Rapidly solidified high-temperature aluminum iron silicon alloys

Patent metadata

Field	Value
Publication number	US-10294552-B2
Application number	US-201615384889-A
Country	US
Kind code	B2
Filing date	Dec 20, 2016
Priority date	Jan 27, 2016
Publication date	May 21, 2019
Grant date	May 21, 2019

Abstract

Methods of making high-strength, lightweight alloy components capable of high temperature performance comprising aluminum, silicon, and iron and/or nickel are provided. A high-energy stream, such as a laser or electron beam, may be selectively directed towards a precursor material to melt a portion of the precursor material in a localized region. The molten precursor material is cooled at a rate of greater than or equal to about 1.0×10 5 K/second to form a solid high-strength, lightweight alloy component comprising a stable ternary cubic phase having high heat resistance and high strength. The stable ternary phase may be Al x Fe y Si z , where x ranges from about 4 to about 5 or about 7.2 to about 7.6, y is about 1.5 to about 2.2, and z is about 1. The stable ternary phase may also be Al 6 Ni 3 Si. Materials and components, such as automotive components, made from such methods are also provided.

First claim

What is claimed is:

1. A method of making a high-strength, lightweight alloy component comprising:
directing an energy stream towards a precursor material in a localized region to melt a portion of the precursor material in the localized region, wherein the precursor material comprises aluminum, silicon, and iron; and
cooling the molten precursor material at a rate of greater than or equal to about 1.0×10 5 K/second to form a solid high strength, lightweight alloy component comprising a stable Al x Fe y Si z phase, wherein x ranges from about 4 to about 5 or about 7.2 to about 7.6, y is about 1.5 to about 2.2, and z is about 1.

2. The method of claim 1 , wherein the solid high-strength lightweight alloy component comprises greater than or equal to about 50% by volume of the stable Al x Fe y Si z phase.

3. The method of claim 1 , wherein the stable Al x Fe y Si z phase has a formula represented by Al 4 Fe 1.7 Si or Al 5 Fe 2 Si, with a composition comprising aluminum at greater than or equal to about 64.5 to less than or equal to about 66 atomic weight %; iron at about 24.5 atomic weight %; and silicon at greater than or equal to about 9.5 to less than or equal to about 11 atomic weight %.

4. The method of claim 1 , wherein the stable Al x Fe y Si z phase has an (a) lattice parameter of about 0.7509 nm and a (c) lattice parameter of about 0.7594 nm and a space group of P6 3 /mmc.

5. The method of claim 1 , wherein the solid high-strength lightweight alloy component comprises greater than or equal to about 80% by volume of the stable Al x Fe y Si z phase.

6. The method of claim 1 , wherein the precursor material further comprises less than or equal to about 0.5 mass % of an alloying element selected from the group consisting of: manganese, copper, and combinations thereof, wherein the stable Al x Fe y Si z phase is formed by converting an intermediate phase having a formula represented by Al 7.4 Fe 2 Si to a hexagonal crystal structure by incorporation of the alloying element.

7. The method of claim 1 , wherein the cooling of the molten precursor material is at a rate of greater than or equal to about 1.0×10 7 K/second.

8. The method of claim 1 , wherein the precursor material is a powder material.

9. The method of claim 8 , wherein the powder material is a combination of elemental powders or a pre-alloyed powder.

10. The method of claim 1 , wherein the localized region has a volumetric size of less than or equal to about 100 μm 3 .

11. A method of making a high-strength, lightweight alloy component comprising:
directing an energy stream towards a precursor material in a localized region to melt a portion of the precursor material in the localized region, wherein the precursor material comprises aluminum, silicon, and at least one of iron or nickel; and
cooling the molten precursor material at a rate of greater than or equal to about 1.0×10 5 K/second to form a solid high-strength, lightweight alloy component comprising a stable ternary phase comprising aluminum, silicon, and at least one of iron or nickel having high heat resistance and high strength.

12. The method of claim 11 , wherein the solid high-strength lightweight alloy component comprises greater than or equal to about 80% by volume of the stable ternary phase and the stable ternary phase is Al x Fe y Si z , wherein x ranges from about 4 to about 5 or about 7.2 to about 7.6, y is about 1.5 to about 2.2, and z is about 1.

13. The method of claim 11 , wherein the solid high-strength lightweight alloy component comprises greater than or equal to about 80% by volume of the stable ternary phase and the stable ternary phase is Al 6 Ni 3 Si, comprising aluminum at greater than or equal to about 58.6 to less than or equal to about 61 atomic weight %; nickel at about 30 atomic weight %; and silicon at greater than or equal to about 9 to less than or equal to about 11.4 atomic weight %.

14. A method of making a high-strength, lightweight alloy component comprising:
directing a high-energy stream selected from the group consisting of: direct metal laser sintering, electron beam direct metal melting systems, and combinations thereof towards a precursor material in a localized region to melt a portion of the precursor material in the localized region, wherein the precursor material comprises aluminum, silicon, and iron and a temperature within the localized region is raised to greater than or equal to about 997° C.; and
cooling the molten precursor material at a rate of greater than or equal to about 1.0×10 5 K/second to form a solid high strength, lightweight alloy component comprising a stable Al x Fe y Si z phase, wherein x ranges from about 4 to about 5 or about 7.2 to about 7.6, y is about 1.5 to about 2.2, and z is about 1.

Assignees

• Gm Global Tech Operations Llc

Inventors

• Liu Zhongyi
• Sachdev Anil K

Classifications

• C22C1/11

  Making amorphous alloys · CPC title

• B22F10/28

  Powder bed fusion, e.g. selective laser melting [SLM] or electron beam melting [EBM] · CPC title

• B33Y10/00

  Processes of additive manufacturing · CPC title

• B33Y80/00

  Products made by additive manufacturing · CPC title

• C22C21/00

  Alloys based on aluminium · CPC title