Rare earth magnet molding and method for manufacturing the same

Patent metadata

Field	Value
Publication number	US-10287656-B2
Application number	US-201013392365-A
Country	US
Kind code	B2
Filing date	Aug 4, 2010
Priority date	Sep 9, 2009
Publication date	May 14, 2019
Grant date	May 14, 2019

Abstract

A rare earth magnet molding (1) of the present invention includes rare earth magnet particles (2), and an insulating phase (3) present among the rare earth magnet particles. Segregation regions (4) in which at least one element selected from the group consisting of Dy, Tb, Pr and Ho is segregated are distributed in the rare earth magnet particles (2). Accordingly, the rare earth magnet molding that has excellent resistance to heat in motor environments or the like while maintaining high magnetic characteristics (coercive force) is provided.

First claim

The invention claimed is:

1. A rare earth magnet molding, comprising:
rare earth magnet particles having particle diameters in a range of 25 μm to 525 μm,
an insulating phase containing a rare earth oxide present among the rare earth magnet particles, a content of the rare earth oxide in the insulating phase is 80% by volume or more, and
magnet fine particles having particle diameters less than 25 μm,
wherein an aggregation region in which the magnet fine particles are aggregated is present in at least part of circumferences of the rare earth magnet particles,
wherein segregation regions in which at least one element selected from the group consisting of Dy, Tb, Pr and Ho is segregated are distributed from a surface of the rare earth magnet particles to a center of the rare earth magnet particles,
wherein a content of the magnet fine particles is 40% by volume or less with respect to a content of the rare earth magnet particles,
wherein a material of the magnet fine particles is the same as a material of the rare earth magnet particles, and
wherein surfaces of the rare earth magnet particles contact the insulating phase.

2. The rare earth magnet molding according to claim 1 , wherein a region in which the magnet fine particles are mixed with the insulating phase is present.

3. The rare earth magnet molding according to claim 1 , wherein each segregation region further contains Co.

4. The rare earth magnet molding according to claim 3 , wherein each segregation region further contains Nd.

5. The rare earth magnet molding according to claim 1 , wherein the rare earth magnet particles are prepared by processing raw material magnetic powder produced by a hydrogenation decomposition desorption recombination method.

6. The rare earth magnet molding according to claim 1 , wherein the rare earth oxide comprises an oxide of at least one element selected from the group consisting of Nd, Dy, Tb, Pr and Ho.

7. The rare earth magnet molding according to claim 6 , wherein the rare earth oxide comprises an oxide of at least one element selected from the group consisting of Dy, Tb and Pr.

8. The rare earth magnet molding according to claim 6 , wherein the rare earth oxide comprises an oxide of at least one element selected from the group consisting of Tb and Pr.

9. A motor comprising: the rare earth magnet molding according to claim 1 .

10. A method for manufacturing the rare earth magnet molding according to claim 1 , the method comprising:
covering a surface of raw material magnetic powder with a single substance of at least one element selected from the group consisting of Dy, Tb, Pr and Ho or an alloy thereof to obtain surface-modified raw material magnetic powder;
subjecting the obtained surface-modified raw material magnetic powder to pressure molding under a heating atmosphere while subjecting to magnetic orientation in a magnetic field to obtain an anisotropic rare earth magnet;
contacting surfaces of rare earth magnet particles obtained by pulverizing the obtained anisotropic rare earth magnet with the insulating phase to obtain a magnet molding precursor; and
heating the obtained magnet molding precursor under pressure.

11. The method for manufacturing a rare earth magnet molding according to claim 10 , further comprising:
mixing and integrating the rare earth magnet particles obtained by pulverizing the obtained anisotropic rare earth magnet with magnet fine particles,
wherein surfaces of the integrated rare earth magnet particles are covered with the insulating phase.

12. A method for manufacturing the rare earth magnet molding according to claim 1 , the method comprising:
subjecting mixed magnetic powder of first raw material magnetic powder and second raw material magnetic powder to pressure molding under a heating atmosphere while subjecting to magnetic orientation in a magnetic field to obtain an anisotropic rare earth magnet, the second raw material magnetic powder being obtained by substituting at least one element selected from the group consisting of Dy, Tb, Pr, and Ho for a part of an element of the first raw material magnetic powder;
contacting surfaces of rare earth magnet particles obtained by pulverizing the obtained anisotropic rare earth magnet with the insulating phase to obtain a magnet molding precursor; and
heating the obtained magnet molding precursor under pressure.

13. The method for manufacturing a rare earth magnet molding according to claim 12 , further comprising:
mixing and integrating the rare earth magnet particles obtained by pulverizing the obtained anisotropic rare earth magnet with magnet fine particles,
wherein surfaces of the integrated rare earth magnet particles are covered with the insulating phase.

14. The rare earth magnet molding according to claim 1 , wherein the segregation regions are distributed continuously from the surface of the rare earth magnet particles to the center of the rare earth magnet particles.

15. The rare earth magnet molding according to claim 1 , wherein the rare earth oxide is dysprosium oxide.

16. The rare earth magnet molding according to claim 1 , wherein surfaces of the rare earth magnet particles are completely covered with the insulating phase.

17. The rare earth magnet molding according to claim 1 , wherein the magnet fine particles aggregated in the aggregation region are mixed with the insulating phase.

18. The rare earth magnet molding according to claim 1 , wherein an average particle diameter of the magnet fine particles is 1/10 or less with respect to an average particle diameter of the rare earth magnet particles.

19. The rare earth magnet molding according to claim 1 , wherein a DyCoNd alloy is segregated in the segregation regions.

20. The rare earth magnet molding according to claim 1 , wherein a DyCo alloy is segregated in the segregation regions.

21. The rare earth magnet molding according to claim 1 , wherein surfaces of the rare earth magnet particles are covered with the insulating phase.

22. A rare earth magnet molding, comprising:
rare earth magnet particles having particle diameters in a range of 25 μm to 525 μm,
an insulating phase containing a rare earth oxide present among the rare earth magnet particles, a content of the rare earth oxide in the insulating phase is 80% by volume or more, and
magnet fine particles having particle diameters less than 25 μm,
wherein an aggregation region in which the magnet fine particles are aggregated is present in at least part of circumferences of the rare earth magnet particles,
wherein segregation regions in which at least one element selected from the group consisting of Dy, Tb, Pr and Ho is segregated are distributed from a surface of the rare earth magnet particles to a center of the rare earth magnet particles,
wherein a content of the magnet fine particles is 40% by volume or less with respect to a content of the rare earth magnet particles,
wherein a material of the magnet fine particles is the same as a material of the rare earth magnet particles,
wherein surfaces of the rare earth magnet particles are covered with the insulating phase, and
wherein an average particle diameter of the magnet fine particles is 1/10 or less with respect to an average particle diameter of the rare earth magnet particles.

Assignees

• Kawashita Yoshio
• Uramoto Kiyohiro
• Miyamoto Takashi
• Yasuda Yoshiteru
• Nissan Motor

Inventors

• Kawashita Yoshio
• Uramoto Kiyohiro
• Miyamoto Takashi
• Yasuda Yoshiteru

Classifications

• B22F1/02

  Operations & Transport · mapped topic

• H01F1/0572

  with a protective layer · CPC title

• C22C28/00 Primary

  Alloys based on a metal not provided for in groups C22C5/00 - C22C27/00 · CPC title

• C22C38/005

  containing rare earths, i.e. Sc, Y, Lanthanides · CPC title

• H01F1/0577

  sintered · CPC title