Fluoroelastomer component for contacting ammonia and/or urea

Patent metadata

Field	Value
Publication number	US-10294344-B2
Application number	US-201415036823-A
Country	US
Kind code	B2
Filing date	Dec 8, 2014
Priority date	Dec 9, 2013
Publication date	May 21, 2019
Grant date	May 21, 2019

Abstract

Described herein is a component for contacting ammonia and/or urea having a surface that in use will come into contact with urea and/or ammonia. The component comprises fluoroelastomer composition comprising fluoropolymer and a hydrotalcite compound.

First claim

What is claimed is:

1. A component for contacting ammonia and/or urea having a surface that is in contact with at least one of urea and ammonia, the surface comprising a fluoroelastomer composition comprising a fluoropolymer and a hydrotalcite compound, wherein the component is part of an exhaust system and wherein the fluoropolymer comprises 50 to 80% by moles of repeating units derived from vinylidene fluoride, tetrafluoroethylene, and hexafluoropropylene.

2. The component of claim 1 , wherein the hydrotalcite compound comprises a synthetic hydrotalcite compound.

3. The component of claim 1 , wherein the hydrotalcite compound corresponds to the formula:
[(M 1 2+ ) a (M 2 2+ ) b ](M 3+ ) y (OH) 2x+3y−2 (A n− ) y/n w H 2 O

wherein M 1 2+ represents at least one divalent metal selected from the group consisting of Mg2+, Ca2+, Sr2+ and Ba2+; M 2+ represents at least one divalent metal selected from the group consisting of Zn2+, Cd2+, Pb2+ and Sn2+; M 3+ represents a trivalent metal ion; A n− represents an n− valent anion; a and b each independently represents a value from 0 to 10, x represents a+b and has a value from 1 to 10, y represents an integer from 1 to 5, and w represents a real number.

4. The component of claim 1 , wherein the hydrotalcite compound is present in an amount of 0.1 to 20% by weight based on the fluoropolymer.

5. The component of claim 1 , wherein the hydrotalcite compound is a natural hydrotalcite compound.

6. The component of claim 1 , wherein the fluoroelastomer composition comprises the cured product of a curable composition comprising (i) a fluoropolymer having a partially fluorinated backbone and having a halogen and/or nitrile capable of participating in a peroxide cure reaction and (ii) an organic peroxide.

7. A method comprising utilizing a hydrotalcite compound in a fluoroelastomer composition of a component for contacting ammonia and/or urea to prevent or reduce swelling of the fluoroelastomer composition when the fluoroelastomer composition is contacted with at least one of urea and ammonia, wherein the component is part of an exhaust system and wherein a fluoropolymer of the fluoroelastomer composition comprises 50 to 80% by moles of repeating units derived from vinylidene fluoride, tetrafluoroethylene, and hexafluoropropylene.

8. The component of claim 1 , wherein the component is selected from at least one of a molded good, a hose, or an O-ring.

9. The method of claim 7 , wherein the hydrotalcite compound corresponds to the formula:
[(M 1 2+ ) a (M 2 2+ ) b ](M 3+ ) y (OH) 2x+3y−2 (A n− ) y/n w H 2 O

wherein M 1 2+ represents at least one divalent metal selected from the group consisting of Mg2+, Ca2+, Sr2+ and Ba2+; M 2 2+ represents at least one divalent metal selected from the group consisting of Zn2+, Cd2+, Pb2+ and Sn2+; M 3+ represents a trivalent metal ion; A n− represents an n− valent anion; a and b each independently represents a value from 0 to 10, x represents a+b and has a value from 1 to 10, y represents an integer from 1 to 5, and w represents a real number.

10. The method of claim 7 , wherein the component is a molded good, a hose, or an O-ring.

11. The method of claim 7 , wherein the fluoroelastomer composition comprises the cured product of a curable composition comprising (i) a fluoropolymer having a partially fluorinated backbone and having a halogen and/or a nitrogen capable of participating in a peroxide cure reaction and (ii) an organic peroxide.

12. The method of claim 7 , wherein the hydrotalcite compound is present in an amount of 0.1 to 20% by weight based on the fluoropolymer in the fluoroelastomer composition.

13. The component of claim 1 , wherein the surface is in contact with a solution comprising at least 10% by weight of at least one of urea and ammonia.

14. The method of claim 7 , wherein the fluoroelastomer composition is in contact with a solution comprising at least 10% by weight of at least one of urea and ammonia.

15. The component of claim 1 , wherein the fluoropolymer comprises at least one of bromine and iodine.

16. The component of claim 1 , wherein the component has improved swell resistance to ammonia and/or urea as compared to the same fluoroelastomer not comprising the hydrotalcite compound.

17. The component of claim 1 , wherein the fluoropolymer is further derived from fluorinated ethylenically unsaturated monomers.

18. The component of claim 17 , wherein the fluorinated ethylenically unsaturated monomers are selected from at least one of vinyl fluoride, perfluorinated vinyl ethers, and perfluorinated allyl ethers.

19. The method of claim 7 , wherein the fluoropolymer is further derived from fluorinated ethylenically unsaturated monomers.

20. The method of claim 19 , wherein the fluorinated ethylenically unsaturated monomers are selected from at least one of vinyl fluoride, perfluorinated vinyl ethers, and perfluorinated allyl ethers.

Assignees

• 3M Innovative Properties Co

Inventors

• Verschuere Alain

Classifications

• C08K5/14

  Peroxides · CPC title

• C08K2003/2227

  of aluminium · CPC title

• C08L27/12 Primary

  containing fluorine atoms · CPC title

• C08K3/22 Primary

  of metals · CPC title

• C08K2003/2217

  of magnesium · CPC title