Flexible, UV resistant poly(phenylene ether) composition and insulated conductor and jacketed cable comprising it

Patent metadata

Field	Value
Publication number	US-10301467-B2
Application number	US-201716084736-A
Country	US
Kind code	B2
Filing date	Feb 3, 2017
Priority date	Mar 17, 2016
Publication date	May 28, 2019
Grant date	May 28, 2019

Abstract

A composition includes specific amounts of a poly(phenylene ether), a hydrogenated block copolymer of an alkenyl aromatic monomer and a conjugated diene, a polypropylene, a low molecular weight polybutene, a flame retardant, an ultraviolet absorbing agent, and a poly(alkylene oxide). The composition is useful as an insulation or jacketing material for wires and cables.

First claim

The invention claimed is:

1. A composition, comprising:
15 to 45 parts by weight of a poly(phenylene ether);
5 to 50 parts by weight of a hydrogenated block copolymer of an alkenyl aromatic monomer and a conjugated diene;
1 to 15 parts by weight of a polypropylene;
2 to 10 parts by weight of a polybutene having a number average molecular weight of 500 to 1500 grams/mole;
10 to 45 parts by weight of a flame retardant;
0.5 to 10 parts by weight of an ultraviolet absorbing agent; and
0.5 to 10 parts by weight of a poly(alkylene oxide);
wherein all parts by weight are based on 100 parts by weight total of flame retardants and polymers other than the poly(alkylene oxide).

2. The composition of claim 1 , wherein the poly(phenylene ether) is a poly(2,6-dimethyl-1,4-phenylene ether) having an intrinsic viscosity of 0.35 to 0.5 deciliter per gram.

3. The composition of claim 1 , wherein the poly(phenylene ether) has an intrinsic viscosity of 0.35 to 0.5 deciliter per gram and comprises poly(phenylene ether) homopolymer and poly(phenylene ether)-polysiloxane block copolymer.

4. The composition of claim 1 , wherein the flame retardant is selected from the group consisting of magnesium dihydroxides, metal dialkylphosphinates, melamine polyphosphates, and combinations thereof.

5. The composition of claim 1 , wherein the ultraviolet absorbing agent is selected from the group consisting of benzotriazole ultraviolet absorbing agents, 2-(2′-hydroxyphenyl)-1,3,5-triazine ultraviolet absorbing agents, benzophenone ultraviolet absorbing agents, oxanilide ultraviolet absorbing agents, cyanoacrylate ultraviolet absorbing agents, and combinations thereof.

6. The composition of claim 1 , wherein the poly(alkylene oxide) is selected from the group consisting of poly(ethylene oxide)s, poly(propylene oxide)s, random copolymers of ethylene oxide and propylene oxide, block copolymers of ethylene oxide and propylene oxide, monoalkyl ethers of the foregoing, dialkyl ethers of the foregoing, and combinations thereof.

7. The composition of claim 1 , wherein the poly(alkylene oxide) has a number average molecular weight of 300 to 40,000 grams/mole.

8. The composition of claim 1 , wherein the poly(alkylene oxide) comprises a poly(propylene oxide) mono(C 1 -C 12 -alkyl) ether.

9. The composition of claim 1 , further comprising 5 to 30 parts by weight of a copolymer of monomers comprising ethylene and a C 3 -C 12 alpha-olefin.

10. The composition of claim 9 , wherein the copolymer comprises a copolymer of ethylene and 1-octene, and a maleic anhydride-grafted copolymer of ethylene and 1-octene.

11. The composition of claim 1 , comprising
17 to 30 parts by weight of the poly(phenylene ether),
7 to 17 parts by weight of the hydrogenated block copolymer,
2 to 7 parts by weight of the polypropylene,
3 to 9 parts by weight of the polybutene,
20 to 30 parts by weight of a copolymer of monomers comprising ethylene and a C 3 -C 12 alpha-olefin,
28 to 38 parts by weight of the flame retardant,
1 to 4 parts by weight of the ultraviolet absorbing agent, and
1 to 4 parts by weight of the poly(alkylene oxide).

12. The composition of claim 11 ,
wherein the poly(phenylene ether) is a poly(2,6-dimethyl-1,4-phenylene ether) having an intrinsic viscosity of 0.35 to 0.5 deciliter per gram;
wherein the hydrogenated block copolymer comprises a polystyrene-poly(ethylene/butylene)-polystyrene triblock copolymer;
wherein the flame retardant comprises magnesium dihydroxide;
wherein the ultraviolet absorbing agent comprises a triazine ultraviolet absorbing agent;
wherein the poly(alkylene oxide) comprises a poly(propylene oxide) mono(C 1 -C 12 -alkyl) ether; and
wherein the copolymer of monomers comprising ethylene and a C 3 -C 12 alpha-olefin comprises a copolymer of ethylene and 1-octene, and a maleic anhydride-grafted copolymer of ethylene and 1-octene.

