Interlaced filtration barrier

Patent metadata

Field	Value
Publication number	US-10293291-B2
Application number	US-201615250865-A
Country	US
Kind code	B2
Filing date	Aug 29, 2016
Priority date	Dec 9, 2013
Publication date	May 21, 2019
Grant date	May 21, 2019

Abstract

A filtration barrier comprises at least one barrier layer which includes polymeric nanofibers interlaced with microfibers, and at least one substrate layer which includes polymeric microfibers. The filtration barrier can be made by electrospinning process.

First claim

What is claimed is:

1. A method of fabricating a filtration barrier, comprising:
obtaining a polymer solution that includes cellulose acetate (CA) and polyethylene oxide (PEO); and
electrospinning the polymer solution onto a substrate layer to form an interlaced structure of nanofibers and microfibers on the substrate layer so that the nanofibers and the microfibers form a barrier layer;
wherein the nanofibers account for 60%-70% by weight in the barrier layer and the microfibers of the interlaced structure account for 30%-40% by weight in the barrier layer;
wherein the barrier layer and the substrate layer are attached to form the filtration barrier,
wherein the nanofibers and the microfibers are made from the same polymer solution, the nanofibers and the microfibers are interlaced in the same layer, and the nanofibers and the microfibers are discharged together from the same polymer solution during electrospinning to form the interlaced structure.

2. The method of claim 1 , wherein the CA accounts for 10%-20% by weight in the polymer solution.

3. The method of claim 1 , wherein the PEO accounts for 0.05%-0.2% by weight in the polymer solution.

4. The method of claim 1 , wherein the polymer solution includes benzyltriethylammonium chloride that accounts for 0.1%-0.3% by weight in the polymer solution.

5. The method of claim 1 , wherein the polymer solution includes dimethylformamide (DMF) that accounts for 80%-90% by weight in the polymer solution.

6. The method of claim 1 further comprising:
varying a conductivity, viscosity or surface tension of the polymer solution during electrospinning the polymer solution onto the substrate layer so that the interlaced structure of nanofibers and microfibers is formed.

7. The method of claim 1 further comprising:
adding a conductivity-enhancing additive into the polymer solution to vary a conductivity of the polymer solution.

8. The method of claim 1 further comprising:
adding a conductivity-enhancing additive into the polymer solution to vary a conductivity of the polymer solution,
wherein the conductivity-enhancing additive is benzyltriethylammonium chloride.

9. The method of claim 1 , wherein the substrate layer is a nonwoven fabric made of 10-100 gsm polypropylene.

10. The method of claim 1 , wherein a diameter of the nanofibers is 10 nanometers to 1000 nanometers, and a diameter of the microfibers in the barrier layer is 1 micron to 10 microns.

11. The method of claim 1 further comprising:
attaching the barrier layer to a supporting layer, wherein the barrier layer is sandwiched between the supporting layer and the substrate layer.

12. The method of claim 1 further comprising:
attaching the barrier layer to a supporting layer, wherein the barrier layer is sandwiched between the supporting layer and the substrate layer, the supporting layer is a nonwoven fabric made of 40-120 gsm polypropylene.

13. The method of claim 1 further comprising:
adding a biocide and a cross-linker to the polymer solution, wherein the biocide is cross-linked to the barrier layer, the biocide is chlorhexidine (CHX), and the cross-linker is organic titanate (TTE).

14. A method of fabricating a filtration barrier, comprising:
obtaining a polymer solution that includes a polymer;
electrospinning the polymer solution to form a barrier layer; and
attaching the barrier layer to a substrate layer to obtain the filtration barrier,
wherein
the barrier layer includes a plurality of first polymer-based nanofibers and a plurality of second polymer-based microfibers that are interlaced with the first polymer-based nanofibers in a same layer; and
the substrate layer includes a plurality of third polymer-based microfibers and is attached onto the barrier layer,
wherein the first polymer-based nanofibers and the second polymer-based microfibers that are interlaced with the first polymer-based nanofibers in the barrier layer are made from the same polymer solution,
wherein the first polymer-based nanofibers are electrospun nanofibers and the second polymer-based microfibers are electrospun microfibers,
wherein the first polymer-based nanofibers account for 60%-70% by weight of the barrier layer, and the interlaced structure of the barrier layer has a pore size of 100-10000 nanometers,
wherein the first polymer-based nanofibers and the second polymer-based microfibers are discharged together from the same polymer solution during electrospinning to form the interlaced structure.

15. The method of claim 14 , wherein the polymer solution includes a combination of cellulose acetate (CA) and polyethylene oxide (PEO).

16. The method of claim 14 , wherein the barrier layer is attached onto the substrate layer via mechanical interlocking or electrostatic attraction.

17. The method of claim 14 , wherein a perimeter of the barrier layer is attached onto a perimeter of the substrate layer via ultrasonic welding.

18. The method of claim 14 , wherein a conductivity, viscosity or surface tension of the polymer solution is varied during electrospinning the polymer solution onto the substrate layer so that the interlaced structure of the first polymer-based nanofibers and the second polymer-based microfibers is formed.

19. The method of claim 14 further comprising:
adding a conductivity-enhancing additive into the polymer solution to vary a conductivity of the polymer solution,
wherein the conductivity-enhancing additive is benzyltriethylammonium chloride.

20. The method of claim 14 further comprising:
attaching a supporting layer to the barrier layer, wherein the barrier layer is sandwiched between the supporting layer and the substrate layer.

Assignees

• Nano & Advanced Materials Inst Ltd
• Nano And Advanced Mat Institute Ltd

Inventors

• Tong Ho Wang
• Kwok Sau Kuen Connie

Classifications

• B01D2239/1233

  Fibre diameter · CPC title

• B01D2239/0654

  Support layers · CPC title

• B01D2239/064

  The fibres being mixed · CPC title

• B01D2239/0631

  Electro-spun · CPC title

• B01D2239/0442

  Antimicrobial, antibacterial, antifungal additives · CPC title