Dry lubricant for zinc coated steel

Patent metadata

Field	Value
Publication number	US-10287665-B2
Application number	US-201615381676-A
Country	US
Kind code	B2
Filing date	Dec 16, 2016
Priority date	Jun 27, 2014
Publication date	May 14, 2019
Grant date	May 14, 2019

Abstract

The present invention relates to the use of an alkaline, aqueous coating composition for coating of zinc or zinc alloy coated steel substrates, comprising one or more alkaline sulfates, and one or more alkaline carbonates, wherein the pH of the composition ranges from 9-12. The present invention also defines a method for the non-reactive coating of zinc or zinc alloy coated steel substrates by use of said compositions and further relates to the application of said method as a surrogate for pre-phosphating of zinc or zinc alloy coated steel substrates in industrial applications.

First claim

The invention claimed is:

1. A method for coating zinc or zinc alloy coated steel substrates, comprising:
contacting a zinc or zinc alloy coated steel substrate with an aqueous composition comprising:
(i) one or more alkaline sulfates selected from the group consisting of sodium sulfate, potassium sulfate, ammonium sulfate, and mixtures thereof,
(ii) one or more alkaline carbonates selected from the group consisting of alkaline metal carbonates, ammonium carbonate, and mixtures thereof, and
(iii) 0 to less than 1 g/l of water soluble inorganic phosphate salts calculated as PO 4 ;
wherein pH of the composition ranges from 9-12;

drying the aqueous composition on the zinc or zinc alloy coated steel substrate without intermediate rinsing, thereby forming a coating having a coating weight after drying of 0.05 to 1.0 g/m 2 .

2. The method of claim 1 , wherein the total alkaline sulfate concentration of the aqueous coating composition is 7-100 g/l.

3. The method of claim 1 , wherein the one or more alkaline carbonates in the aqueous coating composition are selected from the group consisting of sodium carbonate, ammonium carbonate, and mixtures thereof.

4. The method of claim 1 , wherein the total alkaline carbonate concentration of the aqueous coating composition is 0.5-40 g/l.

5. The method of claim 1 , wherein the coating composition additionally comprises chelating agents selected from α-hydroxy-carboxylic acids.

6. The method of claim 5 , wherein the weight fraction of chelating agents in the form of their sodium salts is at least 0.5 wt. %, but less than 10 wt. % based on a total dry salt concentration of the coating composition.

7. The method of claim 1 , wherein the coating composition additionally comprises silicates.

8. The method of claim 7 , wherein the silicates are contained in the coating composition in an amount that gives rise to an elemental loading of less than 2.0 mg/m 2 , but at least 0.1 mg/m 2 with respect to the element Si.

9. The method according to claim 1 , wherein the aqueous coating composition has a total dry salt concentration in a range of 14-200 g/l.

10. A method for coating of zinc or zinc alloy steel substrates, wherein the method comprises:
(a) coating a zinc or zinc alloy coated steel substrate with a wet film of an aqueous coating composition having a pH of 10.2-11.5 and comprising:
(i) 7-100 g/l of one or more alkaline sulfates selected from the group consisting of sodium sulfate, potassium sulfate, ammonium sulfate, and mixtures thereof;
(ii) 0.5-40 g/l of one or more alkaline carbonates selected from the group consisting of alkaline metal carbonates, ammonium carbonate, and mixtures thereof; and
(iii) 0 to less than 1 g/l of water soluble inorganic phosphate salts calculated as PO 4 ;

(b) drying the coated wet film on the zinc or zinc alloy coated steel substrate at temperatures in a range of 40-100° C.

11. The method according to claim 10 , wherein the temperature of the aqueous coating composition during step (a) lies in a range of 15-35° C.

12. The method according to claim 10 , wherein subsequent to step (b) a phosphating step (c) is conducted.

13. The method according claim 12 , wherein subsequent to step (b) the surfaces of the zinc coated steel substrates are loaded with an oil film, prior to any phosphating step (c).

14. The method according to claim 1 , wherein components (i), (ii) and (iii) are selected such that the coating composition has an etching rate of less than 0.01 g/m 2 per hour with respect to the element Zn.

15. The method according to claim 10 , wherein the coating composition of step (a), additionally comprises:
(iv) chelating agents selected from α-hydroxy-carboxylic acids present in a weight fraction in the form of their sodium salts of at least 0.5 wt. %, but less than 10 wt. % based on a total dry salt concentration of the coating composition; and
(v) silicates present in an amount that gives rise to an elemental loading of less than 0.8 mg/m 2 , with respect to the element Si; and
final coating weight after drying step (b) is 0.1 g/m 2 and an absolute amount of the element Si on top of the zinc coated substrate being at least 0.1 mg/m 2 and less than 0.8 mg/m 2 .

16. A method for coating zinc or zinc alloy coated steel substrates, comprising the steps of:
(a) coating a zinc or zinc alloy coated steel substrate with a wet film of an aqueous composition having pH from 9-12 and temperature from 15-35° C. consisting of:
(i) 7-100 g/l of one or more alkaline sulfates selected from the group consisting of sodium sulfate, potassium sulfate, ammonium sulfate, and mixtures thereof,
(ii) 0.5-40 g/l of one or more alkaline carbonates selected from the group consisting of alkaline metal carbonates, ammonium carbonate, and mixtures thereof,
(iii) 0 to less than 1 g/l of water soluble inorganic phosphate salts calculated as PO 4 ,
(iv) less than 0.1 g/l of a total amount of Zr, Ti, Mo, and Cr,
(v) optionally, a weight fraction between 0.5 wt % and 10 wt. % based on the total dry salt concentration of the coating composition of a water soluble sequestrant selected from the group consisting of ethylenediaminetetraacetic acitd (EDTA), α-hydroxy-carboxylic acids, nitrilodiacetic acid (NTA), gluconate sodium gluconate, and mixtures thereof, and
(vi) optionally, an amount of silicates that results in an elemental loading on the substrate of less than 2.0 mg/m 2 but at least 0.1 mg/m 2 with respect to the element Si;
wherein the aqueous coating composition has a total dry salt concentration in a range of 14-200 g/l; and

(b) drying the coated wet film on the zinc or zinc alloy coated steel substrate at temperatures in a range of 40-100° C., such that the dried film has a final coating weight;
wherein the final coating weight after drying is 0.05 to 1.0 g/m 2 .

Assignees

• Henkel Ag & Co Kgaa

Inventors

• Giordani Paolo
• Rigamonti Mauro
• Seidel Reinhard
• Galli Roberto
• Madonini Luigi Dante
• Clodt Hans

Classifications

• C25D5/48

  After-treatment of electroplated surfaces · CPC title

• C23C22/78

  Pretreatment of the material to be coated · CPC title

• C25D7/0614

  Strips or foils · CPC title

• C23C2/06 Primary

  Zinc or cadmium or alloys based thereon · CPC title

• C25D11/36

  Phosphatising · CPC title