Film for thermal compression bonding, which contains cholesteric liquid crystal layer, and application thereof

Patent metadata

Field	Value
Publication number	US-10286582-B2
Application number	US-201615088716-A
Country	US
Kind code	B2
Filing date	Apr 1, 2016
Priority date	Oct 4, 2013
Publication date	May 14, 2019
Grant date	May 14, 2019

Abstract

The present invention provides a film for thermal compression bonding, which contains a cholesteric liquid crystal layer that is formed by curing a liquid crystal composition including a polymerizable rod-like liquid crystal compound, a chiral agent, and a polymerizable monomer, in which the polymerizable rod-like liquid crystal includes a monofunctional rod-like liquid crystal compound having one polymerizable group and a bifunctional rod-like liquid crystal compound having two polymerizable groups, or two or more bifunctional rod-like liquid crystal compounds having two polymerizable groups, the polymerizable monomer has three or more polymerizable groups, and the polymerizable monomer is contained in an amount of 0.3% by mass to 6.0% by mass with respect to the total mass of the polymerizable rod-like liquid crystal compounds; a method for producing a molded article using the film for thermal compression bonding; and a molded article produced by the production method.

First claim

What is claimed is:

1. A method for producing a molded article, comprising
preparing a film including a cholesteric liquid crystal layer formed by curing a liquid crystal composition including a polymerizable rod-like liquid crystal compound, a chiral agent, and a polymerizable monomer;
inserting the film into a mold of an injection molding device;
injecting a resin into the mold of the injection molding device; and
heating and compressing the film and the resin with the injection molding device,
wherein
the resin is polycarbonate,
the liquid crystal composition includes as the polymerizable rod-like liquid crystal compound a monofunctional rod-like liquid crystal compound having one polymerizable group and a bifunctional rod-like liquid crystal compound having two polymerizable groups, or includes as the polymerizable rod-like liquid crystal compound two or more bifunctional rod-like liquid crystal compounds having two polymerizable groups,
the polymerizable monomer has three or more polymerizable groups, and
the polymerizable monomer is contained in an amount of 0.3% by mass to 6.0% by mass with respect to the total mass of the polymerizable rod-like liquid crystal compounds.

2. The production method according to claim 1 , wherein the film further comprises a support, wherein the support is a plastic film selected from the group consisting of polyester, an acrylic resin, an epoxy resin, polyurethane, polyamide, polyolefin, a cycloolefin polymer, a cellulose derivative, and silicone.

3. The production method according to claim 2 , wherein the support is polyethylene terephthalate.

4. The production method according to claim 2 , wherein the film consists of the cholesteric liquid crystal layer and the support.

5. The production method according to claim 1 , wherein the film further comprises an alignment layer, wherein the alignment layer is selected from the group consisting of polyimide, polyvinyl alcohol, polyester, polyarylate, polyamideimide, polyether imide, polyamide, and modified polyamide.

6. The production method according to claim 5 , wherein the film consists of the support, the alignment layer, and the cholesteric liquid crystal layer.

7. The production method according to claim 1 , wherein the chiral agent is a left-turning or right-turning chiral agent having an HTP of 30 μm −1 or more.

8. The production method according to claim 1 , wherein the film further comprises the adhesive layer, wherein the adhesive layer is directly in contact with the cholesteric liquid crystal layer.

9. The production method according to claim 8 , wherein the adhesive layer consists of a resin adhesive selected from a group consisting of a thermosetting adhesive, a thermoplastic adhesive, and a pressurizing adhesive.

10. The production method according to claim 1 , wherein the film is prepared to have an adhesive coated on at least one surface.

11. The production method according to claim 10 , wherein the adhesive consists of a resin adhesive selected from a group consisting of a thermosetting adhesive, a thermoplastic adhesive, and a pressurizing adhesive.

12. The production method according to claim 10 , wherein
the film having the adhesive coated thereon is inserted into the mold of the injection molding device; and
the resin is injected into the mold of the injection molding device to be directly applied on the surface side having the adhesive coated thereon.

Assignees

• Fujifilm Corp

Inventors

• Taguchi Takao
• Oki Kazuhiro

Classifications

• B32B2307/704

  Crystalline · CPC title

• C08F222/102

  of dialcohols, e.g. ethylene glycol di(meth)acrylate or 1,4-butanediol dimethacrylate · CPC title

• B32B2255/26

  Polymeric coating · CPC title

• B32B27/283

  comprising polysiloxanes · CPC title

• B32B7/04 Primary

  Interconnection of layers · CPC title