Weather-resistant thermoplastic resin, thermoplastic resin composition containing the same, and method of preparing thermoplastic

Patent metadata

Field	Value
Publication number	US-10287385-B2
Application number	US-201615531406-A
Country	US
Kind code	B2
Filing date	Oct 6, 2016
Priority date	Oct 7, 2015
Publication date	May 14, 2019
Grant date	May 14, 2019

Abstract

The present invention relates to a weather-resistant thermoplastic resin, a thermoplastic resin composition containing the same, and a method of preparing the thermoplastic resin composition. More particular, the present invention relates to a thermoplastic resin including a) a hard core having a refractive index of 1.530 to 1.590; b) a crosslinked rubber layer that surrounds the hard core, has an average thickness of 30 to 80 nm, and is prepared by polymerizing an alkyl (meth)acrylate compound and a crosslinking agent; and c) a non-crosslinked hard shell that surrounds the crosslinked rubber layer and is prepared by polymerizing an aromatic vinyl compound and a vinyl cyanide compound, a thermoplastic resin composition including the thermoplastic resin, and a method of preparing the thermoplastic resin composition. In accordance to the present disclosure, a weather-resistant thermoplastic resin having superior rigidity and impact resistance, particularly excellent surface gloss and coloring properties, a thermoplastic resin composition containing the same, and a method of preparing the thermoplastic resin composition may be provided.

First claim

The invention claimed is:

1. A thermoplastic resin composition, comprising:
A) 20 to 80% by weight of a thermoplastic resin comprising a) a hard core having a refractive index of 1.530 to 1.590, b) a crosslinked rubber layer that surrounds the hard core, has an average thickness of 30 to 80 nm, and is prepared by polymerizing an alkyl (meth)acrylate compound and a crosslinking agent, and c) a non-crosslinked hard shell that surrounds the crosslinked rubber layer and is prepared by polymerizing an aromatic vinyl compound and a vinyl cyanide compound; and
B) 20 to 80% by weight of a hard thermoplastic resin having a refractive index of 1.52 to 1.56, wherein the thermoplastic resin composition has a coloring property L of between 25.52 and 24.55, and
wherein the hard thermoplastic resin is prepared by copolymerizing 30 to 60% by weight of an alkyl (meth) acrylate compound, 25 to 55% by weight of an aromatic vinyl compound, and 5 to 15% by weight of vinyl cyanide compound.

2. The thermoplastic resin composition according to claim 1 , comprising:
a) 5 to 40% by weight of the hard core having a refractive index of 1.530 to 1.590;
b) 20 to 60% by weight of the crosslinked rubber layer that surrounds the hard core, has an average thickness of 30 to 80 nm, and is prepared by polymerizing an alkyl (meth)acrylate compound and a crosslinking agent; and
c) 20 to 60% by weight of the non-crosslinked hard shell that surrounds the rubber layer and is prepared by polymerizing an aromatic vinyl compound and a vinyl cyanide compound.

3. The thermoplastic resin composition according to claim 1 , wherein the hard core of a) is a crosslinked polymer having a glass transition temperature (Tg) of 20° C. or higher.

4. The thermoplastic resin composition according to claim 1 , wherein the hard core of a) is a copolymer that is prepared by polymerizing an aromatic vinyl compound and a vinyl cyanide compound with a crosslinking agent, or a crosslinking agent and a grafting agent.

5. The thermoplastic resin composition according to claim 4 , wherein the crosslinking agent is comprised in an amount of 0.01 to 0.5 parts by weight with respect to 100 parts by weight of total monomers used in the thermoplastic resin.

6. The thermoplastic resin composition according to claim 4 , wherein the grafting agent is one or more selected from the group consisting of allyl methacrylate (AMA), triallyl isocyanurate (TAIC), triallylamine (TAA), and diallylamine (DAA).

7. The thermoplastic resin composition according to claim 4 , wherein the grafting agent is comprised in an amount of 0.01 to 0.5 parts by weight with respect to 100 parts by weight of total monomers used in the thermoplastic resin.

