Lecithin and plasticizer compositions and methods

Patent metadata

Field	Value
Publication number	US-10294376-B2
Application number	US-201414324770-A
Country	US
Kind code	B2
Filing date	Jul 7, 2014
Priority date	Nov 12, 2008
Publication date	May 21, 2019
Grant date	May 21, 2019

Abstract

The present disclosure is directed to compositions having lecithin and plasticizer components and related methods. The disclosed compositions may also include one or more co-surfactants such as anionic surfactants and/or non-ionic surfactants.

First claim

What is claimed is:

1. A method of dispersing a pigment in a paint, the method comprising:
mixing a bio-derived dispersant and the pigment with a paint formulation;
wherein the bio-derived dispersant comprises lecithin and a plasticizer selected from the group consisting of a citrate, an adipate, a pentaerythritol ester, an isosorbide ester, and combinations of any thereof.

2. The method according to claim 1 , wherein bio-derived dispersant further comprises a plasticizer selected from the group consisting of propylene glycol monoester (PGME), butyl benzyl phthalate (BBP), di-n-butyl maleate (DBM), di-n-butyl phthalate (DBP), diethylene glycol dibenzoate (DEGD), di(2-ethylhexyl) phthalate (DEHP), dioctyl phthalate (DOP), diethyl phthalate (DEP), diisobutyl phthalate (DIBP), diisodecyl adipate (DIDA), diisodecyl phthalate (DIDP), diisoheptyl phthalate (DIHP), diisononyl adipate (DINA), diisononyl cyclohexane-1,2-dicarboxylate (DINCH), diisononyl phthalate (DINP), diisooctyl adipate (DIOA), diisooctyl phthalate (DIOP), dimenthyl phthalate (DMP), di-n-hexyl phthalate (DnHP), di-n-octyl adipate (DnOA), di-n-octyl phthalate (DnOP), dinonyl phthalate (DNP), dioctyl adipate (DOA), di-(2-ethylhexyl) adipate (DEHA), dioctyl maleate (DOM), dioctyl sebacate (DOS), dioctyl terephalate (DOTP), dioctyl azelate (DOZ), dipropylene glycol dibenzoate (DPGB), di(2-propylheptyl) phthalate (DPHP), ditridecyl adipate (DTDA), ditridecyl phthalate (DTDP), diundecyl phthalate (DUP), 2-ethylhexanol (2-EH), epoxidized linseed oil (ELO), epoxidized soybean oil (ESO), general-purpose phthalate (GPP), isodecyl alcohol (IDA), isononyl alcohol (INA), phthalic anhydride (PA), 2-propylheptanol (2-PH), polyvinyl chloride (PVC), tricresyl phosphate (TCP), triisononyl trimellitate (TINTM), triisooctyl trimellitate (TIOTM), trimellitic anhydride (TMA), trioctyl trimellitate (TOTM), triphenyl phosphate (TPP), trixylyl phosphate (TXP), undecyl dodecyl phthalate (UDP), soybean oil, medium chain triglycerides, a polyglycerol ester and combinations of any thereof.

3. The method according to claim 1 , wherein the lecithin is selected from the group consisting of crude filtered lecithin, de-oiled lecithin, chemically modified lecithin, enzymatically modified lecithin, standardized lecithin, and combinations of any thereof.

4. The method according to claim 1 , wherein:
the lecithin comprises from 5% to 95% by weight of the bio-derived dispersant, and
the plasticizer comprises from 5% to 95% by weight of the bio-derived dispersant.

5. The method according to claim 1 , wherein the bio-derived dispersant comprises less than 5 g/L of volatile organic compounds.

6. The method according to claim 1 , wherein the bio-derived dispersant further comprises a surfactant selected from the group consisting of an anionic surfactant, a non-ionic surfactant and combinations of any thereof.

7. The method according to claim 6 , wherein the surfactant has a hydrophilic-lipophilic balance of between 10.0 and 24.0.

