Positive electrode active material precursor for lithium secondary battery, positive electrode active material manufactured by using thereof, and lithium secondary battery including same

Patent metadata

Field	Value
Publication number	US-10283757-B2
Application number	US-201615092303-A
Country	US
Kind code	B2
Filing date	Apr 6, 2016
Priority date	Jun 8, 2012
Publication date	May 7, 2019
Grant date	May 7, 2019

Abstract

The present disclosure relates to a positive electrode active material precursor for a lithium secondary battery, a positive electrode active material manufactured by using thereof, and a lithium secondary battery comprising the same. More specifically, it relates to a positive electrode active material precursor for a lithium secondary battery as a secondary particle comprising transition metals, and formed by gathering of a plurality of primary particles having different a-axis direction length to c-axis direction length ratio, wherein the a-axis direction length to c-axis direction length ratio of the primary particle making up the secondary particle is increased from the center to the surface of the secondary particle; a positive electrode active material; and a lithium secondary battery comprising the same.

First claim

What is claimed is:

1. A positive electrode active material for a lithium secondary battery, which is a secondary particle comprising transition metals,
wherein the secondary particle comprises a plurality of primary particles,
wherein the primary particles have a crystal structure that has an a-axis and a c-axis,
wherein the a-axis direction is a direction from a center to a surface of the secondary particle, and the c-axis direction is perpendicular to the a-axis direction,
wherein the secondary particle comprises the primary particles having the a-axis direction length to the c-axis direction length ratios different from each other,
wherein the a-axis orientation of the primary particles is headed to the center of the secondary particle, and the primary particles are adjoining each other and align with the a-axis direction, and
wherein the a-axis and the c-axis are defined by a diffraction pattern of Fast Fourier Transform from a TEM image of the primary particles.

2. The positive electrode active material for a lithium secondary battery according to claim 1 , wherein at least one metal has concentration gradient in the secondary particle.

3. The positive electrode active material for a lithium secondary battery according to claim 1 , wherein the primary particles comprise Ni.

4. The positive electrode active material for a lithium secondary battery according to claim 1 ,
wherein at least one metal in a first interior has constant concentration, and
wherein at least one metal in a second interior has concentration gradient.

5. The positive electrode active material for a lithium secondary battery according to claim 1 ,
wherein the a-axis direction length to the c-axis direction length ratios of the primary particles are sequentially increased from a center to a surface of the secondary particle.

6. The positive electrode active material for a lithium secondary battery according to claim 1 ,
wherein the primary particles comprise at least two of Ni, Co, or Mn, and
wherein at least one of Ni, Co, or Mn has concentration gradient in the secondary particle.

7. The positive electrode active material for a lithium secondary battery according to claim 6 ,
wherein Ni concentration of the center of the secondary particle is higher than Ni concentration of a surface of the secondary particle.

8. The positive electrode active material for a lithium secondary battery according to claim 6 ,
wherein the secondary particle comprises a first primary particle adjacent to the center of the secondary particle and a second primary particle adjacent to the surface of the secondary particle, and
wherein average Ni concentration of the first primary particle is higher than average Ni concentration of the second primary particle.

9. A positive electrode active material for a lithium secondary battery, which is a secondary particle comprising transition metals,
wherein the secondary particle comprises a plurality of primary particles,
wherein the plurality of the primary particles provide lithium ion path headed to the center of the secondary particle,
wherein a crystal structure of the primary particles has an a-axis and a c-axis,
wherein the a-axis direction is a direction from a center to a surface of the secondary particle, and the c-axis direction is perpendicular to the a-axis direction, and
wherein the a-axis and the c-axis are defined by a diffraction pattern of Fast Fourier Transform from a TEM image of the primary particles.

10. A positive electrode active material for a lithium secondary battery, which is a secondary particle comprising transition metals,
wherein the secondary particle comprises a plurality of primary particles,
wherein the secondary particle comprises at least one of Ni, Co, or Mn,
wherein at least one metal in the primary particles has concentration gradient,
wherein a crystal structure of the primary particles has an a-axis and a c-axis,
wherein the a-axis direction is a direction from a center to a surface of the secondary particle, and the c-axis direction is perpendicular to the a-axis direction, and
wherein the a-axis and the c-axis are defined by a diffraction pattern of Fast Fourier Transform from a TEM image of the primary particles.

11. The positive electrode material for a lithium secondary battery according to claim 10 ,
wherein at least one metal in the primary particles has continuous concentration gradient in the primary particles from a center of the secondary particle to a surface of the secondary particle.

12. The positive electrode material for a lithium secondary battery according to claim 10 ,
wherein the secondary particle comprises Ni, and Ni in the primary particles has concentration gradient in the primary particles.

Assignees

• Iucf Hyu
• Enerceramic Inc

Inventors

• Noh Hyung-Joo
• Sun Yang-Kook
• Park Jang-Wook

Classifications

• H01M4/13 Primary

  Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof · CPC title

• H01M4/505

  of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy · CPC title

• H01M4/525 Primary

  of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy · CPC title

• C01G53/50

  of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2 · CPC title

• H01M10/052

  Li-accumulators · CPC title