Settable, form-filling loss circulation control compositions comprising in situ foamed non-hydraulic sorel cement systems and method of use
US-10150905-B1 · Dec 11, 2018 · US
US10287481B1 · US · B1
| Field | Value |
|---|---|
| Publication number | US-10287481-B1 |
| Application number | US-201816137962-A |
| Country | US |
| Kind code | B1 |
| Filing date | Sep 21, 2018 |
| Priority date | Jan 24, 2018 |
| Publication date | May 14, 2019 |
| Grant date | May 14, 2019 |
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This document relates to settable, non-hydraulic foamed cement compositions comprising nitrogen gas-generating compositions used for loss circulation control.
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The invention claimed is: 1. A method of treating a lost circulation zone, the method comprising: a) forming a foamed cementitious composition comprising: magnesium oxide (MgO); a salt selected from the group consisting of magnesium chloride (MgCl 2 ), magnesium sulfate (MgSO 4 ), ammonium hydrogen phosphate (NH 4 H 2 PO 4 ), and hydrates thereof; an oxidizer; a nitrogen gas-generating compound; and a foam surfactant; and b) introducing the foamed cementitious composition into the lost circulation zone. 2. The method of claim 1 , wherein the nitrogen gas-generating compound is an azo compound, and wherein the salt is magnesium chloride hexahydrate (MgCl 2 .6H 2 O). 3. The method of claim 2 , wherein the azo compound is about 1% to about 10% by weight of the MgO. 4. The method of claim 2 , further comprising an amine activator selected from the group consisting of carbohydrazide (CHZ), tetraethylenepentamine (TEPA), and hydrazine sulfate. 5. The method of claim 4 , wherein the weight ratio of the azo compound to the amine activator is about 5:1 to about 1:5.
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