Polymer nanofiber structural body and polymer nanofiber composite using the structural body, and methods of producing the structural body and the composite
US-2015273812-A1 · Oct 1, 2015 · US
US10294595B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10294595-B2 |
| Application number | US-201514879227-A |
| Country | US |
| Kind code | B2 |
| Filing date | Oct 9, 2015 |
| Priority date | Oct 21, 2014 |
| Publication date | May 21, 2019 |
| Grant date | May 21, 2019 |
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A polymer nanofiber sheet including polymer nanofibers having a polymer, the polymer nanofibers being accumulated and three dimensionally entangled. The polymer nanofiber sheet has a low molecular weight organic compound containing at least one 4- or higher-membered ring structure with an ether linkage. The difference between the average solubility parameter of the polymer and the average solubility parameter of the low molecular weight organic compound is less than 8 (J/cm3)1/2.
Opening claim text (preview).
What is claimed is: 1. A polymer nanofiber sheet comprising polymer nanofibers each of which comprises a polymer, the polymer nanofibers being accumulated, three-dimensionally entangled, and in contact with each other, wherein the polymer nanofiber sheet has a tensile elastic modulus of 100 MPa to 480 MPa, wherein the polymer is a polyamide, a polyamide imide, a polymethyl methacrylate, or a polyethylene terephthalate, wherein a low molecular weight organic compound is on a surface of respective said polymer nanofibers and in the respective said polymer nanofibers, wherein the polymer nanofibers are crosslinked with each other by a chemical reaction between the polymer in each of the polymer nanofibers and the low molecular weight organic compound interposed between the polymer nanofibers at a position where the polymer nanofibers are in contact with each other, and wherein the low molecular weight organic compound is a compound of formula (1): 2. The polymer nanofiber sheet according to claim 1 , wherein the low molecular weight organic compound is contained in an amount of 60% by weight or less with respect to a total weight of the polymer and the low molecular weight organic compound. 3. The polymer nanofiber sheet according to claim 1 , wherein the polymer nanofiber sheet has a film thickness of 0.1 μm to less than 1 mm. 4. The polymer nanofiber sheet according to claim 1 , wherein the polymer nanofiber sheet has pores having an average pore diameter of 10 nm to 50 μm. 5. The polymer nanofiber sheet according to claim 1 , wherein the polymer nanofibers have an average diameter of 50 nm to less than 3000 nm.
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