Cellulose ester multilayer interlayers

Patent metadata

Field	Value
Publication number	US-10293579-B2
Application number	US-201715453466-A
Country	US
Kind code	B2
Filing date	Mar 8, 2017
Priority date	Mar 11, 2016
Publication date	May 21, 2019
Grant date	May 21, 2019

Abstract

An interlayer structure having a cellulose ester layer for use in structural laminates is described herein. The cellulose ester layer provides rigidity and support to multilayer interlayers comprising an array of different layers. Due to the diverse properties of the cellulose ester layers, the present interlayers can be useful in producing structural laminates having high stiffness and which possess good optical clarity for a variety of applications, including outdoor structural applications.

First claim

What is claimed is:

1. A multilayer interlayer comprising:
(a) a non-cellulose ester layer comprising a poly(vinyl acetal) resin and a plasticizer,
wherein the non-cellulose ester layer has a glass transition temperature (“Tg”) of less than 30° C.; and
(b) a cellulose ester layer comprising at least one cellulose ester having a hydroxyl content of at least 0.5 weight percent and not more than 30 weight percent based on the entire weight of the cellulose ester,
wherein said cellulose ester layer has a Tg of at least 50° C. and not more than 250° C.;
wherein an adhesive coating is interposed between the cellulose ester layer and the non-cellulose ester layer.

2. The interlayer of claim 1 , wherein said non-cellulose ester layer has a Tg of less than 20° C.

3. The interlayer of claim 1 , wherein said non-cellulose ester layer has a Tg of less than 10° C.

4. The interlayer of claim 1 , wherein said poly(vinyl acetal) resin comprises polyvinyl butyral.

5. The interlayer of claim 1 , wherein said poly(vinyl acetal) layer exhibits a damping loss factor of at least 0.10 as measured by ISO 16940.

6. The interlayer of claim 1 , wherein said multilayer interlayer exhibits a sound transmission loss, at the coincident frequency, of at least 35 dB as measured according to ASTM E90 at 20° C.

7. The interlayer of claim 1 , wherein said non-cellulose ester layer further comprises a second layer comprising a poly(vinyl acetal) resin and a plasticizer, wherein the second poly(vinyl acetal) layer has a glass transition temperature of greater than 30° C.

8. The multilayer interlayer of claim 1 , wherein the cellulose ester comprises at least two different acyl groups selected from acetate, propionate, butyrate, and other acyl groups.

9. The multilayer interlayer of claim 8 , wherein the cellulose ester comprises at least two of acetate, propionate and butyrate groups and combinations thereof.

10. The multilayer interlayer of claim 1 , wherein said cellulose ester layer exhibits a shear storage modulus that is greater than the shear storage modulus of said non-cellulose ester layer.

11. The interlayer of claim 1 , further comprising a second non-cellulose ester layer comprising a poly(vinyl acetal) resin and a plasticizer, wherein the cellulose ester layer is between and in contact with the non-cellulose ester layer and the second non-cellulose ester layer.

12. A laminate comprising:
a first rigid substrate,
a second rigid substrate, and
the interlayer of claim 11 ,
wherein the interlayer of claim 11 is disposed between and in contact with the first rigid substrate and the second rigid substrate.

13. A multilayer interlayer comprising:
(a) a non-cellulose ester layer comprising:
(i) a first layer comprising a first poly(vinyl acetal) resin and a plasticizer,

wherein the first poly(vinyl acetal) layer has a glass transition temperature (“Tg”) of less than 20° C., and
(ii) a second layer comprising a second poly(vinyl acetal) resin and a plasticizer,

wherein the second poly(vinyl acetal) layer has a Tg of greater than 20° C.;
(b) a cellulose ester layer comprising at least one cellulose ester having a hydroxyl content of at least 0.5 weight percent and not more than 30 weight percent based on the entire weight of the cellulose ester, and a plasticizer,
wherein said cellulose ester layer has a Tg of at least 50° C. and nor more than 250° C.;
wherein an adhesive coating is interposed between the cellulose ester layer and the non-cellulose ester layer.

14. The multilayer interlayer of claim 13 , wherein at least one of the first poly(vinyl acetal) resin and the second poly(vinyl acetal) resin is polyvinyl butyral.

15. The multilayer interlayer of claim 13 , wherein the cellulose ester comprises at least two different acyl groups selected from acetate, propionate, butyrate, and other acyl groups.

16. The multilayer interlayer of claim 15 , wherein the cellulose ester comprises at least two of acetate, propionate and butyrate groups.

17. The multilayer interlayer of claim 13 , wherein said cellulose ester layer exhibits a shear storage modulus that is greater than the shear storage modulus of said non-cellulose ester layer.

18. A multilayer interlayer comprising:
(a) a first non-cellulose ester layer comprising a poly(vinyl acetal) resin and a plasticizer,
wherein the first non-cellulose ester layer has a glass transition temperature (“Tg”) of less than 30° C.;
(b) a cellulose ester layer comprising at least one cellulose ester having a hydroxyl content of at least 0.5 weight percent and not more than 30 weight percent based on the entire weight of the cellulose ester,
wherein said cellulose ester layer has a Tg of at least 50° C. and not more than 250° C.; and
(c) a second non-cellulose ester layer comprising a poly(vinyl acetal) resin and a plasticizer,
wherein the second non-cellulose ester layer has a Tg of greater than 30° C.,
wherein said first non-cellulose ester layer is between and in contact with said cellulose ester layer and said second non-cellulose ester layer; and
wherein an adhesive coating is interposed between a cellulose ester layer and a non-cellulose ester layer.

19. The multilayer interlayer of claim 18 , further comprising a third non-cellulose ester layer comprising a poly(vinyl acetal) resin and a plasticizer, wherein the third non-cellulose ester layer has a glass transition temperature of greater than 30° C., and wherein said third non-cellulose ester layer is disposed in contact with said cellulose ester layer opposite said first non-cellulose ester layer.

20. The multilayer interlayer of claim 18 , wherein the cellulose ester comprises at least two different acyl groups selected from acetate, propionate, butyrate, and other acyl groups.

Assignees

• Solutia Inc

Inventors

• Karagiannis Aristotelis
• Wade Bruce Edward
• Donelson Michael Eugene
• Tran Khanh Duc

Classifications

• B32B2307/558

  Impact strength, toughness · CPC title

• B32B2307/412

  Transparent · CPC title

• B32B23/08

  of synthetic resin · CPC title

• B32B3/02

  characterised by features of form at particular places, e.g. in edge regions {(non-uniform thickness B32B3/263)} · CPC title

• B32B2255/10

  on synthetic resin layer or on natural or synthetic rubber layer · CPC title