Film layers and methods for forming the same

Patent metadata

Field	Value
Publication number	US-10294340-B2
Application number	US-201715646419-A
Country	US
Kind code	B2
Filing date	Jul 11, 2017
Priority date	Jul 27, 2016
Publication date	May 21, 2019
Grant date	May 21, 2019

Abstract

A film layer and a method of forming a film layer are provided herein. The film layer includes a first polymer and a second polymer. The first polymer includes the reaction product of chlorotrifluoroethene and vinylidene fluoride utilized in the first polymer in an amount of at least 4 wt. %. The second polymer includes the reaction product of chlorotrifluoroethene and optionally, vinylidene fluoride utilized in the second polymer in an amount of less than 4 wt. %. A multilayer film and a method of forming a multilayer film are also provided herein. In an embodiment, a multilayer film includes a first film layer and a second film layer adjacent and sealed to the first film layer. At least one of the first film layer or the second film layer includes the first polymer and the second polymer.

First claim

What is claimed is:

1. A film layer, comprising:
a first polymer comprising the reaction product of;
chlorotrifluoroethene, and
vinylidene fluoride utilized in said first polymer in an amount of at least 4 wt. % based on a total weight of all reactants utilized to form said first polymer; and

a second polymer comprising the reaction product of;
chlorotrifluoroethene, and
optionally, vinylidene fluoride utilized in said second polymer in an amount of less than 4 wt. % based on a total weight of all reactants utilized to form said second polymer.

2. The film layer of claim 1 , wherein said first polymer and said second polymer are homogeneously distributed in said film layer.

3. The film layer of claim 1 , wherein said second polymer is further defined as a homopolymer formed from chlorotrifluoroethene.

4. The film layer of claim 1 , wherein said second polymer is further defined as a copolymer comprising the reaction product of:
chlorotrifluoroethene; and
vinylidene fluoride utilized in said second polymer in an amount of less than 4 wt. % based on a total weight of all reactants utilized to form said second polymer.

5. A multilayer film, comprising:
a first film layer and a second film layer sealed to said first film layer, at least one of said first film layer or said second film layer comprising;
a first polymer comprising the reaction product of,
chlorotrifluoroethene, and
vinylidene fluoride utilized in said first polymer in an amount of at least 4 wt. % based on a total weight of all reactants utilized to form said first polymer, and

a second polymer comprising the reaction product of,
chlorotrifluoroethene, and
optionally, vinylidene fluoride utilized in said second polymer in an amount of less than 4 wt. % based on a total weight of all reactants utilized to form said second polymer.

6. The multilayer film of claim 5 , wherein the first film layer and the second film layer are components of a single film sheet.

7. The multilayer film of claim 5 , wherein both of said first film layer and said second film layer comprise said first polymer and said second polymer.

8. The multilayer film of claim 5 , wherein said first film layer and said second film layer are peelable from each other, in accordance with ASTM F88.

9. The multilayer film of claim 5 , wherein said first film layer and said second film layer define a cavity therebetween, said first film layer and said second film layer are in contact at an interface disposed about said cavity.

10. The multilayer film of claim 9 , wherein said first film layer and said second film layer are peelable from each other adjacent said interface, in accordance with ASTM F88.

11. A multilayer film, comprising:
a first film layer and a second film layer sealed to said first film layer, at least one of said first film layer or said second film layer comprising a first polymer comprising the reaction product of;
chlorotrifluoroethene, and
vinylidene fluoride utilized in said first polymer in an amount of at least 4 wt. % based on a total weight of all reactants utilized to form said first polymer; and

a cavity defined between said first film layer and said second film layer, said first film layer and said second film layer are in contact at an interface disposed about said cavity, said interface comprises a first portion having a first seal strength and a second portion having a second seal strength, said first seal strength is lower than said second seal strength.

12. The multilayer film of claim 11 , wherein said first portion has said first seal strength in an amount of from no greater than 10 newtons per centimeter of width (N/cm), in accordance with ASTM F88.

13. The multilayer film of claim 11 , wherein said second portion has said second seal strength in an amount of greater than 10 N/cm, in accordance with ASTM F88.

14. The multilayer film of claim 11 , wherein said second portion has said second seal strength in an amount of greater than 10 to about 40 N/cm, in accordance with ASTM F88.

15. The multilayer film of claim 11 , wherein at least one of said first film layer or said second film layer comprises said first polymer and a second polymer, said second polymer comprising the reaction product of:
chlorotrifluoroethene, and
optionally, vinylidene fluoride utilized in said second polymer in an amount of less than 4 wt. % based on a total weight of all reactants utilized to form said second polymer.

16. The multilayer film of claim 11 , wherein said first film layer and said second film layer are peelable from each other adjacent said first portion of said interface, in accordance with ASTM F88.

17. A method for forming a multilayer film, the multilayer film comprising a first film layer and a second film layer, said method comprising:
providing a first polymer comprising the reaction product of;
chlorotrifluoroethene, and
vinylidene fluoride utilized in the first polymer in an amount of at least 4 wt. % based on total weight of all reactants utilized to form the first polymer;

extruding the first polymer to form at least one of the first film layer or the second film layer; and
heat sealing the first film layer and the second film layer together at an interface to form the multilayer film, the interface comprises a first portion having a first seal strength and a second portion having a second seal strength, the first seal strength is lower than the second seal strength.

18. The method of claim 17 , wherein the step of heat sealing comprises:
applying a first temperature of no greater than 350° F. to at least one of the first film layer or the second film layer adjacent the first portion of the interface; and
applying a second temperature of greater than 350° F. to at least one of the first film layer or the second film layer adjacent the second portion of the interface.

19. The method of claim 17 , wherein the step of heat sealing further comprises:
applying a pressure of at least 5 psi to at least one of the first film layer or the second film layer; and
maintaining application of the temperature of the first temperature and the second temperature and the pressure of at least 5 psi to for a period of at least 0.5 seconds.

20. The method of claim 17 , wherein:
the step of providing the first polymer comprises combining the first polymer and a second polymer to form a polymer composition, the second polymer comprising the reaction product of:
chlorotrifluoroethene; and
optionally, vinylidene fluoride utilized in the second polymer in an amount of less than 4 wt. % based on a total weight of all reactants utilized to form the second polymer; and
the step of extruding the first polymer comprises extruding the polymer composition to form at least one of the first film layer or the second film layer.

Assignees

• Honeywell Int Inc

Inventors

• Lee Jong Soo
• Kerkar Awdhoot Vasant
• Altman Carl
• Xia Tian
• IWAZU Takahiro
• Huang Hanjin

Classifications

• B32B2307/31

  Heat sealable · CPC title

• B32B2270/00

  Resin or rubber layer containing a blend of at least two different polymers · CPC title

• B32B7/06

  permitting easy separation · CPC title

• B32B2439/80

  Medical packaging · CPC title

• B32B2439/46

  Bags · CPC title