Process for the recovering of paraxylene

Patent metadata

Field	Value
Publication number	US-10300404-B2
Application number	US-201715600517-A
Country	US
Kind code	B2
Filing date	May 19, 2017
Priority date	Jun 30, 2016
Publication date	May 28, 2019
Grant date	May 28, 2019

Abstract

Disclosed herein are processes for recovering paraxylene in which a first simulated moving bed adsorption unit is used to produce a paraxylene-rich extract stream that also contains a significant amount of the ethylbenzene and a paraxylene-depleted raffinate stream. Because a significant amount of the ethylbenzene is removed in the paraxylene-rich extract stream (at least enough to limit buildup in the isomerization loop), the paraxylene-depleted raffinate stream may be isomerized in the liquid phase. Avoiding vapor phase isomerization saves energy and capital, as liquid phase isomerization requires less energy and capital than the vapor phase isomerization process due to the requirement of vaporizing the paraxylene-depleted stream and the use of hydrogen, which requires an energy- and capital-intensive hydrogen recycle loop.

First claim

The invention claimed is:

1. A process for recovering paraxylene, the process comprising:
(a) introducing a hydrocarbon feed stream into a first simulated moving bed adsorption unit, wherein the hydrocarbon feed stream comprises a mixture of paraxylene (PX), metaxylene (MX), orthoxylene (OX), and ethylbenzene (EB);
(b) introducing a desorbent stream into the first simulated moving bed adsorption unit, wherein the desorbent stream comprises desorbent;
(c) withdrawing a first PX-rich extract stream from the first simulated moving bed adsorption unit, wherein the first PX-rich extract stream comprises desorbent, PX, and EB, where at least 5 wt % of the EB in the hydrocarbon feed stream is recovered in the first PX-rich extract steam;
(d) withdrawing a first PX-depleted raffinate stream from the first simulated moving bed adsorption unit, wherein the first PX-depleted raffinate stream comprises desorbent, MX, OX, and EB;
(e) isomerizing at least a portion of the first PX-depleted raffinate stream at least partially in the liquid phase to produce a first isomerized stream having a higher PX concentration than the first PX-depleted raffinate stream;
(f) recycling at least a portion of the first isomerized stream to the first simulated moving bed adsorption unit; and
(g) introducing the first PX-rich extract stream to a PX recovery unit to recover a pure PX stream and a pure EB stream.

2. The process of claim 1 , wherein the step (g) comprises:
(g1) introducing the first PX-rich extract stream to the PX recovery unit; and
(g2) recovering a second PX-rich extract stream from the PX recovery unit.

3. The process of claim 2 , wherein the PX recovery unit is a second simulated moving bed adsorption unit.

4. The process of claim 3 , wherein the step (g) further comprises:
(g3) recovering an EB-rich stream from the second simulated moving bed adsorption unit; and
(g4) providing the EB-rich stream to a fractionation column to produce the pure EB stream.

5. The process of claim 1 , further comprising removing desorbent from the first PX-rich extract stream before the step (g).

6. The process of claim 3 , wherein the second simulated moving bed adsorption unit comprises a different adsorbent than the first simulated moving bed absorption unit.

7. The process of claim 3 , wherein a conventional simulated moving bed adsorption unit comprising 24 adsorbent beds, divided into two columns of 12 adsorbent beds each, is retrofitted such that the first column functions as the first simulated moving bed adsorption unit and the second column functions as the second simulated moving bed adsorption unit.

8. The process of claim 1 , wherein the recovery unit is a crystallizer.

9. A process for recovering paraxylene, the process comprising:
(a) providing a hydrocarbon feed stream and a desorbent stream to a first simulated moving bed adsorption unit, wherein the hydrocarbon feed stream comprises a mixture of paraxylene (PX), metaxylene (MX), orthoxylene (OX), and ethylbenzene (EB), and the desorbent stream comprises desorbent;
(b) withdrawing from the first simulated moving bed adsorption unit:
(i) a first PX-rich extract stream, which comprises desorbent, PX, and EB;
(ii) a PX-depleted raffinate stream, which comprises desorbent, MX, OX, and EB,

wherein the first PX-rich extract stream is withdrawn at a location to include at least 5 wt % of the EB in the hydrocarbon feed stream;
(c) isomerizing at least a portion of the PX-depleted raffinate stream at least partially in the liquid phase to produce an isomerized stream having a higher PX concentration than the first PX-depleted raffinate stream;
(d) recycling at least a portion of the isomerized stream to the first simulated moving bed adsorption unit;
(e) providing the first PX-rich extract stream to a second simulated moving bed adsorption unit to produce a second PX-rich extract stream and an EB-rich stream; and
(f) recovering a pure PX stream from the second PX-rich extract stream and a pure EB stream from the EB-rich stream.

