Catalysts for conversion of 2,3-butanediol-containing fermentation mixture to hydrocarbons

Patent metadata

Field	Value
Publication number	US-10300474-B2
Application number	US-201816059512-A
Country	US
Kind code	B2
Filing date	Aug 9, 2018
Priority date	Aug 14, 2017
Publication date	May 28, 2019
Grant date	May 28, 2019

Abstract

A method for producing one or more hydrocarbon compounds from at least one of 2,3-butanediol, acetoin, and ethanol, the method comprising contacting said at least one of 2,3-butanediol, acetoin, and ethanol with a catalyst at a temperature of at least 100° C. and up to 500° C. to result in said 2,3-butanediol, acetoin, and/or ethanol being converted to said one or more hydrocarbon compounds, wherein said catalyst is either: (i) a catalyst comprising nanoparticles composed of (a) a first metal oxide selected from the group consisting of zirconium oxide, cerium oxide, titanium oxide, and lanthanum oxide, and (b) a main group metal oxide; or (ii) a catalyst comprising a zeolite loaded with at least one metal selected from the group consisting of copper, silver, nickel, palladium, platinum, rhodium, and ruthenium in an amount of 1-30 wt % by weight of the zeolite.

First claim

What is claimed is:

1. A method for producing one or more hydrocarbon compounds from a reactant source comprising 2,3-butanediol or acetoin, the method comprising contacting said reactant source with a catalyst at a temperature of at least 100° C. and up to 500° C. to result in said reactant source being converted to said one or more hydrocarbon compounds, wherein said catalyst is either:
(i) a catalyst comprising nanoparticles composed of (a) a first metal oxide selected from the group consisting of zirconium oxide, cerium oxide, titanium oxide, and lanthanum oxide, and (b) a main group metal oxide; or
(ii) a catalyst comprising a zeolite loaded with at least one metal selected from the group consisting of copper, silver, nickel, palladium, platinum, rhodium, and ruthenium in an amount of 1-30 wt % by weight of the zeolite.

2. The method of claim 1 , wherein said reactant source is an aqueous solution, and said catalyst is contacted with said aqueous solution at said temperature.

3. The method of claim 1 , wherein said reactant source is an aqueous 2,3-butanediol fermentation mixture comprising 2,3-butanediol, acetoin, and ethanol, and said catalyst is contacted with said aqueous 2,3-butanediol fermentation mixture at said temperature.

4. The method of claim 3 , wherein said aqueous 2,3-butanediol fermentation mixture contains water in an amount of at least 20 wt %.

5. The method of claim 3 , wherein said aqueous 2,3-butanediol fermentation mixture contains water in an amount of at least 50 wt %.

6. The method of claim 1 , wherein said catalyst is (i) a catalyst comprising nanoparticles composed of (a) a first metal oxide selected from the group consisting of zirconium oxide, cerium oxide, titanium oxide, and lanthanum oxide, and (b) a main group metal oxide.

7. The method of claim 1 , wherein said catalyst is (i) a catalyst comprising nanoparticles composed of (a) a first metal oxide selected from the group consisting of zirconium oxide, cerium oxide, titanium oxide, and lanthanum oxide, (b) a main group metal oxide, and (c) an auxiliary metal oxide selected from the group consisting of zinc oxide, alkali oxides, and alkaline earth oxides.

8. The method of claim 6 , wherein said first metal oxide comprises zirconium oxide.

9. The method of claim 6 , wherein said main group metal oxide comprises silicon dioxide, aluminum oxide, or a combination thereof.

10. The method of claim 6 , wherein said nanoparticles have a core-shell structure containing a core composed of said main group metal oxide and a shell composed of said first metal oxide selected from the group consisting of zirconium oxide, cerium oxide, titanium oxide, and lanthanum oxide, wherein said shell at least partially encapsulates said core.

11. The method of claim 10 , wherein said first metal oxide comprises zirconium oxide.

12. The method of claim 1 , wherein said catalyst is (ii) a catalyst comprising a zeolite loaded with at least one metal selected from the group consisting of copper, silver, nickel, palladium, platinum, rhodium, and ruthenium in an amount of 1-30 wt % by weight of the zeolite.

13. The method of claim 12 , wherein said zeolite is a pentasil zeolite.

14. The method of claim 13 , wherein said pentasil zeolite is a ZSM type of zeolite.

15. The method of claim 12 , wherein said zeolite is selected from the group consisting of MFI, BEA, MWW, and zeolite Y types of zeolites.

16. The method of claim 12 , wherein said zeolite is a 2D pillared zeolite.

17. The method of claim 16 , wherein said 2D pillared zeolite is selected from the group consisting of pillared MFI and MWW zeolites.

18. The method of claim 1 , wherein said one or more hydrocarbon compounds includes at least one compound selected from the group consisting of methyl ethyl ketone, alkenes containing 2-8 carbon atoms, 1,3-butadiene, and 2-methylpropanal.

19. The method of claim 1 , wherein said one or more hydrocarbon compounds includes butenes and/or 1,3-butadiene produced in greater than 50% yield.

20. The method of claim 1 , wherein said one or more hydrocarbon compounds includes methyl ethyl ketone produced in greater than 50% yield.

21. The method of claim 1 , further comprising converting the one or more hydrocarbon compounds produced in the process of claim 1 to a synthetic fossil fuel by contacting the one or more hydrocarbon compounds, at a temperature of at least 100° C. and up to 500° C., with an additional catalyst capable of converting the hydrocarbon compounds to a synthetic fossil fuel.

Assignees

• Ut Battelle Llc

Inventors

• Li Zhenglong

Classifications

• C07C15/46

  Styrene; Ring-alkylated styrenes · CPC title

• B01J29/7038

  MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25 · CPC title

• B01J35/0006 Primary

  Operations & Transport · mapped topic

• B01J23/10

  of rare earths · CPC title

• B01J29/46

  Iron group metals or copper · CPC title