Heat resistant spheroidal graphite cast iron, method of manufacturing the same and engine exhaust system part including the same

Patent metadata

Field	Value
Publication number	US-10294550-B2
Application number	US-201515125477-A
Country	US
Kind code	B2
Filing date	Feb 6, 2015
Priority date	Mar 12, 2014
Publication date	May 21, 2019
Grant date	May 21, 2019

Abstract

Heat resistant spheroidal graphite cast iron having an improved high temperature tensile strength includes carbon (C) in a range of 3.2-3.4 wt %, silicon (Si) in a range of 4.3-4.8 wt %, manganese (Mn) in a range of 0.2-0.3 wt %, molybdenum (Mo) in a range of 0.8-1.0 wt %, vanadium (V) in a range of 0.4-0.6 wt %, chrome (Cr) in a range of 0.2-0.4 wt %, niobium (Nb) in a range of 0.2-0.4 wt %, inevitable impurities, and a remainder of iron (Fe) based on a total weight of the heat resistant spheroidal graphite cast iron. The heat resistant spheroidal graphite cast iron further includes barium (Ba) in a range of 0.0045-0.0075 wt %. A content ratio of chrome (Cr) and barium (Ba) (Cr/Ba) is in a range from about 26 to about 89.

First claim

What is claimed is:

1. A heat resistant spheroidal graphite cast iron for an engine component, comprising:
carbon (C) in a range from 3.2 weight percent to 3.4 weight percent, silicon (Si) in a range from 4.3 weight percent to 4.8 weight percent, manganese (Mn) in a range from 0.2 weight percent to 0.3 weight percent, molybdenum (Mo) in a range from 0.8 weight percent to 1.0 weight percent, vanadium (V) in a range from 0.4 weight percent to 0.6 weight percent, chrome (Cr) in range from 0.2 weight percent to 0.4 weight percent, niobium (Nb) in a range from 0.2 weight percent to 0.4 weight percent, barium (Ba) in a range from 0.0045 weight percent to 0.0075 weight percent, inevitable impurities, and a remainder of iron (Fe), based on a total weight of the heat resistant spheroidal graphite cast iron,
wherein a content ratio of chrome (Cr) and barium (Ba) (Cr/Ba) is in a range from 26 to 89.

2. The heat resistant spheroidal graphite cast iron of claim 1 , wherein the heat resistant spheroidal graphite cast iron has tensile strength of about 670 Mpa or more at a room temperature, and has high temperature tensile strength of 100 Mpa or more at 700° C. and of 59 Mpa or more at 800° C.

3. The heat resistant spheroidal graphite cast iron of claim 1 , wherein the heat resistant spheroidal graphite cast iron has a thermal expansion coefficient of about 13.5 μm/m·° C. or less, and has eutectoid transformation temperature of from about 920° C. to about 940° C.

4. The heat resistant spheroidal graphite cast iron of claim 1 , wherein the heat resistant spheroidal graphite cast iron has high temperature tensile strength of from 59 Mpa to 70 Mpa at 800° C.

5. The heat resistant spheroidal graphite cast iron of claim 1 , wherein the heat resistant spheroidal graphite cast iron comprises a ferrite structure occupying an area of about 50% or more and a pearlite structure occupying an area of 40% or less in a total area, and
wherein graphite having a spheroidal shape is precipitated in the ferrite structure and carbide is precipitated in the pearlite structure.

6. A component of engine exhaust system comprising the heat resistant spheroidal graphite cast iron according to claim 1 .

7. A method of manufacturing heat resistant spheroidal graphite cast iron, comprising:
forming a molten cast iron including carbon (C) in a range from about 3.2 weight percent to about 3.4 weight percent, silicon (Si) in a range from about 4.3 weight percent to about 4.8 weight percent, manganese (Mn) in a range from about 0.2 weight percent to about 0.3 weight percent, molybdenum (Mo) in a range from about 0.8 weight percent to about 1.0 weight percent, vanadium (V) in a range from about 0.4 weight percent to about 0.6 weight percent, chrome (Cr) in a range from about 0.2 weight percent to about 0.4 weight percent, niobium (Nb) in a range from about 0.2 weight percent to about 0.4 weight percent, inevitable impurities, and a remainder of iron (Fe), based on a total weight;
tapping the molten cast iron into a ladle; and
injecting the tapped molten cast iron into a mold
wherein, prior to injecting the tapped molten cast iron into the mold, barium (Ba) is added into the molten cast iron in a range from about 0.0045 weight percent to about 0.0075 weight percent, and a content ratio of chrome (Cr) and barium (Ba) (Cr/Ba) is in a range from about 26 to 89.

8. The method of claim 7 , wherein tapping the molten cast iron into the ladle comprises adding a first inoculants into the molten cast iron, and wherein injecting the tapped molten cast iron into the mold comprises adding a second inoculant into the molten cast iron.

9. The method of claim 7 , wherein forming the molten cast iron comprises
forming a preliminary molten cast iron;
analyzing the preliminary molten cast iron by a thermal analysis or a mass spectrometer; and
adding a deficient ingredient into the preliminary molten cast iron.

Assignees

• Doosan Infracore Co Ltd

Inventors

• Ju Young-Kyu
• Jung Ki-Hwan
• Chung Jong-Kwon
• Yang Sik
• Hwang Jae-Hyoung
• Shim Dong-Seob
• Kim Sang-Beom

Classifications

• C21D2211/004

  Dispersions; Precipitations · CPC title

• H01J49/26

  Mass spectrometers or separator tubes · CPC title

• B22D25/02

  by its peculiarity of shape; of works of art {(cylinders, pistons B22D15/02)} · CPC title

• C22C33/08

  Making cast-iron alloys · CPC title

• G01N25/00

  Investigating or analyzing materials by the use of thermal means (G01N3/00 - G01N23/00 take precedence) · CPC title