Multi-modal polymer blend, hot melt adhesive comprising same and use thereof

Patent metadata

Field	Value
Publication number	US-10294357-B2
Application number	US-201515532659-A
Country	US
Kind code	B2
Filing date	Dec 1, 2015
Priority date	Dec 4, 2014
Publication date	May 21, 2019
Grant date	May 21, 2019

Abstract

A multi-modal polymer blend of at least three fractions as determined by TREF is provided. The blend comprises a first propylene-based polymer, a second propylene-based polymer; and a third propylene-based polymer; wherein when subjected to TREF, the polymer blend exhibits: a first fraction that is soluble at −15° C. in xylene, the first fraction having an isotactic (mm) triad tacticity of about 55 mol % to about 85 mol %; a second fraction that is insoluble at −5 C in xylene or dichlorobenzene and soluble at 40° C. in xylene or dichlorobenzene; and a third fraction that is insoluble at 70° C. in xylene or dichlorobenzene and having an isotactic (mm) triad tacticity of about 85 mol % to about 98 mol %. Also provided are hot melt adhesive compositions comprising the polymer blend, tackifier, wax; and optionally a nucleating agent, articles containing the adhesive and methods of fabricating the articles.

First claim

What is claimed is:

1. A multi-modal polymer blend of at least three fractions as determined by Temperature Rising Elution Fractionation, said blend comprising:
a first propylene-based polymer, wherein the first propylene-based polymer is a homopolymer of propylene or a copolymer of propylene and at least one member selected from the group consisting of ethylene and a C4 to C20 alpha-olefin;
a second propylene-based polymer, wherein the second propylene-based polymer is a homopolymer of propylene or a copolymer of propylene and at least one member selected from the group consisting of ethylene and a C4 to C20 alpha-olefin; wherein the second propylene-based polymer is different than the first propylene-based polymer; and
a third propylene-based polymer, wherein the third propylene-based polymer is a homopolymer of propylene or a copolymer of propylene and at least one member selected from the group consisting of ethylene and a C4 to C20 alpha-olefin; wherein the third propylene-based polymer is different than the first propylene-based polymer and the second propylene-based polymer;
wherein the multi-modal polymer blend has a Mw of about 5000 g/mol to about 250,000 g/mol; and
wherein, when subjected to Temperature Rising Elution Fractionation, the multi-modal polymer blend exhibits:
a first fraction that is soluble at −15° C. in xylene, the first fraction having an isotactic (mm) triad tacticity of about 55 mol % to about 85 mol %;
a second fraction that is insoluble at −5° C. in xylene or dichlorobenzene and soluble at 40° C. in xylene or dichlorobenzene, and
a third fraction that is insoluble at 70° C. in xylene or dichlorobenzene, the third fraction having an isotactic (mm) triad tacticity of about 85 mol % to about 98 mol %.

2. The multi-modal polymer blend according to claim 1 , which has a first fraction that is soluble at −15° C. accounting for at least 50 weight % of the multi-modal polymer.

3. The multi-modal polymer blend according to claim 1 , which has a Mw of about 10,000 g/mol to about 150,000 g/mol.

4. The multi-modal polymer blend according to claim 1 , which has a Mw of about 20,000 g/mol to about 60,000 g/mol.

5. The multi-modal polymer blend according to claim 1 , which has a MWD of about 1.8 to about 3.5.

6. The multi-modal polymer blend according to claim 1 , which has a MWD of about 1.9 to about 3.2.

7. The multi-modal polymer blend according to claim 1 , which has a MWD of about 2.0 to about 3.0.

8. The multi-modal polymer blend according to claim 1 , which is a three reactor blend.

9. The multi-modal polymer blend according to claim 1 , which is a solution blend.

10. The multi-modal polymer blend according to claim 1 , which is in the form of polymeric pellet.

11. The multi-modal polymer blend according to claim 1 , wherein the first propylene-based polymer comprises a copolymer of propylene and ethylene, the second propylene-based polymer comprises a copolymer of propylene and ethylene, and the third propylene-based polymer comprises a copolymer of propylene and ethylene.

12. A hot melt adhesive composition which comprises:
1) about 40 to about 97% by weight of the multi-modal polymer blend according to claim 1 ;
2) about 1 to about 30% by weight of at least one tackifier;
3) about 1 to about 30% by weight of at least one wax;
4) optionally about 0.01 to about 0.5% by weight of at least one nucleating agent; and
5) optionally about 0.01% by weight to 5% by weight of at least one plasticizer,
wherein the % by weight is based on the total weight of the hot melt adhesive composition.

13. The hot melt adhesive composition according to claim 12 , wherein the multi-modal polymer blend has a MWD of about 1.8 to about 3.5.

14. The hot melt adhesive composition according to claim 12 , which further comprises an antioxidant present in an amount of about 0.01 to about 1 wt. % of the hot melt adhesive composition.

15. An article comprising at least one substrate and a hot melt composition according to claim 12 .

16. The article according to claim 15 , wherein the article comprises a first substrate and a second substrate, wherein the first substrate and a second substrate are bonded together by the hot melt adhesive composition, being interposed between the first substrate and a second substrate.

17. The article according to claim 15 , wherein the article is used for packaging, straw attachment, spout bonding, bag closing, heat sealing, coating, bookbinding and filter assembly applications.

18. A method for manufacturing an article according to claim 15 , which comprises
(1) heating the hot melt adhesive composition to a temperature where it is completely molten;
(2) applying the hot melt adhesive composition to at least one surface of a first substrate to form an adhesive layer on the at least one surface of the first substrate, wherein said at least one surface is partly or completely covered by the adhesive layer; and
(3) solidifying the adhesive layer by actively cooling it or allowing it to cool to room temperature.

19. The method according to claim 18 , wherein after step (2), a second substrate is brought into contact with the hot melt adhesive layer on the first substrate.

20. The method according to claim 18 , wherein after step (3), the surface of the adhesive is remelted (“reactivated”) and a second substrate is brought into contact with the hot melt adhesive layer on the first substrate and cooled by actively cooling or allowing it to cool to room temperature.

Assignees

• Exxonmobil Chemical Patents Inc
• Henkel Ag & Co Kgaa
• Henkel Ag & Co —Kgaa

Inventors

• Schauder Jean-Roch
• Milleret Jean-Baptiste
• Hoffmann Gunter
• Gallagher Eamonn

Classifications

• C08L2207/10

  Peculiar tacticity · CPC title

• C09J123/142

  at least partially crystalline copolymers of propene with other olefins · CPC title

• C08L2205/025

  containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title

• C09J123/14

  Copolymers of propene (C09J123/16 takes precedence) · CPC title

• B32B7/12

  using interposed adhesives or interposed materials with bonding properties · CPC title