10. The process of claim 9 , further comprising removing desorbent from the first PX-rich extract stream before the step (e).

11. The process of claim 10 , wherein the first PX-rich extract stream comprises at least 15 wt % of the EB in the hydrocarbon feed stream to the first simulated moving bed adsorption unit.

12. The process of claim 11 , wherein the second simulated moving bed adsorption unit comprises a different adsorbent than the first simulated moving bed absorption unit.

13. The process of claim 12 , wherein paradiethylbenzene is used as a desorbent in the second simulated moving bed adsorption unit and the step (f) comprises providing the second PX-rich extract stream to an extract column to remove desorbent and produce a desorbent-free PX-rich extract stream and providing the desorbent-free PX-rich extract stream to a finishing column to produce the pure PX stream.

14. The process of claim 12 , wherein toluene is used as a desorbent in the second simulated moving bed adsorption unit and the step (f) comprises providing the second PX-rich extract stream to a finishing column to produce the pure PX stream.

15. The process of claim 9 , wherein the step (f) further comprises providing the EB-rich stream to a fractionation column to produce the pure EB stream.

16. The process of claim 9 , further comprising removing C 9+ hydrocarbons from the hydrocarbon feed stream in a xylenes fractionation column prior to the step (a).

17. A process for recovering paraxylene, the process comprising:
(a) providing a hydrocarbon feed stream and a desorbent stream to a simulated moving bed adsorption unit, wherein the hydrocarbon feed stream comprises a mixture of paraxylene (PX), metaxylene (MX), orthoxylene (OX), and ethylbenzene (EB) and the desorbent stream comprises desorbent;
(b) withdrawing from the simulated moving bed adsorption unit:
(i) a first PX-rich extract stream, which comprises desorbent, PX, and EB;
(ii) a PX-depleted raffinate stream, which comprises desorbent, MX, OX, and EB;

wherein the first PX-rich extract stream is withdrawn at a location to include at least 5 wt % of the EB in the hydrocarbon feed stream;
(c) isomerizing at least a portion of the PX-depleted raffinate stream at least partially in the liquid phase to produce an isomerized stream having a higher PX concentration than the PX-depleted raffinate stream;
(d) recycling at least a portion of the isomerized stream to the simulated moving bed adsorption unit; and
(e) providing the first PX-rich extract stream to a crystallizer to produce a second PX-rich extract stream and an EB stream.

18. The process of claim 17 , further comprising removing desorbent from the first PX-rich extract stream before the step (e).

19. The process of claim 18 , wherein the first PX-rich extract stream comprises at least 15 wt % of the EB introduced to the simulated moving bed adsorption unit.

20. The process of claim 19 , further comprising:
(f) providing the second PX-rich extract stream to an extract column to remove desorbent and produce a desorbent-free PX-rich extract stream; and
(g) providing the desorbent-free PX-rich extract stream to a finishing column to produce a pure PX stream.

21. The process of claim 1 , wherein the process does not use a vapor-phase isomerization reactor to isomerize a feed comprising xylenes.

22. The process of claim 21 , further comprising:
(h) isomerizing at least a portion of the EB in the pure EB str

Assignees

• Exxonmobil Chemical Patents Inc

Inventors

• Dorsi Catherine M
• Agrawal Gaurav
• Weber Michael W
• Pilliod Dana L
• Porter John R

Classifications

• B01D2255/50

  Zeolites · CPC title

• C07C7/005

  Processes comprising at least two steps in series · CPC title

• B01D3/065

  Multiple-effect flash distillation (more than two traps) · CPC title

• C07C7/12

  by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers · CPC title

• B01D15/1828 Primary

  characterised by process features · CPC title