Method for recovering calcium-containing solid component from steelmaking slag and recovered solid component

Patent metadata

Field	Value
Publication number	US-10287652-B2
Application number	US-201615560711-A
Country	US
Kind code	B2
Filing date	Mar 16, 2016
Priority date	Mar 23, 2015
Publication date	May 14, 2019
Grant date	May 14, 2019

Abstract

The purpose of the present invention is to provide a method for recovering calcium-containing solid components from steelmaking slag, with which it is possible to easily increase the calcium recovery rate. With the method, steelmaking slag is immersed in an aqueous solution containing carbon dioxide, and calcium in the steelmaking slag is made to leach out into the aqueous solution. Next, the immersed steelmaking slag is removed from the aqueous solution, and, subsequently, the pH of the aqueous solution is increased. When solid components precipitated by doing so are recovered, it is possible to recover solid components containing 20% or more by mass in terms of calcium atoms.

First claim

The invention claimed is:

1. A method for recovering a solid component containing calcium from steelmaking slag, the method comprising:
immersing the steelmaking slag in an aqueous solution containing carbon dioxide;
separating the immersed steelmaking slag from the aqueous solution;
increasing the pH of the aqueous solution separated from the steelmaking slag to precipitate the solid component containing calcium;
recovering the solid component containing calcium; and
removing the carbon dioxide from the aqueous solution separated from the steelmaking slag by introducing, into the aqueous solution from which the steelmaking slag has been separated, a gas having a partial pressure of carbon dioxide lower than an equilibrium pressure of carbon dioxide in the aqueous solution separated from the steelmaking slag, wherein the removing is performed by:
removing the carbon dioxide from the aqueous solution separated from the steelmaking slag, prior to the increasing the pH of the aqueous solution;
removing the carbon dioxide from the aqueous solution separated from the steelmaking slag, during the increasing the pH of the aqueous solution; or
removing the carbon dioxide from the aqueous solution separated from the steelmaking slag and having the increased pH, after the increasing the pH of the aqueous solution and prior to the recovering the solid component containing calcium.

2. The method according to claim 1 , wherein the increasing the pH includes increasing the pH of the aqueous solution by 0.2 or more.

3. The method according to claim 1 , wherein the increasing the pH includes increasing the pH of the aqueous solution by adding an alkaline substance into the aqueous solution.

4. The method according to claim 3 , wherein the adding the alkaline substance includes:
adding slag-immersed water, which is obtained by immersing steelmaking slag in water, to the aqueous solution.

5. The method according to claim 4 , further comprising:
prior to the immersing the steelmaking slag in the aqueous solution, obtaining the slag-immersed water which is obtained by immersing the steelmaking slag that is to be immersed in the aqueous solution containing carbon dioxide, or obtained by immersing another steelmaking slag in the water in water.

6. The method according to claim 1 , further comprising, during the removing carbon dioxide, recovering a solid component precipitated before the pH of the aqueous solution increases by 1.0.

7. A method for recovering a solid component containing calcium from steelmaking slag, the method comprising:
immersing the steelmaking slag in an aqueous solution containing carbon dioxide;
separating the immersed steelmaking slag from the aqueous solution;
increasing the pH of the aqueous solution separated from the steelmaking slag to precipitate a solid component containing calcium, wherein the increasing the pH of the aqueous solution is performed by adding slag-immersed water to the aqueous solution separated from the steelmaking slag, and wherein the slag-immersed water is obtained by immersing in water the steelmaking slag that is to be immersed in the aqueous solution containing carbon dioxide, or obtained by immersing another steelmaking slag in the water; and
recovering the solid component containing calcium.

8. The method according to claim 7 , further comprising,
removing carbon dioxide from the aqueous solution, by introducing, into the aqueous solution, a gas having a partial pressure of carbon dioxide lower than an equilibrium pressure of carbon dioxide in the aqueous solution;
wherein the removing is performed after the separating and prior to the increasing the pH, during the increasing the pH, or after the increasing the pH and prior to the recovering the solid component containing calcium.

Assignees

• Nisshin Steel Co Ltd

Inventors

• Fukui Yasushi
• Asaba Akihiro
• Matsuo Shoichi
• Yamamoto Masaya

Classifications

• C04B5/06

  Ingredients, other than water, added to the molten slag {or to the granulating medium or before remelting}; Treatment with gases or gas generating compounds, e.g. to obtain porous slag · CPC title

• C22B7/04 Primary

  Working-up slag · CPC title

• C01F11/18 Primary

  Carbonates · CPC title

• C22B7/008

  by an alkaline or ammoniacal leaching · CPC title

• C04B5/00 Primary

  Treatment of  {metallurgical}  slag  (manufacture of slag wool C03B; in, or for, the production of metals C21B, C22B); Artificial stone from molten  {metallurgical}  slag  {(other cast stone C04B32/005; mechanical aspects B28B1/54)} · CPC title