8. The method according to claim 6 , wherein the non-ionic surfactant is selected from the group consisting of sorbitan monostearate, polyoxyethylene ester of rosin, polyoxyethylene dodecyl mono ether, polyoxyethylene-polyoxypropylene block copolymer, polyoxyethylene monolaurate, polyoxyethylene monohexadecyl ether, polyoxyethylene monooleate, polyoxyethylene mono(cis-9-octadecenyl)ether, polyoxyethylene monostearate, polyoxyethylene monooctadecyl ether, polyoxyethylene dioleate, polyoxyethylene distearate, polyoxyethylene sorbitan monolaurate polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan monopalmitate, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan trioleate, polyoxyethylene sorbitan tristearate, polyglycerol ester of oleic acid, polyoxyethylene sorbitol hexastearate, polyoxyethylene monotetradecyl ether, polyoxyethylene sorbitol hexaoleate, fatty acids, tall-oil, sorbitol hexaesters, ethoxylated castor oil, ethoxylated soybean oil, ethoxylated polyoxyethylene sorbitol tetraoleate, glycerol and polyethylene glycol mixed esters, alcohols, polyglycerol esters, monoglycerides, sucrose esters, derivatives of any thereof, and combinations of any thereof.

9. The method according to claim 6 , wherein the anionic surfactant is selected from the group consisting of sodium and potassium salts of straight-chain fatty acids, polyoxyethylenated fatty alcohol carboxylates, linear alkyl benzene sulfonates, alpha olefin sulfonates, sulfonated fatty acid methyl ester, arylalkanesulfonates, sulfosuccinate esters, alkyldiphenylether(di)sulfonates, alkylnaphthalenesulfonates, isoethionates, alkylether sulfates, sulfonated oils, fatty acid monoethanolamide sulfates, polyoxyethylene fatty acid monoethanolamide sulfates, aliphatic phosphate esters, nonylphenolphosphate esters, fluorinated anionics, and combinations of any thereof.

10. The method according to claim 1 , wherein the pigment is selected from the group consisting of an organic pigment, an inorganic pigment, a carbon black pigment, and any combinations thereof.

11. The method according to claim 1 , wherein the bio-derived dispersant has a viscosity of 2,000 centipoise or less at 25° C.

12. The method according to claim 1 , wherein the pigment is titanium dioxide, aluminum silicate, or a combination thereof.

13. A method of dispersing a pigment in a paint base, the method comprising:
mixing a bio-derived dispersant comprising a plasticizer selected from the group consisting of a citrate, an adipate, a pentaerythritol ester, an isosorbide ester, and combinations of any thereof with the paint base; and
mixing a pigment with the paint base.

14. The method according to claim 13 , wherein the bio-derived dispersant comprises lecithin and a surfactant having a hydrophilic-lipophilic balance of between 10.0 and 24.0.

15. The method according to claim 13 , wherein the bio-derived dispersant comprises lecithin.

16. The method according to claim 13 , wherein the pigment is titanium dioxide, aluminum silicate, or a combination thereof.

17. The method according to claim 13 , wherein the paint base is aqueous.

18. The method according to claim 13 , wherein the paint base is non-aqueous.

Assignees

• Baseeth Shireen
• Tabuena Salyers Teodora R
• Sebree Bruce
• Archer Daniels Midland Co

Inventors

• Baseeth Shireen
• Tabuena-Salyers Teodora R
• Sebree Bruce

Classifications

• C09B67/0089

  non ionic dispersing agent, e.g. EO or PO addition products · CPC title

• C09C1/48

  Carbon black · CPC title

• C01P2006/22

  Rheological behaviour as dispersion, e.g. viscosity, sedimentation stability · CPC title

• C09C1/56

  Treatment of carbon black {; Purification} · CPC title

• C09B67/0022

  Wet grinding of pigments · CPC title