Superhydrophilic coating composition

Patent metadata

Field	Value
Publication number	US-10301477-B2
Application number	US-201313838501-A
Country	US
Kind code	B2
Filing date	Mar 15, 2013
Priority date	Mar 15, 2013
Publication date	May 28, 2019
Grant date	May 28, 2019

Abstract

A composition for forming a hydrophilic coating includes an organic binder having an average particle size from about 1 to about 100 nm and an inorganic binder having an average particle size from about 1 to about 40 nm. The composition further includes an inorganic photocatalyst that catalyzes an oxidation-reduction reaction. Characteristically, the photocatalyst includes a photocatalytic metal oxide having an average particle size from about 1 to about 50 nm. Advantageously, coatings formed from the composition have improved stain resistance, low contact angle, and resistance to dirt adherence, while maintaining a clear optical character.

First claim

What is claimed is:

1. A composition for forming a hydrophilic coating comprising:
water in an amount from about 5 to 40 percent of the total weight of the composition;
an organic binder having an average particle size greater than 10 nm and less than 60 nm, the organic binder being selected from the group consisting of acrylics, polyurethane dispersions, solution polymers, styrene acrylate dispersions, urethane-acrylic hybrid dispersions, aliphatic polyurethane dispersions, acrylic dispersions, and combinations thereof;
an inorganic binder having an average particle size from about 1 to about 40 nm wherein the inorganic binder is selected from the group consisting of colloidal silicas, silica sols, silicates, and combinations thereof;
an inorganic photocatalyst that catalyzes an oxidation-reduction reaction, the inorganic photocatalyst including a photocatalytic metal oxide having an average particle size from about 1 to about 50 nm; and
a solvent selected from the group consisting of glycols, ethylene glycol, propylene glycol, triglycol, and combinations thereof, the solvent being present in an amount from about the solvent is present in about 0.01 to about 5 percent of the total weight of the composition.

2. The composition of claim 1 wherein the inorganic binder is present in an amount from about 20 to about 80 percent of the combined weight of the organic binder, the inorganic binder, and the inorganic photocatalyst; the organic binder is present in an amount from about 20 to about 80 percent of the combined weight of the organic binder, the inorganic binder, and the inorganic photocatalyst; and the photocatalytic metal oxide is present in an amount from about 2 to about 20 percent of the combined weight of the organic binder, the inorganic binder, and the inorganic photocatalyst.

3. The composition of claim 1 wherein the weight ratio of the inorganic binder to organic binder is from about 1:2 to about 4:1.

4. The composition of claim 1 wherein the inorganic binder has an average particle size from about 1 to about 20 nm, and the photocatalytic metal oxide has an average particle size from about 1 to about 20 nm.

5. The composition of claim 1 wherein the photocatalytic metal oxide is selected from the group consisting of zinc oxide, silicon dioxide, aluminum oxide, antimony oxide, titanium oxide, indium oxide, tin oxide, zirconium oxide, lead oxide, iron oxide, calcium silicate, magnesium oxide, niobium oxide, cerium oxide, composite oxides of these, and combinations thereof.

6. The composition of claim 1 wherein the photocatalytic metal oxide is titanium oxide and present in an amount between about 0.1 to about 20 percent of the total weight of the composition.

7. The composition of claim 1 further comprising an additive with at least one component selected from the group consisting of a solvent, a defoamer, a wetting agent, and a rheology modifier, wherein the additive is present in about 0.1 to about 5 percent of the total weight of the composition.

8. An article comprising:
a substrate; and
a coating disposed over the substrate, the coating having a contact angle less than about 5 degrees, the coating including
an organic binder having an average particle size greater than 10 nm and less than 60 nm, the organic binder being selected from the group consisting of acrylics, polyurethane dispersions, solution polymers, styrene acrylate dispersions, urethane-acrylic hybrid dispersions, aliphatic polyurethane dispersions, acrylic dispersions, and combinations thereof;
an inorganic binder having an average particle size from about 1 to about 40 nm wherein the inorganic binder is selected from the group consisting of colloidal silicas, silica sols, silicates, and combinations thereof, the inorganic binder including particles treated with a silane coupling agent; and
an inorganic photocatalyst that catalyzes an oxidation-reduction reaction, the inorganic photocatalyst including a photocatalytic metal oxide having an average particle size from about 1 to about 50 nm, wherein
the organic binder is present in an amount from about 30 to about 70 percent of the combined weight of the inorganic binder, organic binder, and photocatalyst;
the inorganic binder is present in an amount from about 40 to about 60 percent of the combined weight of the inorganic binder, organic binder, and photocatalyst; and
the inorganic photocatalyst is present in an amount from about 5 to about 15 percent of the combined weight of the inorganic binder, organic binder, and photocatalyst.

9. The article of claim 8 wherein the weight ratio of the inorganic binder to organic binder is from about 1:2 to about 4:1.

10. The article of claim 8 wherein the inorganic binder has an average particle size from about 1 to about 20 nm, and the photocatalytic metal oxide has an average particle size from about 1 to about 20 nm.

11. The article of claim 8 wherein the photocatalytic metal oxide is selected from the group consisting of zinc oxide, silicon dioxide, aluminum oxide, antimony oxide, titanium oxide, indium oxide, tin oxide, zirconium oxide, lead oxide, iron oxide, calcium silicate, magnesium oxide, niobium oxide, cerium oxide, composite oxides of these, and combinations thereof.

12. The article of claim 8 wherein the photocatalytic metal oxide is titanium oxide.

13. The composition of claim 1 wherein the organic binder has an average particle size greater than 30 nm and less than 50 nm.

14. The article of claim 8 wherein the organic binder has an average particle size greater than 30 nm and less than 50 nm.

15. The composition of claim 1 wherein the composition forms a clear-coat coating having a visible transmission greater than 90%.

16. The composition of claim 1 wherein the composition forms a clear-coat coating having a visible transmission from about 90% to about 98%.

17. The article of claim 8 wherein the coating is a clear-coat coating having a visible transmission greater than 90%.

18. The article of claim 8 wherein the coating is clear-coat coating having a visible transmission from about 90% to about 98%.

19. The composition of claim 1 wherein the inorganic binder and the photocatalytic metal oxide each independently include particles treated with a silane coupling agent.

20. The article of claim 8 wherein the photocatalytic metal oxide each independently includes particles treated with a silane coupling agent.

21. The composition of claim 1 wherein:
the organic binder is present in an amount from about 30 to about 70 percent of the combined weight of the inorganic binder, organic binder, and photocatalyst;
the inorganic binder is present in an amount from about 40 to about 60 percent of the combined weight of the inorganic binder, organic binder, and photocatalyst; and
the inorganic photocatalyst is present in an amount from about 5 to about 15 percent of the combined weight of the inorganic binder, organic binder, and photocatalyst.

Assignees

• Behr Process Corp

Inventors

• Shi Jinzhen
• Tarng Ming-Ren
• Li Jigui
• Zhou Shuxue
• Wu Limin
• Yang Ling

Classifications

• C09D7/67

  Particle size smaller than 100 nm · CPC title

• C09D1/00

  Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances · CPC title

• C09D5/16

  Antifouling paints; Underwater paints · CPC title

• C09D5/00 Primary

  Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced {(electrically insulating plastics, resins or waxes H01B3/30)}; Filling pastes · CPC title

• C09D183/02

  Polysilicates · CPC title