Curable resin composition containing aromatic polyester, and cured article thereof
US-2015376447-A1 · Dec 31, 2015 · US
US10301517B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10301517-B2 |
| Application number | US-201715473170-A |
| Country | US |
| Kind code | B2 |
| Filing date | Mar 29, 2017 |
| Priority date | Mar 30, 2016 |
| Publication date | May 28, 2019 |
| Grant date | May 28, 2019 |
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A resin composition including at least (A) an epoxy resin, (B) a curing agent and (C) an inorganic filler, satisfies the following conditions: (I-I) the minimum modulus is no greater than 10 4 MPa when evaluated at a set temperature of 200° C. after temperature increase from room temperature to 200° C. at 50° C./min by evaluation with a rheometer, and the final modulus is 10 5 MPa or greater from 10 minutes after the initial temperature increase; (I-II) the softening point of the epoxy resin (A) is 35° C. or higher; (I-III) the residual solvent in the resin composition is no greater than 0.1%; and (I-IV) the equivalent value of the curing agent (B) is no greater than 90 g/eq and the softening point is 105° C. or higher.
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The invention claimed is: 1. A resin composition including (A) an epoxy resin, (B) a curing agent and (C) an inorganic filler, and satisfying the following conditions: (II-I) X atoms other than C, O, H and N atoms in the main component of the inorganic filler (C) (the component present in a range of 1 to 95 mol %), based on EDX measurement, are on the surface of the inorganic filler (C) in the resin composition; (II-II) the weight percentage of the inorganic filler (C) in the resin composition is no greater than 95 wt %; (II-III) the mean particle size of the inorganic filler (C) is 0.5 μm or greater; (II-IV) a ratio of the specific surface area of the inorganic filler (C) with respect to the total resin composition is no greater than 2 m 2 /g; (II-V) the softening point of the epoxy resin (A) is 35° C. or higher; (II-VI) the residual solvent in the resin composition is less than 0 .1 wt %; and (II-VII) the softening point of the curing agent (B) is 105° C. or higher; and wherein, under the condition (II-I), the abundance ratio of C atoms of the epoxy resin (A) or curing agent (B) and the X atoms of the inorganic filler (C), based on EDX measurement, on the surface of the inorganic filler (C) in the resin composition satisfies the following formula: C/X =>1 wherein C is defined as a molar concentration of the C atoms and X is defined as a molar concentration of the X atoms. 2. The resin composition according to claim 1 , wherein, under the condition (II-VII), the equivalent value of the curing agent (B) is no greater than 90 g/eq and the softening point is 105° C. or higher. 3. A resin composition according to claim 1 , wherein the curing agent (B) is a compound with amino groups. 4. A sealing material comprising the cured product of a resin composition according to claim 1 . 5. A semiconductor device wherein a semiconductor element is sealed with a sealing material according to claim 4 . 6. A method for producing a semiconductor device, including a step of sealing a semiconductor element by compression molding using a sealing material according to claim 4 .
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