8. The thermoplastic resin composition according to claim 1 , wherein the crosslinked rubber layer of b) is a crosslinked rubber layer that is prepared by polymerizing an alkyl (meth)acrylate compound, a crosslinking agent, and a grafting agent.

9. The thermoplastic resin composition according to claim 8 , wherein the grafting agent is comprised in an amount of 0.1 to 1.0 parts by weight with respect to 100 parts by weight of total monomers used in the thermoplastic resin.

10. The thermoplastic resin composition according to claim 1 , wherein the crosslinked rubber layer of b) has a glass transition temperature (Tg) of −70 to −20° C.

11. The thermoplastic resin composition according to claim 1 , wherein the alkyl (meth)acrylate compound of b) is one or more selected from the group consisting of methyl acrylate, ethyl acrylate, butyl acrylate, ethylhexyl acrylate, butyl methacrylate, and ethylhexyl methacrylate.

12. The thermoplastic resin composition according to claim 1 , wherein the crosslinking agent of b) is one or more selected from the group consisting of ethylene glycol dimethacrylate, diethylene glycol dimethacrylate, triethylene glycol dimethacrylate, 1,3-butanediol dimethacrylate, 1,6-hexanediol dimethacrylate, neopentyl glycol dimethacrylate, trimethylol propane trimethacrylate, and trimethylol methane triacrylate.

13. The thermoplastic resin composition according to claim 1 , wherein the crosslinking agent of b) is comprised in an amount of 0.1 to 1.0 parts by weight with respect to 100 parts by weight of total monomers used in the thermoplastic resin.

14. The thermoplastic resin composition according to claim 1 , wherein the thermoplastic resin has an average particle diameter of 150 to 550 nm.

15. The thermoplastic resin composition according to claim 1 , wherein the hard thermoplastic resin of B) has a glass transition temperature (Tg) of 60 to 140° C.

16. The thermoplastic resin composition according to claim 1 , wherein the hard thermoplastic resin of B) has a weight average molecular weight of 50,000 to 500,000 g/mol.

17. The thermoplastic resin composition according to claim 1 , wherein the hard thermoplastic resin of B) is a polymer that is prepared by polymerizing one or more selected from the group consisting of an aromatic vinyl compound, a vinyl cyanide compound, and an alkyl (meth)acrylate.

18. The thermoplastic resin composition according to claim 1 , wherein the thermoplastic resin composition has a light transmittance of 35% or more.

19. The thermoplastic resin composition according to claim 1 , wherein the thermoplastic resin composition has an Izod impact strength of between 16 and 20 (¼″ notched at 23° C., kg·cm/cm), measured according to the ASTM D256 standard.

20. A method of preparing a thermoplastic resin composition, the method comprising a step of melt-kneading and extruding:
A) 20 to 80% by weight of a thermoplastic resin comprising a) a hard core having a refractive index of 1.530 to 1.590, b) a crosslinked rubber layer that surrounds the hard core, has an average thickness of 30 to 80 nm, and is prepared by polymerizing an alkyl (meth)acrylate compound and a crosslinking agent, and c) a non-crosslinked hard shell that surrounds the rubber layer and is prepared by polymerizing an aromatic vinyl compound and a vinyl cyanide compound; and
B) 20 to 80% by weight of a hard thermoplastic resin having a refractive index of 1.52 to 1.56, wherein the thermoplastic resin composition has a coloring property L of between 25.52 and 24.55, and
wherein the hard thermoplastic resin is prepared by copolymerizing 30 to 60% by weight of an alkyl (meth) acrylate compound, 25 to 55% by weight of an aromatic vinyl compound, and 5 to 15% by weight of vinyl cyanide compound.

Assignees

• Lg Chemical Ltd

Inventors

• Oh Hyun Taek
• Hwang Yong Yeon
• Kim Min Jung
• Park Chun Ho
• Lee Sang Mi
• Lee Yeong Min
• Kang Eun Soo

Classifications

• C08L2207/53

  Core-shell polymer · CPC title

• C08J2451/00

  Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers · CPC title

• C08J3/005

  Processes for mixing polymers · CPC title

• C08L25/14

  with unsaturated esters · CPC title

• C08L51/06 Primary

  grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond · CPC title