13. An insulated conductor, comprising:
a conductor; and
an insulating covering disposed over the conductor;
wherein the insulating covering comprises a composition comprising
15 to 45 parts by weight of a poly(phenylene ether);
5 to 50 parts by weight of a hydrogenated block copolymer of an alkenyl aromatic monomer and a conjugated diene;
1 to 15 parts by weight of a polypropylene;
2 to 10 parts by weight of a polybutene having a number average molecular weight of 500 to 1500 grams/mole;
10 to 45 parts by weight of a flame retardant;
0.5 to 10 parts by weight of an ultraviolet absorbing agent; and
0.5 to 10 parts by weight of a poly(alkylene oxide);

wherein all parts by weight are based on 100 parts by weight total of flame retardants and polymers other than the poly(alkylene oxide).

14. The insulated conductor of claim 13 , wherein the composition comprises
17 to 30 parts by weight of the poly(phenylene ether),
7 to 17 parts by weight of the hydrogenated block copolymer,
2 to 7 parts by weight of the polypropylene,
3 to 9 parts by weight of the polybutene,
20 to 30 parts by weight of a copolymer of monomers comprising ethylene and a C 3 -C 12 alpha-olefin,
28 to 38 parts by weight of the flame retardant,
1 to 4 parts by weight of the ultraviolet absorbing agent, and
1 to 4 parts by weight of the poly(alkylene oxide).

15. The insulated conductor of claim 14 ,
wherein the poly(phenylene ether) is a poly(2,6-dimethyl-1,4-phenylene ether) having an intrinsic viscosity of 0.35 to 0.5 deciliter per gram;
wherein the hydrogenated block copolymer comprises a polystyrene-poly(ethylene/butylene)-polystyrene;
wherein the flame retardant comprises magnesium dihydroxide;
wherein the ultraviolet absorbing agent comprises a triazine ultraviolet absorbing agent;
wherein the poly(alkylene oxide) comprises a poly(propylene oxide) mono(C 1 -C 12 -alkyl) ether; and
wherein the copolymer of monomers comprising ethylene and a C 3 -C 12 alpha-olefin comprises a copolymer of ethylene and 1-octene, and a maleic anhydride-grafted copolymer of ethylene and 1-octene.

16. A jacketed cable, comprising:
a conductor;
an insulating covering surrounding the conductor; and
a jacket surrounding the insulation;
wherein the jacket comprises a composition comprising
15 to 45 parts by weight of a poly(phenylene ether);
5 to 50 parts by weight of a hydrogenated block copolymer of an alkenyl aromatic monomer and a conjugated diene;
1 to 15 parts by weight of a polypropylene;
2 to 10 parts by weight of a polybutene having a number average molecular weight of 500 to 1500 grams/mole;
10 to 45 parts by weight of a flame retardant;
0.5 to 10 parts by weight of an ultraviolet absorbing agent; and
0.5 to 10 parts by weight of a poly(alkylene oxide);

wherein all parts by weight are based on 100 parts by weight total of flame retardants and polymers other than the poly(alkylene oxide).

17. The jacketed cable of claim 16 , wherein the composition comprises
17 to 30 parts by weight of the poly(phenylene ether),
7 to 17 parts by weight of the hydrogenated block copolymer,
2 to 7 parts by weight of the polypropylene,
3 to 9 parts by weight of the polybutene,
20 to 30 parts by weight of a copolymer of monomers comprising ethylene and a C 3 -C 12 alpha-olefin,
28 to 38 parts by weight of the flame retardant,
1 to 4 parts by weight of the ultraviolet absorbing agent, and
1 to 4 parts by weight of the poly(alkylene oxide).

18. The jacketed cable of claim 17 ,
wherein the poly(phenylene ether) is a poly(2,6-dimethyl-1,4-phenylene ether) having an intrinsic viscosity of 0.35 to 0.5 deciliter per gram;

Assignees

• Sabic Global Technologies Bv

Inventors

• Peng Hui
• Shan Wei

Classifications

• H01B3/427

  Polyethers · CPC title

• C08L71/123 Primary

  not modified by chemical after-treatment · CPC title

• C08G2650/58

  Ethylene oxide or propylene oxide copolymers, e.g. pluronics · CPC title

• C08K2003/2224

  Magnesium hydroxide · CPC title

• H01B3/441

  from alkenes · CPC title