Silicon-based anode and method for manufacturing the same

Patent metadata

Field	Value
Publication number	US-10283759-B2
Application number	US-201715401841-A
Country	US
Kind code	B2
Filing date	Jan 9, 2017
Priority date	Nov 16, 2009
Publication date	May 7, 2019
Grant date	May 7, 2019

Abstract

A silicon-based anode comprising silicon, a carbon coating that coats the surface of the silicon, a polyvinyl acid that binds to at least a portion of the silicon, and vinylene carbonate that seals the interface between the silicon and the polyvinyl acid. Because of its properties, polyvinyl acid binders offer improved anode stability, tunable properties, and many other attractive attributes for silicon-based anodes, which enable the anode to withstand silicon cycles of expansion and contraction during charging and discharging.

First claim

What is claimed is:

1. A method of making a silicon-based anode, comprising:
adding a polyvinyl acid to a suspension comprising approximately 10 percent weight/volume of substantially elemental silicon particles weight to solvent volume so that the suspension comprises no more than approximately 35 weight percent of polyvinyl acid to substantially elemental silicon anode particles after the addition of the polyvinyl acid to the suspension; and
adding vinylene carbonate to the suspension so that the suspension comprises approximately 1-15 weight percent of vinylene carbonate to silicon particles after the addition of the vinylene carbonate to the suspension.

2. The method of claim 1 , further comprising adding a coating to at least a portion of the silicon particles, so that the particles in the suspension comprises approximately 5-30 weight percent of coating to silicon particles after the addition of the coating to the suspension.

3. The method of claim 2 , wherein the coating is a carbon coating.

4. The method of claim 3 , wherein the carbon coating is made by pyrolysis of polycarbonate, propylene, acetylene, or methane.

5. The method of claim 3 , wherein the suspension comprises approximately 10-25 weight percent of polyvinyl acid to silicon and carbon.

6. The method of claim 1 , further comprising coating an anode current collector with the suspension.

7. The method of claim 6 , further comprising heating the anode current collector at a temperature that does not exceed 100° C. to dry the suspension.

8. The method of claim 7 , wherein the temperature is between approximately 70° C. and 100° C.

9. The method of claim 1 , wherein the solvent is methanol, ethanol, or water, or combinations thereof.

10. The method of claim 1 , wherein the silicon particles are silicon alloy particles comprising an atomic percentage of silicon of 50 to 99.999 percent.

11. The method of claim 1 , further comprising sonicating or stirring the suspension.

12. The method of claim 11 , wherein the suspension is sonicated or stirred for approximately 60 minutes.

13. The method of claim 1 , wherein the suspension comprises approximately 10-25 weight percent of polyvinyl acid to silicon anode particles.

14. The method of claim 13 , wherein the suspension comprises approximately 22 weight percent of polyvinyl acid to silicon anode particles.

15. The method of claim 1 , wherein the polyvinyl acid is a carboxyl acid, a phosphoric acid, a sulfonic acid, a polyacrylic acid, or combinations thereof.

16. The method of claim 1 , wherein the suspension comprises approximately 3 weight percent of vinylene carbonate to silicon particles.

17. The method of claim 1 , wherein vinylene carbonate is configured to continuously release into an electrolyte of an assembled cell based on time.

18. The method of claim 17 , wherein vinylene carbonate is configured to continuously release into the electrolyte of the assembled cell for 1 day to 300 days.

19. A silicon-based anode manufactured according to the method of claim 1 .

20. A method of making a silicon-based anode, comprising:
adding a polyvinyl acid to a suspension comprising approximately 10 percent weight/volume of substantially elemental silicon particles weight to solvent volume so that the suspension comprises no more than approximately 35 weight percent of polyvinyl acid to substantially elemental silicon anode particles after the addition of the polyvinyl acid to the suspension;
coating an anode current collector with the suspension, drying the suspension; and
spraying the anode current collector with a vinylene carbonate-containing solvent so that the anode comprises approximately 1-15 weight percent of vinylene carbonate to silicon particles after the spraying of the vinylene carbonate.

21. The method of claim 20 , further comprising evaporating the solvent.

22. A silicon-based anode manufactured according to the method of claim 20 .

23. The method of claim 11 , wherein the sonicating or stirring causes the vinylene carbonate, the polyvinyl acid and the substantially elemental silicon particles to be dispersed throughout the suspension.

Assignees

• Univ Clemson Res Foundation
• Georgia Tech Res Inst

Inventors

• Yushin Gleb Nikolayevich
• Luzinov Igor
• Zdyrko Bogdan
• Magasinski Alexandre

Classifications

• H01M4/1395 Primary

  of electrodes based on metals, Si or alloys · CPC title

• H01M4/386

  Silicon or alloys based on silicon · CPC title

• H01M4/622

  being polymers · CPC title

• H01M4/0419

  involving spraying · CPC title

• H01M4/366

  as layered products · CPC title