Manufacturing of a ceramic article from a metal preform or metal matrix composite preform provided by 3D-printing or 3D-weaving

Patent metadata

Field	Value
Publication number	US-10294160-B2
Application number	US-201315101678-A
Country	US
Kind code	B2
Filing date	Dec 4, 2013
Priority date	Dec 4, 2013
Publication date	May 21, 2019
Grant date	May 21, 2019

Abstract

The present invention relates to a method of manufacturing a ceramic article ( 3 ) from a metal or metal matrix composite preform ( 1 ) provided by 3D-printing or by 3D-weaving. The preform ( 1 ) is placed in a heating chamber ( 2 ), and a predetermined time-temperature profile is applied in order to controllably react the preform ( 1 ) with a gas introduced into the heating chamber ( 2 ). The metal, the gas and the time-temperature profile are chosen so as to induce a metal-gas reaction resulting in at least a part of the preform ( 1 ) transforming into a ceramic. Preferred embodiments of the invention comprises a first oxidation stage involving a metal-gas reaction in order to form a supporting oxide layer ( 5 ) at the surface of the metal, followed by a second stage in which the heating chamber ( 2 ) is heated to a temperature above the melting point of the metal to increase the kinetics of the chemical reaction. The invention also relates to a number of advantageous uses of a ceramic article manufactured as described.

First claim

The invention claimed is:

1. Method of manufacturing a ceramic article, the method comprising:
providing a metal or metal matrix composite preform,
placing the preform in a heating chamber,
heating the heating chamber by applying a predetermined time-temperature profile in order to controllably react the preform with a gas introduced into the heating chamber,
wherein the metal, the gas and the time-temperature profile are chosen so as to induce a metal-gas reaction resulting in at least a part of the preform transforming into a ceramic,
wherein the time-temperature profile comprises a first oxidation stage in which the heating chamber is heated to below the melting point of the metal to allow metal-gas reaction in order to form a supporting oxide layer at the surface of the metal followed by a second stage in which the heating chamber is heated to a temperature above the melting point of the metal to increase the kinetics of the chemical reaction, wherein the first stage has a duration resulting in a thick enough oxide layer forming so that the article does not slump when heated to more elevated temperatures in the second stage, and a contiguous oxide layer forming so that the not yet reacted metal does not leak out when melting during the second stage,
wherein there is a third stage in which the heating chamber is heated to a higher temperature than in the second stage so that phase transformation of the ceramic material takes place, and
wherein the preform is provided by 3D-printing or by 3D-weaving.

2. Method according to claim 1 , wherein the preform is 3D-printed using an additive manufacturing method selected from the group consisting of powder-bed, blown-powder and wire-fed.

3. Method according to claim 1 , wherein the 3D-printing process deploys one or more heat sources selected from the group consisting of: laser, electron beam, plasma and incoherent light, to melt the metal.

4. Method according to claim 1 , wherein the metal pre-form is 3D-printed into a shape selected from the group consisting of: a lattice, an open cellular foam, a porous article, a mould and die.

5. Method according to claim 1 , comprising a first stage of oxidation treatment by a chemical, electro-chemical or plasma electrolytic anodising process in order to form a supporting oxide layer at the surface of the metal before the preform is placed in the heating chamber and then placing the preform in the heating chamber, followed by a second stage in which the heating chamber is heated to a temperature above the melting point of the metal to increase the kinetics of the chemical reaction.

6. Method according to claim 1 , wherein the metal-gas reaction(s) take place at a gas pressure in the heating chamber of 0.1-10 atm.

7. Method according to claim 1 , wherein the preform is fully transformed to make a fully ceramic article.

8. Method according to claim 1 , wherein the preform is only partially transformed into ceramic to make a ceramic-metal composite.

9. Method according to claim 8 , wherein the partially transformed ceramic-metal composite is further leached in a leaching solution to remove any remaining metal so as to create hollow ceramic tubes.

10. Method according to claim 1 , wherein the preform is made of or comprises a material selected from the group consisting of aluminium, zirconium, yttrium, cerium, titanium, hafnium, tungsten, vanadium, niobium, tantalum, beryllium, iron, cobalt nickel, copper, lanthanum, lead, zinc, tin, indium, silicon, germanium, magnesium, calcium and an alloy thereof.

11. Method according to claim 1 , wherein the gas introduced into the heating chamber is selected from the group consisting of is air, oxygen, nitrogen, silane, borane, methane, ammonia, hydrogen, hydrogen sulphide, halogen, phosphine, carbon dioxide and a mixture thereof.

12. Method according to claim 1 , wherein the ceramic article is made of a material selected from the group consisting of a metal-oxide, a metal-nitride, a metal-silicide, a metal-boride, a metal-carbide, a metal-hydride, a metal-sulphide, metal-phosphide, metal-halide and a mixed ceramic material.

13. Method according to claim 1 , wherein the type of gas in the heating chamber is changed during the process so as to create a layered ceramic article of varying composition.

14. Method according to claim 1 , further comprising a subsequent step of reacting the formed ceramic article with acid.

15. Method according to claim 1 further comprising chemically washing an active metal catalyst onto the ceramic article to form a catalytic substrate lattice.

16. Method according to claim 1 further comprising providing the metal or metal matrix preform configured such that the manufactured ceramic article is configured to be used as a medical device, selected from the group consisting of a biomedical implant, an orthopaedic device, an artificial bone structure and a stem-cell scaffold.

17. Method according to claim 1 further comprising providing the metal or metal matrix preform configured such that the manufactured ceramic article is configured to be used for an application selected from the group consisting of RF antenna, dielectric, microwave, embedded sensors and photonic applications.

Assignees

• ESA

Inventors

• Jarvis David John
• Voice Wayne Eric
• Adkins Nicholas John Elsworth
• Hassanin Hany Salamam Sayed Ali

Classifications

• B22F10/32

  of the atmosphere, e.g. composition or pressure in a building chamber · CPC title

• B22F10/38

  to achieve specific product aspects, e.g. surface smoothness, density, porosity or hollow structures · CPC title

• B22F10/28

  Powder bed fusion, e.g. selective laser melting [SLM] or electron beam melting [EBM] · CPC title

• C04B2235/46

  Gases other than oxygen used as reactant, e.g. nitrogen used to make a nitride phase · CPC title

• C23C8/10

  Oxidising · CPC title