Process for the preparation of glycols

Patent metadata

Field	Value
Publication number	US-10294181-B2
Application number	US-201616060221-A
Country	US
Kind code	B2
Filing date	Dec 7, 2016
Priority date	Dec 9, 2015
Publication date	May 21, 2019
Grant date	May 21, 2019

Abstract

The invention provides a continuous process for the preparation of ethylene glycol and 1, 2-propylene glycol from starting material comprising one or more saccharides, said process being carried out in a reactor system comprising a reactor vessel equipped with an external recycle loop and said process comprising the steps of: i) providing the starting material in a solvent, via an inlet, to the external recycle loop and contacting it therein with a retro-aldol catalyst composition to provide an intermediate stream; ii) then contacting said intermediate stream with hydrogen in the presence of a hydrogenation catalyst composition in the reactor vessel; iii) withdrawing a product stream comprising glycols from the reactor vessel; iv) providing a portion of said product stream, via an outlet, for separation and purification of the glycols contained therein; and v) recycling the remainder of said product stream via the external recycle loop.

First claim

That which is claimed is:

1. A continuous process for the preparation of ethylene glycol and 1,2-propylene glycol from starting material comprising one or more saccharides, said process being carried out in a reactor system comprising a reactor vessel equipped with an external recycle loop and said process comprising the steps of:
i) providing the starting material in a solvent, via an inlet, to the external recycle loop and contacting it therein with a retro-aldol catalyst composition to provide an intermediate stream;
ii) then contacting said intermediate stream with hydrogen in the presence of a hydrogenation catalyst composition in the reactor vessel;
iii) withdrawing a product stream comprising glycols from the reactor vessel;
iv) providing a portion of said product stream, via an outlet, for separation and purification of the glycols contained therein; and
v) recycling the remainder of said product stream via the external recycle loop.

2. The process as claimed in claim 1 , wherein the feed stream comprising said starting material in a solvent is contacted with the retro-aldol catalytic composition in the presence of hydrogen.

3. The process as claimed in claim 1 , wherein the retro-aldol catalyst composition comprises one or more compound, complex or elemental material comprising tungsten, molybdenum, vanadium, niobium, chromium, titanium or zirconium.

4. The process as claimed in claim 1 , wherein the hydrogenation catalytic composition comprises one or more metals selected from the list consisting of iron, cobalt, nickel, ruthenium, rhodium, palladium, iridium and platinum.

5. The process as claimed in claim 1 , wherein the hydrogenation catalytic composition is heterogeneous.

6. The process as claimed in claim 4 , wherein the one or more metals are supported on a solid support.

7. The process as claimed in claim 1 , wherein the reactor vessel operates in an essentially plug flow manner.

8. The process as claimed in claim 1 , wherein the reactor vessel operates with a high degree of back-mixing.

9. The process as claimed in claim 8 , wherein the portion of the product stream which has been removed for separation and purification of the glycols contained therein is subjected to further reaction in a finishing reactor.

Assignees

• Shell Oil Co

Inventors

• Chewter Leslie Andrew
• Lange Jean Paul Andre Marie Joseph Ghislain
• Muthusamy Duraisamy
• Nisbet Timothy Michael
• Van Der Heide Evert
• Huizenga Pieter

Classifications

• C07C2521/06

  Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof · CPC title

• C07C2523/30

  Tungsten · CPC title

• C07C31/205

  1,3-Propanediol; 1,2-Propanediol · CPC title

• C07C29/132 Primary

  by reduction of an oxygen containing functional group · CPC title

• B01J19/1881

  externally, i.e. the mixture leaving the vessel and subsequently re-entering it · CPC title