antistatic resin composition comprising a thermoplastic resin and the antistatic agent according to claim 1 .

8. The antistatic resin composition according to claim 7 , wherein said thermoplastic resin is at least one selected from the group consisting of polyolefin-based resins, polystyrene-based resins and copolymers thereof.

9. The antistatic resin composition according to claim 7 , wherein the mass ratio of said thermoplastic resin and said antistatic agent is in a range of 99/1 to 40/60.

10. A molded article composed of the antistatic resin composition according to claim 7 .

11. An antistatic resin composition comprising a thermoplastic resin and the antistatic agent composition according to claim 6 .

12. The antistatic resin composition according to claim 11 , wherein the mass ratio of said thermoplastic resin and said antistatic agent composition is in a range of 99/1 to 40/60.

Assignees

• Adeka Corp

Inventors

• Nakamura Tatsuhito
• Nomura Kazukiyo

Classifications

• C08L55/02

  ABS [Acrylonitrile-Butadiene-Styrene] polymers · CPC title

• C09K3/16 Primary

  Anti-static materials · CPC title

• C08L67/00

  Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain (of polyester-amides C08L77/12; of polyester-imides C08L79/08); Compositions of derivatives of such polymers · CPC title

• C08G63/672

  Dicarboxylic acids and dihydroxy compounds · CPC title

• C08G63/199

  Acids or hydroxy compounds containing cycloaliphatic rings · CPC title